eChem Bifenthrin 100 EC lnsecticide

Hazard statements (CLP)

H301, H304, H315, H317, H332, H335, H351, H372, H410

Code

Statements

H301

Toxic if swallowed

Hazard statements

This product is classified as: Xi, lrritating. T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500k9(L) or less; or lBCs (refer to SP AUQ1). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H301: Toxic if swallowed. H304: May be fatal if swallowed and enters airuvays. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H31B: Causes serious eye damage. H332: Harmful if inhaled. H335: May cause respiratory irritation. H351: Suspected ofcausing cancer. H372: Causes damage to the nervous system through prolonged or repeated exposure H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

SO

ADG classification

Class 9 Miscellaneous Dangerous Goods UN NumbET: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Signal word

DANGER Acute Toxicity Oral Category 3

Aspiration hazard

Category 1 Skin Corrosion Category 2 Skin Sensitisation Category 1 Serious eye damage Category 1 Acute Toxicity lnhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Carcinogenicity Category 2 Specific Target Organ toxicity - repeated exposure Category 1 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P?44' \A/ash cnnlantpd aroaq thnrnr rnhlrr aftcr handlinn Product Name: eChem Bifenthrin 100 EC Insecticide Page: 2of 7 This version issued: March, 2019 P270: Do not eat, drink or smoke when using this product. P271:Use only outdoors or in a wellventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye orface protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P310 lF SWALLOWED lmmediately call a POISON CENTRE or doctor P301+P330+P331 lF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 lF ON SKIN Wash with plenty of soap and water' P304+P340 lF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 lF lN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 lf skin irritation or rash occurs Get medical advice' P337+P313 lf eye irritation persists Get medical advice P39'1 : Collect spillage. P370+P378: ln case of fire, use carbon dioxide, dry chemical, foam. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P41 0: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container' P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Eme Overview Physical Description & Golour: Clear straw to golden yellow liquid Odour: Aromatic hydrocarbon liquid

Health hazards

Bifenthrin is harmfulto mammals when ingested. Large doses may cause incoordination, tremor, salivation, vomiting, diarrhoea, and irritability to sound and touch. LD5e for Bifenthrin is about 54 mg/kg in female rats and 70 mg/kg in male rats. The LD5e for rabbits whose skin is exposed to Bifenthrin is greater than 2,000 mg/kg. Bifenthrin does not sensitize the skin of guinea pigs. Although it does not cause inflammation or irritation on truman skin, it can cause a tingling sensation which lasts about 12 hours. lt is virtually non-irritating to rabbit eyes. May cause serious damage to health by prolonged exposure, toxic if swallowed, limited evidence of a carcinogenic effect, may cause serious damage to eyes, irritating to respiratory system and skin, harmful if inhaled, possible skin sensitiser, if aspirated, may cause lung damage.