Ballpoint Pen Ink - Black

Hazard statements (CLP)

H302, H312, H314, H315, H317, H318, H319, H332, H335, H410, H411

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labelling

Hazard pictograms

GHS07 GHS09 GHS07 GHS09

Hazardous Ingredients

2-phenoxyethanol [4-[p,p'-bis(dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium m-[[p-anilinophenyl]azo]benzenesulphonate benzyl alcohol Phosphoric acid, 2-ethylhexyl ester 2-phenoxyethanol [4-[p,p'-bis(dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium m-[[p-anilinophenyl]azo]benzenesulphonate benzyl alcohol Phosphoric acid, 2-ethylhexyl ester

Hazard statements

H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects. (Contd. on page 12) IN Trade name: Ballpoint Pen Ink - Black (Contd. of page 11)

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves / eye protection / face protection. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ International regulations. P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves / eye protection / face protection. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ International regulations.

Additional information

EUH208 Contains [4-[p,p'-bis(dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene] dimethylammonium m-[[p-anilinophenyl]azo]benzenesulphonate. May produce an allergic reaction.

PBT Substances

Not applicable Not applicable Persistent, Bioaccumulative and Toxic

vPvB Substances

Not applicable IN (Contd. on page 3) Trade name: Ballpoint Pen Ink - Black (Contd. of page 3) · Information for doctor: Treat symptomatically and supportively. · 4.3 Indication of any immediate medical attention and special treatment needed Immediate medical attention is required. Treat symptomatically SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Water spray Alcohol resistant foam Fire-extinguishing powder Carbon dioxide · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Carbon dioxide (CO2) Carbon monoxide (CO) · 5.3 Advice for firefighters · Protective equipment: Wear suitable protective clothing to avoid contact with skin. Wear self-contained respiratory protective device. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Avoid breathing vapors, mist or gas. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Do not allow product to reach sewage system or any water course. · 6.3 Methods and material for containment and cleaning up: A b s o r b w i t h l i q u i d - b i n d i n g m a t e r i a l ( s a n d , d i a t o m i t e , a c i d b i n d e r s , u n i v e r s a l binders, sawdust). Dispose contaminated material as waste according to item 13. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. IN (Contd. on page 5) Trade name: Ballpoint Pen Ink - Black (Contd. of page 4) SECTION 7: Handling and storage · 7.1 Precautions for safe handling Avoid contact with eyes and skin. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. · 7.2 Conditions for safe storage, including any incompatibilities Not applicable very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity - oral – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1B: Skin sensitisation – Category 1B STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 · Sources

Storage

Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one common storage facility: Store away from oxidising agents. · Further information about storage conditions: Store under inert gas. · 7.3 Specific end use(s) Used as inks for sketch pens, fine liners and all kind of writing instruments SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Do not inhale dust / smoke / mist. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Respiratory protection: Half or full face piece respirator, self-contained breathing apparatus (SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. · Protection of hands: Protective gloves (Contd. on page 6) IN Trade name: Ballpoint Pen Ink - Black (Contd. of page 5) The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles · Body protection: Protective work clothing SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information Appearance: Liquid · Form: Liquid · Colour: Black · Odour: Characteristic · Odour threshold: Not applicable · pH-value: Not applicable · Change in condition Melting point/freezing point: Undetermined. Initial boiling point and boiling range: 205 °C · Flash point: >101 °C · Flammability (solid, gas): Not applicable · Ignition temperature: 435 °C · Auto-ignition temperature: Product is not self-igniting. · Explosive properties: Product does not present an explosion hazard. (Contd. on page 7) IN Trade name: Ballpoint Pen Ink - Black (Contd. of page 6) · Explosion limits: Lower: 1.3 Vol % Upper: 13.0 Vol % · Vapour pressure at 20 °C: 0.1 hPa · Density: Not determined. · Vapour density Not applicable · Evaporation rate Not applicable · Solubility in / Miscibility with Water: Not miscible or difficult to mix. · Partition coefficient: n-octanol/water: Not applicable · Viscosity: Dynamic: Not applicable Kinematic: Not applicable · Solvent content: Organic solvents: 40.0 % VOC (EC) 46.00 % Solids content: <60.0 %

Further information

No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability Stable under recommended storage conditions. · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts violently with oxidising agents. · 10.4 Conditions to avoid Extreme heat · 10.5 Incompatible materials: Avoid contact with strong oxidizing agents. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. · Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) (Contd. on page 13) IN Trade name: Ballpoint Pen Ink - Black (Contd. of page 12) ICAO: International Civil Aviation Organisation ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO) ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent

TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects · Acute toxicity Harmful if swallowed. · LD/LC50 values relevant for classification: 122-99-6 2-phenoxyethanol Oral LD50 1850 mg/kg bw (rat(Wistar)male/female) (Contd. on page 8) IN Trade name: Ballpoint Pen Ink - Black (Contd. of page 7) Dermal LD50 14391 mg/kg bw (rat) Inhalative LC50 > 1000 mg/m³ air (rat(Wistar)male/female) 100-51-6 benzyl alcohol Oral LD50 1620 mg/kg bw (rat(Wistar)male) Dermal LD50 >2000 mg/kg bw (rabbit) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye irritation. Eye irritation: CAS No.122-99-6 Animal/Species: Vienna White rabbit cornea score: 1.7 chemosis score: 1.3 iris score:0.7 Result: Irritating to eyes · Respiratory or skin sensitisation No sensitising effects known · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity No data available. · Carcinogenicity No data available. · Reproductive toxicity No data available. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure No data available.

Aspiration hazard

No data available

ECOLOGICAL INFORMATION

12.1 Toxicity · Aquatic toxicity: 122-99-6 2-phenoxyethanol EC50 (48-h) > 500 mg/L (Daphnia magna) EC50(72-h) > 500 mg/L (Algae) LC50(96 -h) 344 mg/L (Pimephales promelas (Fish, fresh water)) 100-51-6 benzyl alcohol EC50(48-h) 230 mg/L (Daphnia magna) EC50(72-h) 770 mg/L (Algae) LC50(96-h) 460 mg/L (Pimephales promelas (Fish, fresh water)) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. (Contd. on page 9) IN Trade name: Ballpoint Pen Ink - Black (Contd. of page 8) · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

Other hazards

No further relevant information available SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Dispose of waste material according to local, state and federal regulations. · Waste disposal key: 08 03: wastes from Manufacture, Formulation, Supply and Use (MFSU) of printing inks · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information

UN Number

ADR, IMDG, IATA UN3082 · 14.2 UN proper shipping name · ADR 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((Z)-octadec-9- enylamine, Phosphoric acid, 2-et hylhexyl ester) · IMDG E N V I R O N M E N T A L L Y H A Z A R D O U S SUBSTANCE, LIQUID, N.O.S. ((Z)-octadec-9- enylamine, Phosphoric acid, 2-et hylhexyl ester), MARINE POLLUTANT · IATA E N V I R O N M E N T A L L Y H A Z A R D O U S SUBSTANCE, LIQUID, N.O.S. ((Z)-octadec-9- enylamine, Phosphoric acid, 2-et hylhexyl ester) (Contd. on page 10) IN Trade name: Ballpoint Pen Ink - Black (Contd. of page 10) · Maximum net quantity per outer packaging: 1000 ml · Transport category 3 · Tunnel restriction code - · IMDG · Limited quantities (LQ) 5L · Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml · UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS S U B S T A N C E , L I Q U I D , N . O . S . ( ( Z ) - OCTADEC-9-ENYLAMINE, PHOSPHORIC ACID, 2-ETHYLHEXYL ESTER), 9, III SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Labelling