FD and C Blue No.1 Powder

Hazard statements (CLP)

H313

Code

Statements

H313

May be harmful in contact with skin

Signal word

Warning Hazard statsments H313 May be harmful in contact with skin,

Precautionary statements

P312 Call 2 POISON CENTER or dectoriphysician if you feel unwell,

Additional information

Ne Additional Information Clagsfizaton and nazaids sletements ane i1 atconding fo the Untea Nat ens Globaliy Hasmnnizer Syslem of Giassiicabon and Labatrg of Chemicals (OHS) Regus ininovdus countr estregicns Mt classiieat ons and arard Sitements are apploatls Based on sdopled 1aZard <lasses and Ca Precaut snary statemiels are bstod aczorsng i Regutat ans it sl CaUNT O TGS Cther hazards: Dermal contact may discolor the sxin due fo dye characleristics. May form combustible dust concentrations in air, See Section 11 for foxicological information. SDS Name: FD and C Blue No.1 Powder positive pressure mode} and approved protective clothing. Personnel withcut suitable raspiratory protecticn must leave the area to prevent significant expesure to hazardous gases from cornbustion, burning or decomposition. In an enclosed or poorly ventiiated ares, wear SCBA during cleanup immediately after 2 fire as well as during the attack phase of firefighting operations. See section 9 for additional information, SECTION 6: Accidental release measures Personal pracautions, protective equipment and amergency procedures: See Seclion 8 for recommendations on the use of personal protective equipment. If spified in an enclosed area, ventilate. Avoid raising powdered material due to explosion hazard. Use spark- proof and explosion-proof equipment. if inhalation of dust cannct be avoided, wesr an approved particulate respirator. Environmental pracautions: Do not flush product into public sewer, water systems of surface waters, Mathods and materials for containment and cleaning up: Centain spill. Wear proper personal protective clothing and equipment. Using cars to avoid dust generation, vacuum or sweep into a closed conlainer for reuse or disposal. Use approved industrial vacuum cleaner for removal. Avoid causing dust. Place into labeled, closed container; store in safe focation to await dispesal. Change contaminated clothing and launder before reuse. SECTION 7: Handling and storage Pracautions for safe handling: As with any chemical prodisct, use good laboratoryiworkplace procedures. Wash thoroughly after handling this product. Always wash up befors eating, smoking or Lsing the faciliies. Use under well-veniilated conditions. Avoid eye and skin cantact. Avoid drinking, tasting, swaliowing or ingesting this product. Avoid routine inhalation of dust of any kind Exercise care when emptying containers, sweeping, mixing of doing other tasks which can create dust. Wash contaminated clothing before reuse. Provide eyewash fountains and safety showers in the work area. As a precaution to contrel dust explasion potential, implement the following safety measures:Eliminate ignition sources (e.g., sparks, static buildup, excessive heat, ete.). In general, dust of organic materials is a static charge genarator which may be ignited by electrostatic discharge, electrical arcs, sparks, welding forches, cigareftes, open flame, or cther significant heat sources. Uise spark-proof tools and equipment. Bond, ground and properly vent conveyars, dust control devices and other transfer equipment. Prohibit flow of polymer, powder of dust through non-conductive ducts, vacuum hoses of pipes, etc.; only use grounded, slectrically conductive transfer lines when preumatically conveying product. Good housekeeping and controlling of dusts are necessary for safe handling of product. Prevent accurmulation of dust (e.g., wel- ventilated conditions, promplly vacuuming spills, cleaning overhead horizontal surfaces, etc.). Conditions for safe storage, including any incompatibilifes: Store coot and dry, under well-ventilated concitions. Store this materiaf away fram incompatible substances (ses section 16}, Do not siore in open, unlabeled or misiabeled containers. Keep conlainer closed when not in use. SECTION 8: Exposure controls [ personal protection Centrol parameters: Occupational exposure fimits (OELY: Gharmical Nara AGGH - TWAGating ACGH - STEL C.LACeBlES NE WE Chemicel Nare. Ausata How Zestand Kores Tavan $08 Name: FD and C Blue No.1 Powder Dust combustibility data C.l. ACID BLUE 9 DISOOIUM SALT Farticle size variation is considered a critical factor in regards to dust expiosion hazard information. Results epplicable as follows: sample particle size <75 um, <6% moisture content, Sample tested may not be typical of product. - Minimu explosive concentration: 37 gim3 - Minimurm ignilion energy (spark gap): >38 mJ - Minimum ignition energy (Chem ign) 500-1000 mJ - Minimum Autoignition temperature (dust cloud): 530 °C - Minimum Autoignition temperature {dust layer): 275 °C - Maximum pressure of explosion: 9.0 bars-gauge - Deflagration Index, Kst: 146 bar-m/sec - Explosivity index <0.16 - Dust Hazard Class: 1 (weak) SECTION 10: Stability and reactivity Reactivity: None known. Chemical stabllity: This product is stable, Possibliity of hazardous reactions: Hazardous polymerization will not ccour, Conditions to avoid: Avoid dust formaticn. Incompatible matsrals: Avoid oxidizing agents and redusing agents. Hazardous decomposition products: Oxides of carbon, oxides of nitragen, oxides of sulfur, oxides of soditm. SECTION 11: Toxicological information Information on likely routes of exposure: Gensral: Caution must be exercised through the prudant use of protective equipment and handling procedires to minimize axposure. Eyes: Sofid particles on the eye (powder/dust) may cause pain and be accompanied by irritation. 8kin: May be harmiul in contact with skin, Repeated or prolonged skin contact may cause irritation Inhalation: Dust inhalation may cause respiratory irmitation. tngestion: Ingestion may cause iritation Acute toxiaity Information; May be harmiul in contact with skin - Category 5. No toxicity studies have been conducted on fivs product. Oral L0560, Ret >2000 myikg. Based on data from similar material(s). Dermal LDS0, Rabbit >4000-5000 myrkg. Based on data from similar materialis). Chesmical Name inhalston L35 Spaca O LES) Spocies Dsrmaf 105G Spacies . o Bloe 8.6 sodun st we e 3500 e Rt s 453 e viouse Skdn corrosionfirritation: Not classified (based on available data. the classification eriteria are notmet). Chemica: Nams, SKin fritmton. Spacise B80S Name: FD and C Blue No.1 Powder Dispose of unused contents {incineration or iandfillf in accordance with national and local reguiations. Dispese of container in accordanee with national and local regulations. Ensure the use of properly authorized waste management companies, where appropriate., See Section 8 for recommendations on the use of personal protective equipment.

2.1 Classification of the substance or mixture

Acute Toxicity, Dermal, category 5, H313