ZINC ALLOY INSERTS (WITH Cr (+VI) FINISH)

Hazard statements (CLP)

H228, H251, H261, H271, H272, H290, H301, H303, H311, H314, H317, H318, H319, H330, H331, H334, H335, H340, H341, H350, H351, H361, H372, H400, H401, H410, H411, H412, H413

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

(29 CFR 1910.1200) Classification of the substance, compound, or mixture

Environmental hazards

Flammable

Signal word

DANGER Hazard statements H228 Flammable solids H251 Self heating chemicals H261 Chemicals which, in contact with water, emit flammable gases H271 May cause fire or explosion. Strong oxidizer H272 May intensify fire. Oxidizer H290 May be corrosive to metals H301, H311 Toxic if swallowed or in contact with skin H303 Harmful if swallowed H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H330 Fatal if inhaled H331 Toxic if inhaled H334 May cause allergy, asthma symptoms, or breathing difficulties H335 May cause respiratory irritation H340 May cause genetic defects H341 Suspected of causing genetic defects H350 May cause cancer H351 Suspected of causing cancer H361 Suspected of damaging fertility of the unborn child H372 Causes damage to organs through prolonged or repeated exposures H400 Very toxic to aquatic life H401 Toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects H412, H413 Toxic to aquatic life, Chronic

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames, and hot surfaces. No smoking. P220 Keep / store away from clothing or combustible materials. P221 Take any precaution to avoid mixing with combustibles. P223 Do not allow contact with water. P231, P232 Manage under inert gas. Protect from moisture. P234 Keep only in original container. P235, P410 Keep cool. Protect from sunlight. P240 Ground or bond container and receiving equipment. P260 Do not breathe dust, fumes, gas, mist, vapor, spray. P261 Avoid breathing machined dusts, fumes, gases, mists, vapors, or sprays. P264 Wash hands thoroughly after managing this product. P270 Do not eat, drink, or smoke when managing this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280, P281 Use personal protective equipment as required. P283 Wear fireproof, flame resistant, or fire-retardant clothing as required. P284 Wear respiratory protection. P285 In case of inadequate ventilation, wear respiratory protection.

Response

P301, P330, P331 IF SWALLOWED: Rinse mouth, do not induce vomiting. P303, P361, P353 IF ON SKIN: Remove / take off immediately all contaminated clothing. Rinse or shower. P314 IF SWALLOWED: Call a POISON CENTER or doctor / physician if you feel unwell. P302, P352 IF ON SKIN: Lightly brush machined dusts from skin. Rinse the skin with soap and water. P304, P340 IF INHALED: Remove worker to fresh air and keep in a position comfortable for breathing. P305, P338, P351 IF IN EYES: Remove contact lens (if present). Rinse cautiously with water for 15 minutes. P306, P360 IF ON CLOTHING: Rinse contaminated clothing or skin immediately. P310 IMMEDIATELY CALL: Poison center or doctor / physician. P334, P335 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. Wrap in wet bandages. P337, P313 IF EYE IRRITATION PERSISTS: Get medical advice / attention. P308, P313 IF EXPOSED (or concerned): Get medical advice / attention. P363 IF CLOTHING IS CONTAMINATED: Wash before reuse. P370, P378 IN CASE OF FIRE: Use dry sand, dry chemical, or alcohol resistant foam to extinguish. P371, P380, P375 IN CASE OF FIRE: Evacuate area. Fight fire remotely due to risk of explosion. P333, P313 IF SKIN IRRITATION OR A RASH OCCURS: Get medical advice / attention. P341, P342, P311 IF EXPERIENCING RESPIRATORY SYMPTOMS: Get medical advice / attention. P390 IF SPILLED: Absorb spillage to prevent material damage. P391 IF SPILLED, COLLECT SPILLAGE: Use a proper disposal container.

Storage

P402, P404 Store in a dry place. Store in a closed container. P403, P233, P235 Store in a well-ventilated place. Keep cool. P405 Store in a secure location. P406 Store in a corrosive resistant container. P407 Maintain air gap between stacks / pallets. P420 Store away from other materials.

Disposal

P501 Dispose of contents / container in accordance with disposal regulations.

Other hazards which do not result in classification

Zinc Alloy Inserts (with Cr (+VI) Finish) is INERT in its solid form. Zinc Alloy Inserts (with Cr (+VI) Finish) present minor inhalation, ingestion, and contact health hazards. User-generated dust, fumes, and mists may pose a hazard if inhaled or ingested. Avoid inhalation of metal dusts and fumes. Dust may be irritating to the unprotected skin or eyes. Metal dust / fumes may cause an influenza-like illness. Avoid skin / eye contact with dusts to prevent mechanical irritation. Section 3 (3.1) is a summary of compounds typically found in Zinc Alloy Inserts. Section 3 (3.2) is a summary of compounds typically found in Hexavalent Rainbow Color Chromate Solutions. Various grades of Zinc Alloy Inserts (with Cr (+VI) Finish) will contain different combinations of these compounds. Other trace elements may also be present in minute amounts. These small quantities (less than 0.1 %) are frequently referred to as "trace" or "residual" compounds.

2.1 Classification of the substance or mixture

GHS classification in accordance with: US OSHA (29 CFR 1910-1200) - Flammable solids, Cat. 1, Cat. 2 / H228 - Self heating chemicals, Cat. 1 / H251 - Chemicals which, in contact with water, emit flammable gases (Cat. 2) / H261 - Oxidizing solution / H271 - Oxidizing liquids, Cat. 3 / H272 - Corrosive to metals, Cat. 1 / H290 - Acute toxicity, oral, Cat. 3 / H301 - Acute toxicity, oral, Cat. 5 / H303 - Acute toxicity, dermal. Cat. 3 / H311 - Skin Corrosion, Cat. 1A / H314 - Skin sensitivity, Cat. 1 / H317 - Causes serious eye damage, Cat. 1 / H318 - Eye irritation, Cat. 2A / H319 - Acute toxicity, inhalation, Cat 1 / H330 - Acute toxicity, inhalation, Cat. 3 / H331 - Respiratory sensitivity, Cat. 1 / H334 - Respiratory tract irritation, Cat. 3 / H335 - Mutagenicity, Cat. 1B . H340 - Germ cell mutagenicity, Cat. 2 / H341 - Carcinogen, Cat 1B, H350 - Carcinogenicity, Cat. 2 / H351 - Reproductive toxicity, Cat. 2 / H361 - Specific target organ toxicity following repeated exposure, Cat. 1 / H372 - Aquatic, acute, Cat. 1 / H400 - Very toxic to aquatic life with long lasting effects / H410