Ballpoint Pen Ink - Red

Hazard statements (CLP)

H315, H319, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labelling

Hazard pictograms

GHS07 (Contd. on page 2) IN Trade name: Ballpoint Pen Ink - Red (Contd. of page 3) · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. Wear fully protective suit. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Observe all warnings and precautions listed for the product. Use in accordance with good manufacturing and industrial hygiene practices. Use product in a properly ventilated work area. Do not eat, drink or smoke while handling product. Enclosure or extractor facilities are required. Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Ensure good ventilation/exhaustion at the workplace. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. · 7.2 Conditions for safe storage, including any incompatibilities

Storage

Requirements to be met by storerooms and receptacles: Store in tightly closed containers. · Information about storage in one common storage facility: Store in cool and dry area. Keep away from direct sources of heat. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) Use as inks for sketch pens, fine liners and all kinds of writing instruments. IN (Contd. on page 5) Trade name: Ballpoint Pen Ink - Red (Contd. of page 4) SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles (Contd. on page 6) IN Trade name: Ballpoint Pen Ink - Red (Contd. of page 5) · Body protection: Protective work clothing SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information Appearance: Liquid · Form: Liquid · Colour: Red · Odour: Characteristic · Odour threshold: Not applicable · pH-value: Not applicable · Change in condition Melting point/freezing point: Undetermined. Initial boiling point and boiling range: 205 °C · Flash point: >101 °C · Flammability (solid, gas): Not applicable · Ignition temperature: 360 °C · Auto-ignition temperature: Product is not self-igniting. · Explosive properties: Product does not present an explosion hazard. · Explosion limits: Lower: Not applicable Upper: Not applicable · Vapour pressure at 20 °C: 0.1 hPa · Density: Not determined. · Vapour density Not applicable · Evaporation rate Not applicable · Solubility in / Miscibility with Water: Not miscible or difficult to mix. · Partition coefficient: n-octanol/water: Not applicable · Viscosity: Dynamic: Not applicable Kinematic: Not applicable · Solvent content: VOC (EC) 55.00 % (Contd. on page 7) IN Trade name: Ballpoint Pen Ink - Red (Contd. of page 6)

Further information

No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability Stable under recommended storage conditions. · Thermal decomposition / conditions to be avoided: Keep away from heat. · 10.3 Possibility of hazardous reactions No dangerous reaction know. · 10.4 Conditions to avoid Incompatible materials · 10.5 Incompatible materials: Strong oxidising agent. · 10.6 Hazardous decomposition products: Carbon oxides.

TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values relevant for classification: 122-99-6 2-phenoxyethanol Oral LD50 1850 mg/kg bw (rat(Wistar)male/female) Dermal LD50 14391 mg/kg bw (Rat (male/female)) 100-51-6 benzyl alcohol Oral LD50 1620 mg/kg bw (rat(Wistar)male) Dermal LD50 < 5000 mg/kg bw (Guinea pig) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. CAS No.122-99-6 TYPE OF TEST : Standard Draize test

Principle Routes of Exposure

Administration into the eye SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 250 ug/24H REACTION SEVERITY : Severe · Respiratory or skin sensitisation Not sensitising · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity No data available. · Carcinogenicity No data available. · Reproductive toxicity No data available. · STOT-single exposure No data available. · STOT-repeated exposure No data available. (Contd. on page 8) IN Trade name: Ballpoint Pen Ink - Red (Contd. of page 7)

Aspiration hazard

No data available SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: Quantitative data on the ecological effect of this product are not available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish · Additional ecological information: · General notes: Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Must not be disposed together with household garbage. Do not allow product to reach sewage system. · Waste disposal key: 08 03: wastes from Manufacture, Formulation, Supply and Use (MFSU) of printing inks · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · ADR, IMDG, IATA Void (Contd. on page 9) IN Trade name: Ballpoint Pen Ink - Red (Contd. of page 8) · 14.2 UN proper shipping name · ADR, IMDG, IATA Not applicable · 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class Not applicable · 14.4 Packing group · ADR, IMDG, IATA Not applicable · 14.5 Environmental hazards: Not applicable. · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation": Not applicable SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 · Signal word Warning · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs: Get medical advice/attention. (Contd. on page 10) IN Trade name: Ballpoint Pen Ink - Red (Contd. of page 9) P337+P313 If eye irritation persists: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/ International regulations. · Directive 2012/18/EU · Named dangerous substances - ANNEX I Substance not listed · National regulations: · Other regulations, limitations and prohibitive regulations User to follow national laws and regulations. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. · Department issuing SDS: Product safety department. · Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organisation ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO) ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances (Contd. on page 11) IN Trade name: Ballpoint Pen Ink - Red (Contd. of page 10) ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Muta. 2: Germ cell mutagenicity – Category 2 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 · Sources REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 ECHA Registered dossier for CAS No. 100-51-6 ECHA Registered dossier for CAS No. 122-99-6 RTECS for CAS No. 122-99-6 · * Data compared to the previous version altered. Section 1: Identification of the substance/mixture and of the company/undertaking