PAINTERS EDGE Interior Latex Flat Light Ledgestone

Hazard statements (CLP)

H315, H319, H350, H372

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Ingredient(s) with unknown acute toxicity

2.4% (oral), 2.4% (dermal), 2.4% (inhalation)

Signal word

Danger

Hazard statements

Causes skin irritation. Causes serious eye irritation. May cause cancer. Causes damage to organs through prolonged or repeated exposure. (respiratory tract)

Precautionary statements

General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.

Response

IF exposed or concerned: Get medical advice or attention. Take off contaminated clothing and wash it before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation occurs Get medical advice or attention. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Storage

Store locked up.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure. Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.

2.3 Other hazards

None known.

2.1 Classification of the substance or mixture

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 2.4% (oral), 2.4% (dermal), 2.4% (inhalation) GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Causes skin irritation. Causes serious eye irritation. May cause cancer. Causes damage to organs through prolonged or repeated exposure. (respiratory tract) Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response : IF exposed or concerned: Get medical advice or attention. Take off contaminated clothing and wash it before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Supplemental label Adequate ventilation required when sanding or abrading the dried film. If Adequate elements ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure. Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Hazards not otherwise : None known. classified Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of : Not available. identification CAS number/other identifiers Ingredient name % by weight CAS number Calcium Carbonate ≥10 - <20 1317-65-3 Titanium Dioxide ≤10 13463-67-7 Cristobalite, respirable powder ≤3 14464-46-1 Heavy Paraffinic Oil ≤1 64742-65-0 Crystalline Silica, respirable powder ≤0.3 14808-60-7 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : Causes skin irritation. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: irritation redness Ingestion : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Section 5. Fire-fighting measures Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide metal oxide/oxides Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Section 7. Handling and storage Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials incompatibilities (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits (OSHA United States) Ingredient name CAS # Exposure limits Calcium Carbonate 1317-65-3 OSHA PEL (United States, 5/2018). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust NIOSH REL (United States, 10/2020). TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: Total Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Cristobalite, respirable powder 14464-46-1 OSHA PEL Z3 (United States, 6/2016). TWA: 250 mppcf / 2 x (%SiO2+5) 8 hours. Form: Respirable TWA: 10 mg/m³ / 2 x (%SiO2+2) 8 hours. Form: Respirable TWA: 30 mg/m³ / 2 x (%SiO2+2) 8 hours. Form: Total dust OSHA PEL (United States, 5/2018). TWA: 50 µg/m³ 8 hours. Form: Respirable dust ACGIH TLV (United States, 1/2021). TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2020). TWA: 0.05 mg/m³ 10 hours. Form: respirable dust Heavy Paraffinic Oil 64742-65-0 OSHA PEL (United States, 5/2018). TWA: 5 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist Crystalline Silica, respirable powder 14808-60-7 OSHA PEL Z3 (United States, 6/2016). Section 8. Exposure controls/personal protection TWA: 250 mppcf / (%SiO2+5) 8 hours. Form: Respirable TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form: Respirable OSHA PEL (United States, 5/2018). TWA: 50 µg/m³ 8 hours. Form: Respirable dust ACGIH TLV (United States, 1/2021). TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2020). TWA: 0.05 mg/m³ 10 hours. Form: respirable dust Occupational exposure limits (Canada) Ingredient name CAS # Exposure limits Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 1/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 7/2019). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. Cristobalite 14464-46-1 CA British Columbia Provincial (Canada, 1/2021). TWA: 0.025 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 7/2019). TWAEV: 0.05 mg/m³ 8 hours. Form: Respirable dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 0.025 mg/m³ 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 0.05 mg/m³ 8 hours. Form: Respirable particulate matter. CA Saskatchewan Provincial (Canada, 7/2013). TWA: 0.05 mg/m³ 8 hours. Form: respirable fraction Quartz 14808-60-7 CA British Columbia Provincial (Canada, 1/2021). TWA: 0.025 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 7/2019). TWAEV: 0.1 mg/m³ 8 hours. Form: Respirable dust. CA Alberta Provincial (Canada, 6/2018). Section 8. Exposure controls/personal protection 8 hrs OEL: 0.025 mg/m³ 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 0.1 mg/m³ 8 hours. Form: Respirable particulate matter. CA Saskatchewan Provincial (Canada, 7/2013). TWA: 0.05 mg/m³ 8 hours. Form: respirable fraction Occupational exposure limits (Mexico) CAS # Exposure limits Cristobalite, respirable powder 14464-46-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, controls local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Section 9. Physical and chemical properties The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Appearance Physical state : Liquid. Color : Not available. Odor : Not available. Odor threshold : Not available. pH : 9.1 Melting point/freezing point : Not available. Boiling point, initial boiling : 100°C (212°F) point, and boiling range Flash point : Closed cup: Not applicable. Evaporation rate