Ballpoint Pen Ink - Green

Hazard statements (CLP)

H302, H312, H314, H315, H317, H319, H332, H400, H410, H412

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labelling

Hazard pictograms

GHS07 Trade name: Ballpoint Pen Ink - Green (Contd. of page 2) SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Call for a doctor immediately. Drink plenty of water and provide fresh air. Call for a doctor immediately. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · Information for doctor: Treat symptomatically and supportively. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, dry chemical powder, water spray, or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Not known. · 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. Carbon oxides · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear suitable protective clothing and gloves. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Trade name: Ballpoint Pen Ink - Green (Contd. of page 3) · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Keep in suitable, closed containers for disposal. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. · 7.2 Conditions for safe storage, including any incompatibilities GHS07

Storage

Requirements to be met by storerooms and receptacles: Store in a cool, dry, well-ventilated area. · Information about storage in one common storage facility: Store away from incompatible materials. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

Additional information

The lists valid during the making were used as basis · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Trade name: Ballpoint Pen Ink - Green (Contd. of page 4) · Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles · Body protection: Protective work clothing SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information Appearance: Liquid · Form: Liquid · Colour: Green · Odour: Characteristic · Odour threshold: Not applicable · pH-value: Not applicable · Change in condition Melting point/freezing point: Undetermined. Initial boiling point and boiling range: 205 °C Trade name: Ballpoint Pen Ink - Green (Contd. of page 5) · Flash point: >101 °C · Flammability (solid, gas): Not applicable · Ignition temperature: 435 °C · Auto-ignition temperature: Product is not self-igniting. · Explosive properties: Product does not present an explosion hazard. · Explosion limits: Lower: 1.3 Vol % Upper: 13.0 Vol % · Vapour pressure at 20 °C: 0.1 hPa · Density: Not determined. · Evaporation rate Not applicable · Solubility in / Miscibility with Water: Not miscible or difficult to mix. · Partition coefficient: n-octanol/water: Not applicable · Viscosity: Dynamic: Not applicable Kinematic: Not applicable · Solvent content: Organic solvents: 55.0 % VOC (EC) 55.00 % Solids content: 45.0 %

Further information

No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability Stable under recommended storage conditions. · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Hazardous polymerisation will not occur. · 10.4 Conditions to avoid Extreme heat · 10.5 Incompatible materials: Incompatible with oxidizing materials. · 10.6 Hazardous decomposition products: May produce carbon mono-oxide and/or carbon dioxide. IN (Contd. on page 7) Trade name: Ballpoint Pen Ink - Green (Contd. of page 6) This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. (Contd. on page 10) IN Trade name: Ballpoint Pen Ink - Green (Contd. of page 9) H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. · Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organisation ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO) ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent

TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values relevant for classification: 122-99-6 2-phenoxyethanol Oral LD50 1260 mg/kg (rat) Dermal LD50 5000 mg/kg (rabbit) 100-51-6 benzyl alcohol Oral LD50 1230 mg/kg (rat) Dermal LD50 2000 mg/kg (rabbit) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. CAS: 122-99-6 The substance was found to cause irreversible effects to rabbit eye in a study performed as per OECD guideline no. 405. · Respiratory or skin sensitisation May cause an allergic skin reaction. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity No data available. · Carcinogenicity No data available. · Reproductive toxicity No data available. · STOT-single exposure No data available. · STOT-repeated exposure No data available.

Aspiration hazard

No data available

ECOLOGICAL INFORMATION

12.1 Toxicity · Aquatic toxicity: Quantitative data on the ecological effect of this product are not available. · 12.2 Persistence and degradability CAS number: 122-99-6 2-phenoxyethanol was found to be readily biodegradable. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Must not reach sewage water or drainage ditch undiluted or unneutralised. (Contd. on page 8) IN Trade name: Ballpoint Pen Ink - Green (Contd. of page 7) Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

PBT Substances

Not applicable Persistent, Bioaccumulative and Toxic

vPvB Substances

Not applicable very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 · Sources

Other hazards

No further relevant information available SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Dispose of waste material according to local, state and federal regulations. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information

UN Number

ADR, IMDG, IATA Not applicable · 14.2 UN proper shipping name · ADR, IMDG, IATA Not applicable · 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class Not applicable · 14.4 Packing group · ADR, IMDG, IATA Not applicable

Environmental hazards

Marine pollutant: Not applicable · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation": Not applicable IN (Contd. on page 9) Trade name: Ballpoint Pen Ink - Green (Contd. of page 8) SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Labelling

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/ International regulations.