ECOFOAM B-600 MP

SECTION 2: Hazards identification

Note Propane-1,2-diol, CAS No.: 25322-69-4 40-60% Acute Tox. 4, H302 propoxylated EC No.: 500-039-8 REACH: 01-2119457556-29- XXXX Index No.: 2-(2- CAS No.: 112-34-5 20-40% Eye Irrit. 2, H319 [1], butoxyethoxy)ethanol;die EC No.: 203-961-6 [3] thylene glycol monobutyl REACH: 01-2119475104-44- ether 0006 Index No.: 603-096-00-8 See full text of H-phrases in section 16. Occupational exposure limits are listed in section 8, if these are available.

Further information

1] European occupational exposure limit. [3] According to REACH, Annex XVII, the substance is subject to restrictions. 4.1. Description of first aid measures General information: In the case of accident: Contact a doctor or casualty department – take the label or this safety data sheet. Contact a doctor if in doubt about the injured person’s condition or if the symptoms persist. Never give an unconscious person water or other drink. Inhalation: Upon breathing difficulties or irritation of the respiratory tract: Bring the person into fresh air and stay with him/her. Skin contact: Upon irritation: rinse with water. In the event of continued irritation, seek medical assistance. Eye contact: If in eyes: Flush eyes immediately with plenty of water or isotonic water (20-30 °C) for at least 5 minutes and continue until irritation stops. Remove contact lenses. Make sure to flush under upper and lower eyelids. If irritation continues, contact a doctor. Continue flushing during transport. Ingestion: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Burns: Not applicable. 4.2. Most important symptoms and effects, both acute and delayed Irritation effects: This product contains substances, which may cause irritation upon exposure to skin, eyes or lungs. Exposure may result in an increased absorption potential of other hazardous substances at the area of exposure. 4.3. Indication of any immediate medical attention and special treatment needed If eye irritation persists: Get medical advice/attention. Information to medics Bring this safety data sheet or the label from this product. 5.1. Extinguishing media Suitable extinguishing media: Alcohol-resistant foam, carbon dioxide, powder, water mist. Unsuitable extinguishing media: Waterjets should not be used, since they can spread the fire. 5.2. Special hazards arising from the substance or mixture Fire will result in dense smoke. Exposure to combustion products may harm your health. Closed containers, which are exposed to fire, should be cooled with water. Do not allow fire- extinguishing water to enter the sewage system and nearby surface waters. If the product is exposed to high temperatures, e.g. in the event of fire, dangerous decomposition compounds are produced. These are: Carbon oxides (CO / CO2) 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective clothing to prevent contact. Upon direct exposure contact The National Poisons Information Service (dial 111, 24 h service) in order to obtain further advice. 6.1. Personal precautions, protective equipment and emergency procedures Contaminated areas may be slippery. 6.2. Environmental precautions Avoid discharge to lakes, streams, sewers, etc. Keep unauthorized persons away from the spill 6.3. Methods and material for containment and cleaning up Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Wherever possible cleaning should be performed with normal cleaning agents. Avoid use of solvents. 6.4. Reference to other sections See section 13 “Disposal considerations” on handling of waste. See section 8 "Exposure controls/personal protection" for protective measures. 7.1. Precautions for safe handling Smoking, drinking and consumption of food is not allowed in the work area. See section 8 "Exposure controls/personal protection" for information on personal protection. 7.2. Conditions for safe storage, including any incompatibilities Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Recommended storage material: Keep only in original packaging. Storage conditions: Dry, cool and well ventilated 0 - 40°C Protect from tempratures 65 °C, above this limit irrversible changes take place. Incompatible materials: Acids Bases Reactions with oxidising agents. Reactions with reducing agents. Reactions with amines. Reactions with alkalies. mercaptanes (thio alcohols) 7.3. Specific end use(s) This product should only be used for applications quoted in section 1.2. 8.1. Control parameters 2-(2-butoxyethoxy)ethanol;diethylene glycol monobutyl ether Long term exposure limit (8 hours) (ppm): 10 Long term exposure limit (8 hours) (mg/m³): 67,5 Short term exposure limit (15 minutes) (ppm): 15 Short term exposure limit (15 minutes) (mg/m³): 101,2 ΟΡΙΑΚΕΣ ΤΙΜΕΣ ΕΚΘΕΣΗΣ ΧΗΜΙΚΩΝ ΠΑΡΑΓΟΝΤΩΝ & ΔΕΙΚΤΕΣ ΒΙΟΛΟΓΙΚΗΣ ΕΚΘΕΣΗΣ ΣΕ ΧΗΜΙΚΟΥΣ ΠΑΡΑΓΟΝΤΕΣ 2019 (Ελληνική νομοθεσία). DNEL 2-(2-butoxyethoxy)ethanol;diethylene glycol monobutyl ether Duration: Other physical and chemical No data available. parameters: Oxidizing properties: No relevant or available data due to the nature of the product. 10.1. Reactivity No data available. 10.2. Chemical stability The product is stable under the conditions, noted in section 7 “Handling and storage”. 10.3. Possibility of hazardous reactions None known. 10.4. Conditions to avoid Moisture 10.5. Incompatible materials Acids Bases Reactions with oxidising agents. Reactions with reducing agents. Reactions with amines. Reactions with alkalies. mercaptanes (thio alcohols) 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Product/substance Propane-1,2-diol, propoxylated Test method: OECD 401 Species: Rat Route of exposure: Oral Test: LD50 Result: >300-<2000 mg/kg Product/substance Propane-1,2-diol, propoxylated Species: Rat Route of exposure: Inhalation Test: LC50 Result: Not conclusive Product/substance Propane-1,2-diol, propoxylated Species: Rat Route of exposure: Dermal Test: LD50 Result: >2.000 mg/kg Harmful if swallowed. Skin corrosion/irritation Product/substance Propane-1,2-diol, propoxylated Result: No adverse effect observed (Not irritating) Serious eye damage/irritation Product/substance Propane-1,2-diol, propoxylated Species: Rabbit Result: No adverse effect observed (Not irritating) Causes serious eye irritation. Respiratory sensitisation Based on available data, the classification criteria are not met. Skin sensitisation Product/substance Propane-1,2-diol, propoxylated Result: No adverse effect observed (not sensitising) Germ cell mutagenicity Product/substance Propane-1,2-diol, propoxylated Conclusion: No adverse effect observed Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. 11.2. Information on other hazards Long term effects Irritation effects: This product contains substances, which may cause irritation upon exposure to skin, eyes or lungs. Exposure may result in an increased absorption potential of other hazardous substances at the area of exposure. Endocrine disrupting properties This mixture/product does not contain any substances known to have hormone-disrupting properties in relation to health. Other information None known. 12.1. Toxicity No data available. 12.2. Persistence and degradability Based on available data, the classification criteria are not met. 12.3. Bioaccumulative potential Based on available data, the classification criteria are not met. 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification. 12.6. Endocrine disrupting properties This mixture/product does not contain any substances considered to have endocrine-disrupting properties in relation to the environment. 12.7. Other adverse effects None known. 13.1. Waste treatment methods Product is covered by the regulations on hazardous waste. HP 4 - Irritant (skin irritation and eye damage) HP 6 - Acute toxicity Dispose of contents/container to an approved waste disposal plant. Commission Regulation (EU) No 1357/2014 of 18 December 2014 on waste. EWC code: Not applicable. Contaminated packing Packaging containing residues of the product must be disposed of similarly to the product. 14.1 14.2 14.3 14.4 14.5 Other UN / ID UN proper shipping name Hazard class(es) PG* Env** informat ion: ADR - IMDG - 14.1 14.2 14.3 14.4 14.5 Other UN / ID UN proper shipping name Hazard class(es) PG* Env** informat ion: IATA - * Packing group ** Environmental hazards

Principle Routes of Exposure

DNEL: Long term – Local effects - Workers Inhalation 67.5 mg/m³ Short term – Local effects - Workers Inhalation 101.2 mg/m³ Long term – Systemic effects - General population Oral 6.25 mg/kg bw/day Propane-1,2-diol, propoxylated Duration: DNEL: Long term – Systemic effects - General population Dermal 8.3 mg/kg bw/day Long term – Systemic effects - Workers Dermal 13.9 mg/kg bw/day Long term – Local effects - General population Inhalation 10 mg/m³ Long term – Local effects - Workers Inhalation 10 mg/m³ Long term – Systemic effects - General population Inhalation 29 mg/m³ Long term – Systemic effects - Workers Inhalation 98 mg/m³ Long term – Systemic effects - General population Oral 8.3 mg/kg bw/day PNEC 2-(2-butoxyethoxy)ethanol;diethylene glycol monobutyl ether Duration of Exposure: PNEC: Freshwater 1.1 mg/L Freshwater sediment 4.4 mg/kg Intermittent release (freshwater) 11 mg/L Marine water 110 µg/L Marine water sediment 440 µg/kg Predators 56 mg/kg Soil 320 µg/kg Propane-1,2-diol, propoxylated Duration of Exposure: PNEC: Freshwater 100-200 µg/L Freshwater sediment 419-765 µg/kg Intermittent release (freshwater) 1-1.06 mg/L Marine water 10-20 µg/L Marine water sediment 41.9-76.5 µg/kg Sewage treatment plant 100 mg/L Soil 30.6-109 µg/kg 8.2. Exposure controls Apply general control to prevent unnecessary exposure General recommendations: Smoking, drinking and consumption of food is not allowed in the work area. Exposure scenarios: There are no exposure scenarios implemented for this product. Exposure limits: Occupational exposure limits have not been defined for the substances in this product. Appropriate technical measures: Apply standard precautions during use of the product. Avoid inhalation of vapours. Hygiene measures: In between use of the product and at the end of the working day all exposed areas of the body must be washed thoroughly. Pay special attention to hands, forearms and face. Measures to avoid environmental No specific requirements. exposure: Individual protection measures, such as personal protective equipment Generally: Use only CE marked protective equipment. Respiratory Equipment: Type Class Colour Standards S/SL P2 White EN149 Skin protection: Recommended Type/Category Standards Wear appropriate protection clothing, e.g. coveralls in polypropylene or working clothes in cotton or polyester. Hand protection: Material Glove thickness Breakthrough time Standards (mm) (min.) Nitrile 0.4 > 30 EN374-2, EN374-3, EN388 Butyl 0,3 > 30 EN374-2, EN374-3, EN388 Eye protection: Type Standards Face shield EN166 9.1. Information on basic physical and chemical properties Physical state: Liquid Colour: Transparent Odour / Odour threshold: No relevant or available data due to the nature of the product. pH: 5,5 ±1 Density (g/cm³): Kinematic viscosity: No relevant or available data due to the nature of the product. Particle characteristics: Does not apply to liquids. Phase changes Melting point/Freezing point (°C): No relevant or available data due to the nature of the product. Softening point/range (°C): Does not apply to liquids. Boiling point (°C): No relevant or available data due to the nature of the product. Vapour pressure: No relevant or available data due to the nature of the product. Relative vapour density: No relevant or available data due to the nature of the product. Decomposition temperature (°C): No relevant or available data due to the nature of the product. Data on fire and explosion hazards Flash point (°C): Not applicable - estimated > 140 °C Flammability (°C): No relevant or available data due to the nature of the product. Auto-ignition temperature (°C): No relevant or available data due to the nature of the product. Lower and upper explosion limit (% No relevant or available data due to the nature of the v/v): product. Solubility Solubility in water: No relevant or available data due to the nature of the product. n-octanol/water coefficient (LogKow): No relevant or available data due to the nature of the product. Solubility in fat (g/L): No relevant or available data due to the nature of the product.