AWS A5.13, A5.21

Hazard statements (CLP)

H302, H312, H315, H317, H319, H320, H330, H334, H335, H350i, H351, H361f, H372, H400, H410, H412

Code

Statements

H302

Harmful if swallowed

2.1 Classification of the substance or mixture

The product is placed on the market in solid form

Hazard statements

Solid metallic products are generally classified as “articles” and do not constitute a hazardous material in solid form under the definitions of the OSHA Hazard Communication Standard (29 CFR 1910.1200). Any articles manufactured from these solid products would be generally classified as non-hazardous. However some hazardous elements contained in these products can be emitted under certain processing conditions such as but not limited to: burning, melting, cutting, sawing, brazing, grinding, machining, milling, and welding. Products in the solid state present no fire or explosion hazard. Small chips, fines, and dust may ignite readily, though. The following classification information is for the hazardous elements which may be released during processing. 2.1.1 Classification in accordance with GHS-US Acute Tox. 4 (Oral) H302 STOT SE 3 H335 Acute Tox. 4 (Dermal) H312 Carc. 1B H350i Skin Irrit. 2 H315 Carc. 2 H351 Skin Sens. 1 H317 Repr. Tox 2 H361f Eye Irrit. 2A H319 STOT RE 1 H372 Eye Irrit. 2B H320 Aquatic Acute 1 H400 Acute dust/mist 1,2 H330 Aquatic Chronic 1 H410 Resp. Sens. 1B H334 Aquatic Chronic 3 H412 H302 Harmful if swallowed H312 Harmful in contact with skin H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H320 Causes eye irritation H330 Fatal if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation H350i May cause cancer by inhalation H351 Suspected of causing cancer. H361f Suspected of damaging fertility H372 Causes damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects.

2.2 Label elements

GHS-US labeling

Hazard pictograms

GHS07 GHS08 GHS09

Signal word

Danger

Precautionary statements

P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace P273 Avoid release into the environment P280 Wear protectective gloves/protective clothing/eye protection/face protection. P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of saop and water P308+P313 If exposed or concerned: Get medical advice/attention. P314 Get medical advice and attention if you feel unwell P321 Specific treatment (see label) P330 Rinse mouth P333+P313 If skin irritation or a rash occurs: Get medical advice/attention P362+P364 Take off contaminated clothing and wash before reuse P391 Collect spillage P405 Store locked up P501 Dispose of contents and container in accordance with local/regional/national/international regulations.

2.3 Other hazards

Welding Hazards: CAUTION. Welding will create fumes which may be toxic. If welding is performed on plated or coated materials such as galvanised or painted steel, excessive fume may be produced which contains additional hazardous components, and may result in metal fume fever or other health effects. The product and work surface will be hot during and after welding. Electric shock can kill. Arc Rays can injur eyes and burn skin. May be harmful if swallowed. Causes mild skin irritation. Very toxic to aquatic life with long lasting effects. Very toxic to aquatic life.

Ingredient(s) with unknown acute toxicity

37.65% of the mixture consists of ingredient(s) of unknown toxicity SECTION: 3