eChem Grazmore 400 Herbicide

eChem Australia Pty Ltd

Revision date : 2022-07-02

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GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

111-90-0

Name of the chemical

2-(2-Ethoxyethoxy)ethanol Diethylene Glycol Monoethyl Ether (DEGEE)

Concentration

N/A

General Information

Revision date

2022-07-02

Product name

eChem Grazmore 400 Herbicide

Product name

eChem Grazmore 400 Herbicide

Identification on the label/Trade name

eChem Grazmore 400 Herbicide 83435

1.2.1 Relevant identified uses

Agricultural herbicide for use as described on the product label

Icons in SDS

GHS07 GHS08 GHS09

Company Information

company name

eChem Australia Pty Ltd

GHS Information

Signal word

WARNING

Hazard Codes

Hazard statements (CLP)

H302, H315, H317, H320, H332, H335, H373, H410

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

SECTION 2: Hazards identification

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

WARNING Acute Toxicity Oral Category 4 Skin Irritation Category 2 Skin sensitisation Category 1 Eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ Toxicity – Repeated Exposure Category 2 Hazardous to the aquatic environment, long term (chronic) – category 1

Hazard statements

H302: Harmful if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H373: May cause damage to kidneys and liver through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

Prevention

P102: Keep out of reach of children. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P370+P378: Not combustible. Use extinguishing media suited to burning materials.

Storage

P405: Store locked up. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Clear brown liquid. Odour: No data re odour.

Health hazards

The oral LD50 of Triclopyr in rats ranges from 630 to 729 mg/kg , and is over 2000 mg/kg for various amine and ester formulated products. The dermal LD50 for the technical material in rabbits is greater than 2000 mg/kg, and greater than 4000 mg/kg for the formulations. Inhalation of Triclopyr did not affect rats, but inhalation of some of the formulations did cause nasal irritation. These data indicate Triclopyr is harmful. This product is irritating to eyes and skin, harmful if swallowed, skin sensitiser, may cause damage to kidney and liver through repeated/prolonged exposure.

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