ZYCRETE PMC (PART B)

Hazard statements (CLP)

H315+H320, H317, H332, H334, H335

Code

Statements

H315+H320

Cause skin and eye irritation

SECTION 2: Hazards identification

29 CFR 1910.1200) OSHA / HCS STATUS: THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).

2.1 Classification of the substance or mixture

SKIN CORROSION/IRRITATION (CATEGORY 2) SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE; RESPIRATORY TRACT IRRITATION (CATEGORY 3) ACUTE INHALATION (VAPOR AND MIST)TOXICITY (CATEGORY 4) RESPIRATORY SENSITIZATION ( CATEGORY 1) EYE IRRITANT (CATEGORY 2B) SKIN SENSITIZATION (CATEGORY 1)

Ingredient(s) with unknown acute toxicity

100%

Hazard pictograms

EXCLAMATION MARK (IRRITANT) HEALTH HAZARD (HEALTH HAZARD)

Signal word

DANGER!

Hazard statements

H315 + H320: CAUSES SKIN AND EYE IRRITATION H317: MAY CAUSE AN ALLERGIC SKIN REACTION H332: HARMFUL IF INHALED H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED H335: MAY CAUSE RESPIRATORY IRRITATION

Prevention

P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY. P264: WASH SKIN THOROUGHLY AFTER HANDLING. 2 1 1 P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION. THE TYPE OF RESPIRATORY SELECTION MUST COMPLY WITH THE REQUIREMENTS SET FORTH IN OSHA'S RESPIRATORY PROTECTION STANDARD (29CFR 1910.134) OR REGIONAL STANDARDS.

Response

P302 + P350 IF ON SKIN GENTLY WASH WITH PLENTY OF SOAP AND WATER P304 + P341 IF INHALED IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. P305 + P351 + P338 IF IN EYES RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL. P333 + P313 IF SKIN IRRITATION OR RASH OCCURS GET MEDICAL ADVICE/ATTENTION P337 + P313 IF EYE IRRITATION PERSISTS GET MEDICAL ADVICE/ATTENTION P342 + P311 IF EXPERIENCING RESPIRATORY SYMPTOMS CALL A POISON CENTER/DOCTOR/ P362 + P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.

Storage

P405: STORE LOCKED UP.

Disposal

P501: DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS.

Supplemental label elements

WARNING! INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO ISOCYANATES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST.

2.3 Other hazards

A HISTORY OF ECZEMA OR RESPIRATORY ALLERGIES SUCH AS HAY FEVER, ARE POSSIBLE REASONS FOR EXCLUSION FROM ISOCYANATE WORK AREAS. APPLICANTS WITH A HISTORY OF PRIOR ISOCYANATE SENSITIZATION SHOULD BE EXCLUDED FROM FURTHER WORK WITH ISOCYANATES. A COMPREHENSIVE ANNUAL MEDICAL SURVEILLANCE PROGRAM SHOULD BE INSTITUTED FOR ALL EMPLOYEES WHO ARE POTENTIALLY EXPOSED TO DIISOCYANATES. ONCE A WORKER HAS BEEN DIAGNOSED AS SENSITIZED TO ANY ISOCYANATE, NO FURTHER EXPOSURE SHOULD BE PERMITTED. 2 1 1