BB Ultra Sport Spray (Pump) SPF 50

Hazard statements (CLP)

H225, H320

Code

Statements

H225

Highly Flammable liquid and vapour

Classification (GHS-US)

OSHA Flammable liquids Category 2 Highly flammable liquid and vapor Serious eye damage/eye irritation Category 2B Causes eye iritation

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor Causes eye irritation

Precautionary statements

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed Ground/Bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment Use only non-sparking tools. Take precautionary measures against static discharge Wear protective clothing, eye protection, face protection, protective gloves. Wash hands, forearms and face thoroughly after handling In case of fire: Use media other than water to extinguish If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 10/3/2024 (Revision date) US-en 112 If eye iritation persists: Get medical advice or attention Store in a well-ventilated place. Keep cool Dispose of container in accordance with local, regional, national and intemational regulations

Other hazards which do not result in classification

No additional information available

Ingredient(s) with unknown acute toxicity

No additional information available 3.1. Substances Not applicable 3.2. Mixtures Name

Product definition

Ethyl alcohol CAS-No: 64-17-5 |60 -80 2-Propenoic acid, 2-cyano-3,3-diphenyl-, 2-ethylhexyl ester CAS-No.: 6197-304 |5- 10 Decanoic acid, ester with 1,2,3-propanetriol octanoate CAS-No.: 65381-09-1 |3-7 Hydrocarbons, C4, 1,3-butadiene-free, polymerized, triisobutylene fraction, hydrogenated CAS-No.: 93685-81-5 [3-7 2-Ethylhexyl salicylate CAS-No: 118-60-5 [3-7 1,3-Propanedione, 1-[4-(1,1-dimethylethyl)phenyi]-3-(4-methoxyphenyl)- CAS-No.: 70356-09-1 [1-5 D-Limonene CAS-No.: 5989-27-5 |0.1—1 Comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. US GHS: The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph

Further information

This material and its container must be disposed of in a safe way, and as per local legislation. 10/3/2024 (Revision date) US-en 312 6.4. Reference to other sections For further information refer to section 13. 7.1. Precautions for safe handling Additional hazards when processed Not expected to present a significant hazard under anticipated conditions of normal use. Precautions for safe handling Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapors may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not taste or swallow. Ensure good ventilation of the work station. Handle and open container with care. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product 7.2. Conditions for safe storage, including any incompatibilities Technical measures Ground/bond container and receiving equipment Storage conditions Store in a well-ventilated place. Keep cool. Keep container tightly closed. Keep out of reach of children. Store tightly closed in a dry, cool and well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS) Packaging materials Store always product in container of same material as original container. 8.1. Control parameters BB Ultra Sport Spray (Pump) SPF 50 No additional information available Ethyl alcohol (64-17-5) USA - ACGIH - Occupational Exposure Limits ACGIH OEL STEL 1000 ppm Remark (ACGIH) TLV® Basis URT irr. Notations A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans) ACGIH chemical category Confirmed Animal Carcinogen with Unknown Relevance to Humans Regulatory reference ACGIH 2024 USA No additional information available 10.1. React ty Highly flammable liquid and vapor. 10.2. Chemical stability Stable under normal conditions. 10.3. Possil ity of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include and are not limited to: oxides of carbon 11.1. Information on toxicological effects Acute toxicity (oral) Not classified Acute toxicity (dermal) Not classified Acute toxicity (inhalation) Not classified Ethyl alcohol ( 64-17-5) LD50 oral rat 7060 mg/kg (Source: NLM_CIP) 10/3/2024 (Revision date) US-en Ethyl alcohol ( 64-17-5) LD50 oral 8300 mg/kg body weight Animal: mouse LD50 dermal rabbit > 15800 mg/kg body weight (Rabbit, Experimental value, Dermal) LC50 Inhalation - Rat 133.8 mgl/4h LC50 Inhalation - Rat (Dust/Mist) > mg/li4h LC50 Inhalation - Rat (Vapours) 133.8 mgl/4h ATE US (oral) 7060 mg/kg body weight ATE US (vapors) 133.8 mgl/4h ATE US (dust, mist) 133.8 mg//4h 2-Propenoic acid, 2-cyano-3,3-diphenyl-, 2-ethylhexyl ester ( 6197-30-4) LD50 oral rat > 5 gkg (Source: NLM_CIP) LD50 dermal rat > 2000 mg/kg (Source: ECHA_API) Hydrocarbons, C4, 1,3-butadiene-free, polymerized, triisobutylene fraction, hydrogenated ( 93685-81-5) LD50 oral rat > 2000 mg/kg (Source: IUCLID) LD50 dermal rat 2000 mg/kg body weight Animal rat, Guideline OECD Guideline 402 (Acute Dermal Toxicity) LD50 dermal rabbit > 5000 mg/kg (Source: ECHA_API) LC50 Inhalation - Rat > 16.7 mg/li4h LC50 Inhalation - Rat (Vapours) > 16.7 mg/li4h 2-Ethylhexyl salicylate ( 118-60-5) LD50 oral rat > 5000 mg/kg (Source: EU_CLH) LD50 dermal rat > 5000 mg/kg (Source: ECHA_API) 1,3-Propanedione, 1-[4-(1,1-dimethylethyl)phe nyl]-3-(4-methoxyphenyl)- ( 70356-09-1) LD50 oral rat 16000 mg/kg body weight Animal rat, Guideline OECD Guideline 401 (Acute Oral Toxicity) LD50 dermal rat 1000 mg/kg body weight Animal rat, Guideline OECD Guideline 402 (Acute Dermal Toxicity) D-Limonene ( 5989-27-5) LD50 oral rat 4400 mglkg (Source: CHEMVIEW) LD50 dermal rabbit > 5 gkg (Source: CHEMVIEW) LC50 Inhalation - Rat (Vapours) > 20 mg/lih ATE US (oral) 4400 mg/kg body weight Skin corrosioniiritation Not classified Serious eye damagefiritation Causes eye irritation Respiratory or skin sensitization Not classified Germ cell mutagenicity Not classified Carcinogenicity Not classified Ethyl alcohol ( 64-17-5) IARC group 1 - Carcinogenic to humans, (in alcoholic beverages) D-Limonene ( 5989-27-5) IARC group 3 - Not classifiable 10/3/2024 (Revision date) US-en 712 D-Limonene ( 5989-27-5) National Toxicity Program (NTP) Status Evidence of Carcinogenicity Reproductive toxicity Not classified STOT-single exposure Not classified STOT-repeated exposure Not classified Ethyl alcohol ( 64-17-5) NOAEL (subchronic oral,animal/male,90 days) 9700 mg/kg body weight Animal mouse, Animal sex male, Guideline EPA OPPTS 870.3100 (90-Day Oral Toxicity in Rodents) NOAEL (subchronic,oral, animal/female,90 days) 9400 mg/kg body weight Animal mouse, Animal sex female, Guideline EPA OPPTS 870.3100 (90-Day Oral Toxicity in Rodents) 2-Ethylhexyl salicylate ( 118-60-5) NOAEL (oral,rat,90 days) 250 mg/kg body weight Animal rat, Guideline OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity Study in Rodents) 1,3-Propanedione, 1-[4-(1,1-dimethylethyl) phenyl]-3-(4-methoxyphenyl)- ( 70356-09-1) LOAEL (oral,rat,90 days) 1000 mg/kg body weight Animal rat, Guideline OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity Study in Rodents) NOAEL (oral,rat,90 days) 450 mg/kg body weight Animal rat, Guideline OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity Study in Rodents) NOAEL (dermal,rat/rabbit90 days) 360 mglkg body weight Animal rabbit, Guideline OECD Guideline 410 (Repeated Dose Dermal Toxicity 21/28-Day Study) Aspiration hazard Not classified Symptoms/effects after inhalation Prolonged inhalation may be hamful. Symptoms/effects after skin contact Prolonged or repeated contact may dry skin and cause iritation Symptoms/effects after eye contact Direct contact with eyes may cause temporary iritation. Causes eye irrtation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Symptoms/effects after ingestion May cause stomach distress, nausea or vomiting 12.1. To! ty Ecology - general See below for route-specific details. Ethyl alcohol ( 64-17-5) LC50 - Fish [1] 12— 16 ml (Exposure time 96 h - Species Oncorhynchus mykiss [static] Source EPA) EC50 - Crustacea [1] 9268 — 14221 mg/l (Exposure time 48 h - Species Daphnia magna) LC50 - Fish [2] 100 mg/l (Exposure time 96 h - Species Pimephales promelas [static] Source EPA) EC50 - Crustacea [2] mg/l (Exposure time 48 h - Species Daphnia magna [Static]) EC50 72h - Algae [1] 275 mg/l (Equivalent or similar to OECD 201, Chlorella vulgaris, Static system, Fresh water, Experimental value, Growth rate) NOEC (chronic) 9.6 mg/l Test organisms (species): Daphnia magna Duration: '9 d' 2-Propenoic acid, 2-cyano-3,3-diphenyl-, 2-ethylhexyl ester ( 6197-30-4) EC50 - Crustacea [1] > 0.023 mg/l Test organisms (species): Daphnia magna EC50 72h - Algae [1] > 220 mg/l Test organisms (species): Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) 10/3/2024 (Revision date) US-en 812 Decanoic acid, ester with 1,2,3-propanetriol octanoate ( 65381-09-1) LC50 - Fish [1] > 10000 mg/l (Exposure time: 96 h Species Brachydanio rerio Source IUCLID) EC50 - Crustacea [1] mg/l (Exposure time 48 h - Species Daphnia magna) EC50 72h - Algae [1] > 100 mg/l (Species: Desmodesmus subspicatus) EC50 96h - Algae [1] 50 mg/l (Species: Desmodesmus subspicatus) Hydrocarbons, C4, 1,3-butadiene-free, polymerized, triisobutylene fraction, hydrogenated ( 93685-81-5) EC50 - Crustacea [1] > 1.3 mg/l Test organisms (species): Daphnia magna LOEC (chronic) 0.029 mg/ Test organisms (species) Daphnia magna Duration '21 d" 2-Ethylhexyl salicylate ( 118-60-5) LC50 - Fish [1] 82 mg/l (Exposure time 96 h - Species Danio rerio [static] Source ECHA) EC50 - Crustacea [1] 10 mg/l Test organisms (species): Daphnia magna 1,3-Propanedione, 1-[4-(1,1-dimethylethyl)phel nyl]-3-(4-methoxyphenyl)- ( 70356-09-1) LC50 - Fish [1] > 0.03 mg/l Test organisms (species): Cyprinus carpio EC50 - Crustacea [1] > 0.03 mg/l Test organisms (species): Daphnia magna EC50 96h - Algae [1] > 0.055 mg/l Test organisms (species): Raphidocelis subcapitata (previous names: Pseudokirchneriella subcapitata, Selenastrum capricornutum) D-Limonene ( 5989-27-5) LC50 - Fish [1] 0.619 — 0.796 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through] Source: EPA) EC50 - Crustacea [1] 0.307 mg/l Test organisms (species): Daphnia magna LC50 - Fish [2] 35 mg/l (Exposure time: 96 h Species Oncorhynchus mykiss Source EPA) EC50 - Crustacea [2] 0.51 mg/l Test organisms (species): Daphnia magna EC50 72h - Algae [1] 0.32 mg/l Test organisms (species): Raphidocelis subcapitata (previous names Pseudokirchneriella subcapitata, Selenastrum capricornutum) EC50 72h - Algae [2] 0.214 mg/ Test organisms (species): Raphidocelis subcapitata (previous names: Pseudokirchneriella subcapitata, Selenastrum capricornutum) 12.2. Persistence and degradal Ethyl alcohol ( 64-17-5) Persistence and degradabilty Biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.8 0.967 g O./g substance Chemical oxygen demand (COD) 1.7 g Ozfg substance ThOD 2.1 g O,/g substance 2-Propenoic acid, 2-cyano-3,3-diphenyl-, 2-ethylhexyl ester ( 6197-30-4) Persistence and degradabilty Not readily biodegradable in water. 12.3. Bioaccumulative potential Ethyl alcohol ( 64-17-5) Partition coefficient n-octanolwater (Log Pow) -0.35 (at 24 °C (at pH 7.4) 10/3/2024 (Revision date) US-en 12 Ethyl alcohol ( 64-17-5) Bioaccumulative potential Not bioaccumulative. 2-Propenoic acid, 2-cyano-3,3-diphenyl-, 2-ethylhexyl ester ( 6197-30-4) BCF - Fish [1] (887 dimensionless (normalised lipid fraction) Partition coefficient n-octanol/water (Log Pow) 6.1 (at 23°C) Bioaccumulative potential Potential for bioaccumulation (500 < BCF < 5000) 2-Ethylhexyl salicylate ( 118-60-5) Partition coefficient n-octanol/water (Log Pow) > 6 (at 40 °C (at pH 7.71) 1,3-Propanedione, 1-[4-(1,1-dimethylethyl)phe nyl]-3-(4-methoxyphenyl)- ( 70356-09-1) Partition coefficient n-octanol/water (Log Pow) 6.1 (at 20 °C (at pH 6.9) D-Limonene ( 5989-27-5) Partition coefficient n-octanol/water (Log Pow) 4.38 (at 37 °C (at pH 7.2) 12.4. Mobi in soil Ethyl alcohol ( 64-17-5) Surface tension 2231 mNim (20°C, 100 %) Organic Carbon Normalized Adsorption Coefficient 0.2 (log Koc, Experimental value) (Log Koc) Ecology - soil Highly mobile in soil 2-Propenoic acid, 2-cyano-3,3- phenyl-, 2-ethylhexyl ester ( 6197-30-4) Surface tension No data available in the literature Organic Carbon Normalized Adsorption Coefficient 4.48 - 4.9 (log Koc, Calculated value) (Log Koc) Ecology - soil Low potential for mobility in soil 12.5. Other adverse effects No additional information available 13.1. Disposal methods Regional waste regulation Disposal must be done according to official regulations. Waste treatment methods Dispose of the material collected according to regulations. Sewage disposal recommendations Disposal must be done according to official regulations. Product/Packaging disposal recommendations Since emptied containers may retain product residue, follow label wamings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling, disposal or collection Additional information Flammable vapors may accumulate in the container. In accordance with DOT 10/3/2024 (Revision date) US-en 1012 DOT 14.1. UN number UN1170 14.2. Proper Shipping Name Ethanol solutions 14.3. Transport hazard class(es) 3(LTDQTY) I - v 14.4. Packing group 14.5. Environmental hazards Dangerous for the environment: No No supplementary information available 14.6. Special precautions for user DoT UN-No.(DOT) UN1170 DOT Special Provisions (49 CFR 172.102) 24 - Alcoholic beverages containing more than 70 percent alcohol by volume must be transported as materials in Packing Group I1. Alcoholic beverages containing more than 24 percent but not more than 70 percent alcohol by volume must be transported as materials in Packing Group lll 1B2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPaat 55 C (1.3 bar at 131 F) are authorized T4 - 2.65 178.274(d)(2) Normal 178.275(d)(3) TP1 - The maximum degree of filing must not exceed the degree of filling determined by the following: Degree of filing = 97/ 1+ a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and f is the temperature in degrees celsius of the liquid during filling DOT Packaging Exceptions (49 CFR 173.xxx) 4b;150 DOT Packaging Non Bulk (49 CFR 173.xxx) 202 DOT Packaging Bulk (49 CFR 173.xxx) 242 DOT Quantity Limitations Passenger aircraftrail (49 5L CFR17327) DOT Quantity Limitations Cargo aircraft only (49 60 L CFR175.75) DOT Vessel Stowage Location A - The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel. 14.7. Transport in bulk according to Annex Il of MARPOL 73/78 and the IBC Code Not applicable 10/3/2024 (Revision date) US-en 112 15.1. US Federal regulations All components of this product are present and listed as Active on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory, except for: Hydrocarbons, C4, 1,3-butadiene-free, polymerized, | CAS-No. 93685-81-5 3-7% triisobutylene fraction, hydrogenated Dibutyl maleate-isobornyl acrylate-vinyl acetate CAS-No. 136392-68-2 1-5% polymer This product or mixture is not known to contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR §372.38(a) subject to the reporting requirements of section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFRPart 372 15.2. International regulations No additional information available 15.3. US State regulations Califomia Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm Revision date 10/3/2024