Halox 520 Herbicide

Hazard statements (CLP)

H227, H302, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg (L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H227: Combustible liquid. H302: Harmful if swallowed. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

WARNING Flammable liquids Category 4 Acute Toxicity Oral Category 4 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam.

Storage

P410: Protect from sunlight. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Dark yellow water-thin liquid Odour: Characteristic odour.

Health hazards

For Haloxyfop-methyl the oral LD50 is 393 mg/kg for rats. The LD50 is greater than 5,000 mg/kg for rabbits whose skin is exposed to Haloxyfop-methyl. Haloxyfop-ethoxyethyl has an oral LD50 of 518-531 mg/kg for rats. The dermal LD50 is greater than 2000 mg/kg for rats and greater than 5,000 mg/kg for rabbits. Both Haloxyfop forms are non-irritating to skin and do not cause skin sensitization. They are mild eye irritants. The symptoms of toxicity in rats are reduced food intake and reduced food consumption. They may also cause liver and kidney damage. Harmful if swallowed.