BIOLOGICAL DEFINITION

Hazard statements (CLP)

H302

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16 CLASSIFICATION (67/548/EEC) THE FULL TEXT FOR ALL R-PHRASES AND HAZARD STATEMENTS ARE DISPLAYED IN SECTION 16 HUMAN HEALTH - THE LIQUID IS IRRITATING TO EYES AND SKIN. HARMFUL IF SWALLOWED PHYSICAL HAZARDS: THIS MIXTURE DOES NOT PRESENT A PHYSICAL HAZARD CLASSIFICATION (EU1272/2008) HEALTH HAZARDS: ACUTE ORAL TOXICITY, CATEGORY 4 (ACUTE TOX. 4, H302) ENVIRONMENTAL HAZARDS: THIS MIXTURE DOES NOT PRESENT AN ENVIRONMENTAL HAZARD

2.2 Label elements

GHS07

Signal word

WARNING.

Contains

EC 284-510-0 MYRRH OIL (C. MYRRHA)

Hazard statements

H302 HARMFUL IF SWALLOWED. P264 WASH WITH WATER AND SOAP THOROUGHLY AFTER HANDLING. P270 DO NO EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.

Precautionary statements

P301 + P312 IF SWALLOWED: CALL A POISON CENTER/DOCTOR/.../IF YOU FEEL UNWELL. P330 RINSE MOUTH. P501 DISPOSE OF CONTENTS/CONTAINER TO WASTE DISPOSAL FACILITY LICENSED. SUPPLEMENTARY PRECAUTIONARY STATEMENTS NONE SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL.

2.3 Other hazards

ADVERSE PHYSIO-CHEMICAL PROPERTIES NO DATA THE MIXTURE DOES NOT CONTAIN SUBSTANCES CLASSIFIED AS ‘SUBSTANCES OF VERY HIGH CONCERN' (SVHC) >= 0.1% PUBLISHED BY THE EUROPEAN

Potential Acute Health Effects

CHEMICALS AGENCY (ECHA) UNDER ARTICLE 57 OF REACH: HTTP://ECHA.EUROPA.EU/FR/CANDIDATE-LIST-TABLE. THE MIXTURE SATISFIES NEITHER THE PBT NOR THE VPVB CRITERIA FOR MIXTURES IN ACCORDANCE WITH ANNEXE XIII OF THE

2.1 Classification of the substance or mixture

CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16. THE FULL TEXT FOR ALL R-PHRASES AND HAZARD STATEMENTS ARE DISPLAYED IN SECTION 16. CLASSIFICATION (67/548/EEC) HUMAN HEALTH - THE LIQUID IS IRRITATING TO EYES AND SKIN. HARMFUL IF SWALLOWED PHYSICAL HAZARDS: THIS MIXTURE DOES NOT PRESENT A PHYSICAL HAZARD. CLASSIFICATION (EU1272/2008) HEALTH HAZARDS: ACUTE ORAL TOXICITY, CATEGORY 4 (ACUTE TOX. 4, H302). ENVIRONMENTAL HAZARDS: THIS MIXTURE DOES NOT PRESENT AN ENVIRONMENTAL HAZARD. 2.2 LABEL ELEMENTS LABEL IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008. GHS LABEL GHS07 SIGNAL WORD WARNING. CONTAINS EC 284-510-0 MYRRH OIL (C. MYRRHA) HAZARDS STATEMENT H302 HARMFUL IF SWALLOWED. P264 WASH WITH WATER AND SOAP THOROUGHLY AFTER HANDLING. P270 DO NO EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. PRECAUTIONARY STATEMENTS P301 + P312 IF SWALLOWED: CALL A POISON CENTER/DOCTOR/.../IF YOU FEEL UNWELL. P330 RINSE MOUTH. P501 DISPOSE OF CONTENTS/CONTAINER TO WASTE DISPOSAL FACILITY LICENSED. SUPPLEMENTARY PRECAUTIONARY STATEMENTS NONE SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL. 2.3 OTHER HAZARDS ADVERSE PHYSIO-CHEMICAL PROPERTIES NO DATA THE MIXTURE DOES NOT CONTAIN SUBSTANCES CLASSIFIED AS ‘SUBSTANCES OF VERY HIGH CONCERN' (SVHC) >= 0.1% PUBLISHED BY THE EUROPEAN ADVERSE EFFECTS ON HUMAN HEALTH CHEMICALS AGENCY (ECHA) UNDER ARTICLE 57 OF REACH: HTTP://ECHA.EUROPA.EU/FR/CANDIDATE-LIST-TABLE. THE MIXTURE SATISFIES NEITHER THE PBT NOR THE VPVB CRITERIA FOR MIXTURES IN ACCORDANCE WITH ANNEXE XIII OF THE REACH REGULATIONS EC 1907/2006. THE MIXTURE FULFILS NEITHER THE PBT NOR THE VPVB CRITERIA FOR MIXTURES IN ACCORDANCE WITH ANNEXE XIII OF THE REACH PBT OR VPVB ACCORDING TO ANNEX XIII REGULATIONS EC 1907/2006. SECTION 3: COMPOSITION OF INGREDIENTS 100% MYRRH OIL (C. MYRRHA) CAS NO: 8016-37-3 3.2 SUBSTANCES EC NO: 284-510-0 CLASSIFICATION (EC 1272/2008) GHS07, WNG, ACUTE TOX. 4, H302 SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION ALWAYS REMOVE CONTAMINATED CLOTHING IMMEDIATELY. INHALATION GET MEDICAL ATTENTION IMMEDIATELY. REMOVE FROM EXPOSURE SITE TO FRESH AIR, KEEP AT REST, AND OBTAIN MEDICAL ATTENTION. DO NOT GIVE THE PATIENT ANYTHING ORALLY. IN THE EVENT OF SWALLOWING, IF THE QUANTITY IS SMALL (NO MORE THAN ONE INGESTION MOUTHFUL), RINSE THE MOUTH WITH WATER, ADMINISTER ACTIVATED MEDICAL CHARCOAL AND CONSULT A DOCTOR. SEEK MEDICAL ATTENTION, SHOWING THE LABEL. IF SWALLOWED ACCIDENTALLY, CALL A DOCTOR TO ASCERTAIN WHETHER OBSERVATION AND HOSPITAL CARE WILL BE NECESSARY. SKIN CONTACT REMOVE CONTAMINATED CLOTHES. WASH THOROUGHLY WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION PERSISTS. EYE CONTACT FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF SYMPTOMS PERSIST. 4.2 MOST IMPORTANT SYMPTOMS & EFFECTS (ACUTE & NO ADDITIONAL DATA AVAILABLE. DELAYED) 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION OR NO ADDITIONAL DATA AVAILABLE. SPECIAL TREATMENT REQUIRED SECTION 5: FIRE FIGHTING MEASURES 5.1 NON FLAMMABLE, THEREFORE EXTINGUISH FLAMES AS PER SURROUNDING AREA DICTATES. EXTINGUISHING MATERIAL EXTINGUISHING MEDIA: CARBON DIOXIDE (CO2). POWDER. WATER SPRAY. 5.2 A FIRE WILL OFTEN PRODUCE A THICK BLACK SMOKE. EXPOSURE TO DECOMPOSITION PRODUCTS MAY BE HAZARDOUS TO SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR HEALTH. DO NOT BREATHE IN SMOKE. MIXTURE IN THE EVENT OF A FIRE, THE FOLLOWING MAY BE FORMED: CARBON MONOXIDE (CO) AND CARBON DIOXIDE (CO2) 5.3 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: ADVICE FOR FIRE-FIGHTERS WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND APPROPRIATE PROTECTIVE CLOTHING. SECTION 6: ACCIDENTAL RELEASE MEASURES WEAR PROTECTIVE CLOTHING AS DESCRIBED IN SECTION 8 OF THIS SAFETY DATA SHEET. HANDLE THE PRODUCT USING 6.1 PROTECTIVE GLOVES RESISTANT TO THE CHEMICALS EXPOSED. AVOID CONTACT WITH SKIN AND EYES. MAINTAIN ADEQUATE PERSONAL PRECAUTIONS VENTILATION IN THE WORKING AREA AFTER SPILLING. 6.2 DO NOT DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DISPOSE OF IN LINE WITH LOCAL AUTHORITY ENVIRONMENTAL PRECAUTIONS GUIDELINES. 6.3 COVER WITH AN INERT, INORGANIC, NON-COMBUSTIBLE ABSORBENT MATERIAL (E.G. DRY-LIME, SAND, SODA ASH). PLACE IN METHODS & MATERIAL FOR CONTAINMENT AND CLEANING COVERED CONTAINERS USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS. VENTILATE AREA AND WASH SPILL SITE WITH DETERGENT AFTER MATERIAL PICKUP IS COMPLETE. DO NOT USE SOLVENTS. DISPOSE OF IN ACCORDANCE WITH CURRENT UP LAWS AND REGULATIONS. 6.4 REFERENCES TO OTHER SECTIONS REFER & CONSIDER SECTION 8. SECTION 7: HANDLING & STORAGE ALWAYS WASH HANDS AFTER HANDLING. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USING. FIRE PREVENTION: PREVENT ACCESS BY UNAUTHORISED PERSONNEL. 7.1 RECOMMENDED EQUIPMENT AND PROCEDURES: FOR PERSONAL PROTECTION, SEE SECTION 8. OBSERVE PRECAUTIONS STATED PRECAUTIONS FOR SAFE-HANDLING ON LABEL AND ALSO INDUSTRIAL SAFETY REGULATIONS. PROHIBITED EQUIPMENT AND PROCEDURES: NO SMOKING, EATING OR DRINKING IN AREAS WHERE THE MIXTURE IS USED. 7.2 KEEP THE PRODUCT CONTAINER TIGHTLY CLOSED, IN A DRY, VENTILATED AREA. KEEP AWAY FROM POTENTIAL SOURCES OF CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES IGNITION AND PROTECTED FROM LIGHT. MAINTAIN LIMITED CONTACT WITH OXYGEN. 7.3 NO DATA. SPECIFIC END USE(S) SECTION 8: EXPOSURE CONTROLS & PERSONAL PROTECTION 8.1 NONE. CONTROL PARAMETERS 8.2 EXPOSURE CONTROLS EYE PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. HAND PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. RESPIRATORY EQUIPMENT WEAR SUITABLE RESPIRATORY EQUIPMENT. HYGIENE MEASURES GOOD PERSONAL HYGIENE PRACTICES ARE ALWAYS ADVISABLE, ESPECIALLY WHEN WORKING WITH CHEMICALS / OILS. ENGINEERING MEASURES PROVIDE ADEQUATE VENTILATION. WORK CLOTHING WORN BY PERSONNEL SHALL BE LAUNDERED REGULARLY. AFTER CONTACT WITH THE PRODUCT, ALL PARTS OF SKIN PROTECTION THE BODY THAT HAVE BEEN SOILED MUST BE WASHED. AVOID INHALATION AND CONTACT WITH SKIN AND EYES. USE PERSONAL PROTECTIVE EQUIPMENT THAT IS CLEAN AND HAS BEEN PERSONAL PROTECTION PROPERLY MAINTAINED. STORE PERSONAL PROTECTIVE EQUIPMENT IN A CLEAN PLACE, AWAY FROM THE WORK AREA. OTHER PROTECTION WEAR SUITABLE PROTECTION TO AVOID CONTACT WITH SKIN AND EYES. DO NOT INHALE VAPOURS. PROCESS CONDITIONS ENSURE AREA IS WELL VENTILATED. AVOID VAPOUR INHALATION. SAFETY SHOWER & EYE BATH. ENVIROMENTAL EXPOSURE CONTROLS AVOID DISCHARGING INTO DRAINAGE WATER. ONLY ELIMINATE BY AUTHORISED COMPANIES. SECTION 9: PHYSICAL & CHEMICAL PROPERTIES 9.1 PHYSICAL & CHEMICAL PROPERTIES APPEARANCE LIQUID COLOUR AMBER YELLOW TO BROWN YELLOW OFTEN WITH GREENISH TINGE. ODOUR CHARACTERISTIC, BALSAMIC, SPICY RELATIVE DENSITY APPROX. 0.995 @ 20°C FLASH POINT (°C) > 100 C REFRACTIVE INDEX @ 20 °C APPROX. 1.507 @ 20°C SOLUBILITY IN WATER @ 20 °C NO DATA 9.2 OTHER INFORMATION NO DATA SECTION 10: STABILITY & REACTIVITY 10.1 REACTIVITY NO HAZARDOUS REACTIONS IF STORED AND HANDLED AS PRESCRIBED / INDICATED. 10.2 CHEMICAL STABILITY STABLE UNDER SUGGESTED STORAGE CONDITIONS (<15°C). 10.3 POSSIBILITY OF HAZARDOUS REACTIONS NO ADDITIONAL DATA AVAILABLE. 10.4 CONDITIONS TO AVOID STORAGE AT HIGH TEMPERATURES. DO NOT STORE ABOVE 15°C. 10.5 INCOMPATIBLE MATERIALS NO ADDITIONAL DATA AVAILABLE. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS THE THERMAL DECOMPOSITION MAY RELEASE/FORM CARBON MONOXIDE AND CARBON DIOXIDE (CO) (CO2). SECTION 11: TOXICOLOGICAL INFORMATION 11.1 TOXICOLOGICAL EFFECTS HARMFUL IF SWALLOWED. ACUTE TOXICITY MYRRH OIL (C. MYRRHA) (CAS NO: 8016-37-3) ORAL ROUTE: LD50 = 1650 MG/KG. SPECIES: RAT SKIN IRRITATION NO ADDITIONAL DATA AVAILABLE. EYE DAMAGE OR IRRITATION NO ADDITIONAL DATA AVAILABLE. RESPIRATORY OR SKIN SENSITIVITY NO ADDITIONAL DATA AVAILABLE. GERM CELL MUTAGENICITY NO ADDITIONAL DATA AVAILABLE. CARCINOGENICITY NO ADDITIONAL DATA AVAILABLE. REPRODUCTIVE TOXICITY NO ADDITIONAL DATA AVAILABLE. STOT – SINGLE EXPOSURE NO ADDITIONAL DATA AVAILABLE. STOT – REPEATED EXPOSURE NO ADDITIONAL DATA AVAILABLE. ASPIRATION HAZARD NO ADDITIONAL DATA AVAILABLE. OTHER INFORMATION NO ADDITIONAL DATA AVAILABLE. SECTION 12: ECOLOGICAL INFORMATION 12.1 NO ADDITIONAL DATA AVAILABLE. TOXICITY 12.2 PERSISTENCE & DEGRADABILITY NO ADDITIONAL DATA AVAILABLE. 12.3 BIO- ACCUMULATIVE POTENTIAL NO ADDITIONAL DATA AVAILABLE. 12.4 MOBILITY IN SOIL NO ADDITIONAL DATA AVAILABLE. 12.5 RESULTS OF PBT & VPVB ASSESSMENT NO ADDITIONAL DATA AVAILABLE. 12.6 OTHER ADVERSE EFFECTS DO NOT ALLOW PRODUCT TO ENTER STREAMS, SEWERS OR OTHER WATERWAYS. SECTION 13: DISPOSAL INFORMATION DISPOSE OF IN COMPLIANCE WITH ALL LOCAL AND NATIONAL REGULATIONS. PROPER WASTE MANAGEMENT OF THE MIXTURE AND/OR ITS CONTAINER MUST BE DETERMINED IN ACCORDANCE WITH DIRECTIVE 2008/98/EC. WASTE: DO NOT POUR INTO DRAINS OR WATERWAYS. WASTE MANAGEMENT IS CARRIED OUT WITHOUT ENDANGERING HUMAN HEALTH, WITHOUT HARMING THE ENVIRONMENT AND, IN PARTICULAR WITHOUT 13.1 RISK TO WATER, AIR, SOIL, PLANTS OR ANIMALS. WASTE TREATMENT METHODS RECYCLE OR DISPOSE OF WASTE IN COMPLIANCE WITH CURRENT LEGISLATION, PREFERABLY VIA A CERTIFIED COLLECTOR OR COMPANY. DO NOT CONTAMINATE THE GROUND OR WATER WITH WASTE, DO NOT DISPOSE OF WASTE INTO THE ENVIRONMENT. SOILED PACKAGING: EMPTY CONTAINER COMPLETELY. KEEP LABEL(S) ON CONTAINER. GIVE TO A CERTIFIED DISPOSAL CONTRACTOR. SECTION 14: TRANSPORT INFORMATION 14.1 TRANSPORT INFORMATION UN NUMBER NOT REGULATED 14.2 UN SHIPPING NAME NONE. 14.3 NONE. TRANSPORT HAZARD CLASS(ES) 14.4 PACKING GROUP NONE. 14.5 NO DATA. ENVIROMENTAL HAZARDS 14.6 SPECIAL PRECAUTIONS FOR USER NO ADDITIONAL DATA AVAILABLE. 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 & THE IBC NO DATA CODE. SECTION 15: REGULATORY INFORMATION 15.1 PRODUCT SPECIFIC SAFETY, HEALTH & ENVIRONMENTAL REGULATIONS & LEGISLATION REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL OF 18TH DECEMBER 2006. CONCERNING THE REGISTRATION, EVALUATION, AUTHORIZATION & RESTRICTION OF EU DIRECTIVES CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION (EEC) NO793/93 & COMMISSION REGULATION (EC) NO1488/94 AS WELL AS COUNCIL DIRECTIVE 76/769/EEC & COMMISSION DIRECTIVE 91/155/ECC, 93/67/ECC, 93/105/EEC & 2000/21/EC (INCLUDING AMENDMENTS). THE CHEMICALS (HAZARD INFORMATION & PACKAGING FOR SUPPLY REGULATIONS 2009 (S.I.2009 STATUTORY INSTRUMENTS NO 716). CLASSIFICATION & LABELLING OF SUBSTANCES & PREPARATIONS DANGEROUS FOR SUPPLY. SAFETY DATA APPROVED CODE OF PRACTICE SHEETS FOR SUBSTANCES & PREPARATIONS. GUIDANCE NOTES WORKPLACE EXPOSURE LIMITS EH40. CHIP FOR EVERYONE HSG 108. 15.2 CHEMICAL SAFETY ASSESSMENT - SECTION 16: OTHER INFORMATION HAZARD AND/ OR PRECAUTIONARY STATEMENTS IN FULL H302 HARMFUL IF SWALLOWED. TRAINING INSTRUCTIONS: REFER TO POSSIBLE HAZARD BEFORE USE OF THIS PRODUCT. ABBREVIATIONS & ACRONYMS: MSDS MATERIAL SAFETY DATA SHEET. INCI INTERNATIONAL NOMENCLATURE OF COSMETIC INGREDIENTS. CAS CHEMICAL ABSTRACT SERVICE. IMDG INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS. ACCORD EUROPEAN SUR LE TRANSPORT DES MERCHANDISES DANGEREUSES PAR ROUTE (EUROPEAN ADR AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD). RID INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY RAIL. ICAO INTERNATIONAL CIVIL AVIATION ORGANIZATION. ADN INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS. GHS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION & LABELLING OF CHEMICALS. TREM CARD TRANSPORT EMERGENCY CARD. STOT SPECIFIC TARGET ORGAN TOXICITY. DOCUMENTATION REVISION DATE CHANGE DESCRIPTION 10TH APRIL 2018 DATA LAUNCH 2021 REVIEW JANUARY 2023 REVIEW SPECIFICATION SHEET PRODUCT NAME: MYRRH, ESSENTIAL OIL PRODUCT INCI: COMMIPHORA MYRRHA OIL CAS NUMBER: 84929-26-0 EINECS NUMBER: 284-510-0 MANUFACTURING METHOD: STEAM DISTILLATION SHELF LIFE / BEST BEFORE: 36 MONTHS ANALYTICAL DETAILS RANGE APPEARANCE LIQUID COLOUR LIQUID AMBER YELLOW TO BROWN YELLOW (OFTEN WITH GREENISH TINGE) ODOUR CHARACTERISTIC, BALSAMIC SPICY. SPECIFIC GRAVITY @ 20C 0.950 – 1.040 REFRACTIVE INDEX @ 20C 1.485 – 1.530 OPTICAL ROTATION (C) -120.0 TO -30.0 STORAGE CONDITIONS STORE IN A COOL DRY PLACE AWAY FROM HEAT & SUNLIGHT DOCUMENTATION REVIEW DATE: 2021 Vegetarian & Vegan Suitability Statement PRODUCT NAME: Myrrh Ekokoza s.r.o. can confirm that the above listed product has not been tested in animals and does not contain dairy or any other animal product, by product or derivative and is therefore suitable for vegetarian and vegan use. 06/03/2023