KERA S-Powder

Hazard statements (CLP)

H301, H302, H312, H314, H317, H319, H330, H334, H340, H350, H350i, H360, H360FD, H372, H400, H410, H413

Code

Statements

H301

Toxic if swallowed

2.1 Classification of the substance or mixture

The sinter powder has been classified and labelled according to the CLP regulation. Classification of the substance according to Regulation (EC) No. 1272/2008

Hazard categories

Acute toxicity: Acute tox. 4 - Serious eye damage/eye irritation: Eye irrit. 2 - Respiratory/skin sensitization: Resp. sens. 1 . . - Respiratory/skin sensitization: Skin sens. 1 - Carcinogenicity: Carc. 1B - Reproductive toxicity: Repr. 1B - Hazardous to the aquatic environment: Aqu. chron. 4

Hazard statements

Harmful if swallowed. - May cause an allergic skin reaction. - Causes serious eye irritation. - May cause allergy or asthma symptoms or breathing difficulties if inhaled. - May cause cancer if inhaled. - May damage fertility. May damage the unborn child. Information concerning - May cause long lasting harmful effects to aquatic life. particular hazards for humans and for the This product must be labelled due to the calculation procedure of the P201 Obtain special instructions before use. P261 Avoid breathing dust. P280 Wear protective gloves/protective clothing/eye protection/face protection. P308+ P313 If exposed or concerned: Get medical advice/attention. P342+ P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Welding and brazing processes can cause spatter, melting metal and UV/IR heat can cause burns or start fires. Chromium: Dust and smoke arise during welding and grinding. Chromium(VI)oxide, which is classified as carcinogenic particulate matter and ozone can arise. During welding sodium chromate can arise. Sodium chromate is classified as follows: H350 May cause cancer. H340 May cause genetic defects. H360FD May damage fertility. May damage the unborn child. H330 Fatal if inhaled. H301 Toxic if swallowed. H372 Causes damage to organs through prolonged or repeated exposure. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H410 Very toxic to aquatic life with long lasting effects. 2.3 Other hazards during opening and processing of the alloy: This classification applies only to sodium chromate. The percentage of sodium chromate contained in the welding fume depends on the electrode, the welding material and conditions. It is not possible to assess which of the aforementioned properties the welding fumes actually have. Cobalt: The mandatory harmonized classification (as set out in Annex VI of the Regulation (EC) No 1272/2008) differs from the registered classification at ECHA (European Chemicals Agency). The following H statements were added to the mandatory, harmonized

Environmental hazards

EC General Classification Directive for Preparations" in its latest valid version. Users: Qualified professionals (dental technicians, dentists)

Classification system

The classification complies with the latest EU lists, but there are additional data from specialized literature and from the company. The following identification is applicable for any kind of handling the powder, such as opening the container, working or processing its contents, since dust, vapor or smoke is generated. 2.2 GHS07 / GHS08-

Hazardous Ingredients

Cobalt

Signal word

Warning / Danger

Hazard pictograms

GHS07 / GHS08 Danger! Attention H302 Harmful if swallowed. GHS08 GHS07 H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350i May cause cancer if inhaled. H360FD May damage fertility. May damage the unborn child. H413 May cause long lasting harmful effects to aquatic life.

Classifications

H302 Harmful if swallowed. H319 Causes serious eye irritation. H330 Fatal if inhaled. H350 May cause cancer. H360 May damage fertility. May damage the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. The mandatory H statement “H413 Harmful to aquatic life with long lasting effects” is used instead of the H statements being proposed by ECHA “H400 Very toxic to aquatic life” and “H410 Very toxic to aquatic life with long lasting effects”. For alloys, the classification as H330 “Fatal if inhaled” is not recommended by the Cobalt Development Institute (CDI).