IB2 Epoxy Infusion Bio Resin

Hazard statements (CLP)

H302, H302+H332, H314, H317, H318, H332, H335, H412

Code

Statements

H302

Harmful if swallowed

Hazard pictograms

GHS05 GHS07

Signal word

DANGER

Product definition

EC 239-556-6 METHYLPENTANE DIAMINE EC 216-032-5 M-PHENYLENEBIS(METHYLAMINE) EC 500-105-6 PROPYLIDYNETRIMETHANOL, PROPOXYLATED, REACTION PRODUCTS WITH AMMONIA

Hazard statements

H302 + H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. see section 16) [1] Substance for which maximum workplace exposure limits are available. As a general rule, in case of doubt or if symptoms persist, always call a doctor. NEVER induce swallowing by an unconscious person. 4.1. description of first aid measures In the event of exposure by inhalation In the event of massive inhalation, remove the person exposed to fresh air. Keep warm and at rest. If the person is unconscious, place in recovery position. Notify a doctor in all events, to ascertain whether observation and supportive hospital care will be necessary. If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor. Do not proceed with mouth-to-mouth or mouth-to-nose resuscitation.Use the appropriate equipment. If breathing is irregular or stopped, that qualified personnel provide artificial respiration and call a doctor. In the event of splashes or contact with eyes Wash thoroughly with fresh, clean water for 15 minutes holding the eyelids open. Regardless of the initial state, refer the patient to an ophthalmologist and show him the label. Flush with large amounts of water. Remove contact lenses if the victim is. Continue to rinse. Seek medical attention if symptoms persist. In the event of splashes or contact with skin Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. Remove any soiled or splashed clothing immediately. Watch out for any remaining product between skin and clothing, watches, shoes, etc. In the event of an allergic reaction, seek medical attention. If the contaminated aera is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital. In the event of swallowing Do not give the patient anything orally. In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water, administer activated medical charcoal and consult a doctor. Seek medical attention immediately, showing the label. If swallowed accidentally, call a doctor to ascertain whether observation and hospital care will be necessary. Show the label. 4.2. Most important symptoms and effects, both acute and delayed No data available. 4.3. Indication of any immediate medical attention and special treatment needed Information for the doctor In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to remain under medical supervision for 48 hours. Contact a specialist for treatment poisoning if large quantities have been ingested or inhaled. Non-flammable. 5.1. Extinguishing media Suitable methods of extinction In the event of a fire, use - sprayed water or water mist Unsuitable methods of extinction In the event of a fire, do not use - water jet 5.2. Special hazards arising from the substance or mixture A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health. Do not breathe in smoke. In the event of a fire, the following may be formed - carbon monoxide (CO) - carbon dioxide (CO2) - nitrogen oxide (NO) - nitrogen dioxide (NO2) 5.3. Advice for firefighters Firefighters should wear suitable protective clothing and a respirator mask with self- full operated in positive pressure mode. Wear conform with the European standard EN 469. 6.1. Personal precautions, protective equipment and emergency procedures Consult the safety measures listed under headings 7 and 8. For non first aid worker Avoid inhaling the vapors. Avoid any contact with the skin and eyes. If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety apparatus. For first aid worker First aid workers will be equipped with suitable personal protective equipment (See section 8). 6.2. Environmental precautions Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal. Prevent any material from entering drains or waterways. 6.3. Methods and material for containment and cleaning up Neutralise with an acidic decontaminant. If the ground is contaminated, once the product has been recovered by sponging with an inert and non-combustible absorbent material, wash the contaminated area in plenty of water. Clean preferably with a detergent, do not use solvents. 6.4. Reference to other sections No data available. Requirements relating to storage premises apply to all facilities where the mixture is handled. Individuals with a history of skin sensitisation should not, under any circumstance, handle this mixture. 7.1. Precautions for safe handling Always wash hands after handling. Remove and wash contaminated clothing before re-using. Emergency showers and eye wash stations will be required in facilities where the mixture is handled constantly. Fire prevention Handle in well-ventilated areas. Prevent access by unauthorised personnel. Recommended equipment and procedures For personal protection, see section 8. Observe precautions stated on label and also industrial safety regulations. Avoid inhaling vapors. Carry out any industrial operation which may give rise to this in a sealed apparatus. Provide vapor extraction at the emission source and also general ventilation of the premises. Also provide breathing apparatus for certain short tasks of an exceptional nature and for emergency interventions. In all cases, recover emissions at source. Prohibited equipment and procedures No smoking, eating or drinking in areas where the mixture is used. 7.2. Conditions for safe storage, including any incompatibilities No data available. Storage Keep out of reach of children. Keep the container tightly closed in a dry, well-ventilated place. Keep away from food and drink, including those for animals. Store in original container protected from direct sunlight in a dry, cool and well ventilated area away from heat sources.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. Disposal P501 Dispose of contents/container to hazardous waste.

Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ...

Response

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/...

Storage

P405 Store locked up.

2.3 Other hazards

The mixture does not contain substances classified as 'Substances of Very High Concern' (SVHC) >= 0.1% published by the European CHemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table

2.1 Classification of the substance or mixture

Serious eye damage, Category 1 (Eye Dam. 1, H318). Skin sensitisation, Category 1 (Skin Sens. 1, H317). Specific target organ toxicity (single exposure), Category 3 (STOT SE 3, H335). Hazardous to the aquatic environment - Chronic hazard, Category 3 (Aquatic Chronic 3, H412). This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site. 2.2. Label elements In compliance with EC regulation No. 1272/2008 and its amendments. Hazard pictograms