DM Black 01

Hazard statements (CLP)

H317, H319, H412

Code

Statements

H317

May cause an allergic skin reaction

Hazard categories

Serious eye damage/eye irritation: Eye frrit. 2 Respiratory or skin sensitization: Skin Sens Hazardous to the aquatic environment: Aquatic Chronic 3 Hazard Statements Causes serious eye irritation May cause an allergic skin reaction Harmful to aquatic life with long lasting effects

Signal word

Warning

Hazard statements

May cause an allergic skin reaction Causes serious eye irritation Harmful to aquatic life with long lasting effects

Precautionary statements

If eye irritation persists: Get medical advice/attention. {f skin irritation occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not handle untit all safety precautions have been read and understood. protective equipment and emergency procedures Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use personal protection equipment. Environmental precautions Do not allow to enter into surface water or drains. Methods and material for containment and cleaning wu Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8

2.3 Other hazards

No information available. Mixtures Hazardous components CAS No Components Quantity 57693-14-8 Trisedium bis[3-hydroxy-4- 9.944 %| [(2-hydroxy-1-naphthyl}azo]-7-nitronaphthalene-1-sulphonato(3-)ichromate(3-) 64-19-7 Acetic acid 5.865 %| 67785-16-4 Amines, tallow alkyl, ethoxylated, sulfates, ammonium salts 1.548 % 68920-66-1 Alcohols, C16-18 and C18-unsatd., ethoxylated 1.548 %| 72403-66-8 Disodium [N-(2-chiorophenyl)-2-[(2-hydroxy-5-nitrophenyl)azo}-3-oxobutyramidato(2-)] 0.4972 % [3-hydroxy-4-{(2-hydroxy-1-naphthylazo}-7-nitronaphthalene-1-sulphonato(3-)jchromate(2-} Description of first aid measures After inhalation Provide fresh air. When in doubt or if symptoms are observed, get medical advice. After contact with skin After contact with skin, wash immediately with polyethylene glycol, followed by plenty of water. Take off immediately all contaminated clothing and wash it before reuse. Medical treatment necessary. After contact with eyes After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmoiogist immediately. After ingestion Rinse mouth immediately and drink plenty of water. Most important symptoms and effects, both acute and delayed No information available. Indication of any immediate medical attention and special treatment needed Treat symptomatically. Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. Specific hazards arising from the chemical Non-flammabie. Special protective equipment and precautions for fire-fighters Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.

Additional information

Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Personal

Disposal

see section 13 Precautions for safe handlin Advice on safe handling No special measures are necessary. Advice on protection against fire and explosion No speciai fire protection measures are necessary. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Advice on storage compatibility No special measures are necessary. Control parameters Exposure limits CAS No. Hazardous decomposition products No known hazardous decomposition products.

2.1 Classification of the substance or mixture

Regulation (EC) No. 1272/2008 Hazard categories: Serious eye damage/eye irritation: Eye frrit. 2 Respiratory or skin sensitization: Skin Sens. 1 Hazardous to the aquatic environment: Aquatic Chronic 3 Hazard Statements: Causes serious eye irritation May cause an allergic skin reaction Harmful to aquatic life with long lasting effects