Hardener 500AE

Dunlop Service B.V

Revision date : 2023-04-18

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GHS02 GHS08 GHS07
Health risk rating 5
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

205-500-4/141-78-6

Name of the chemical

acetic acid, ethyl ester

Concentration

>=70-<90

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

>=10-<20 >=5% >=5% >=5% >=0,1%

EC/CAS

247-714-0/26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

>=0,1-<1 >=5% >=5% >=5% >=0,1%

General Information

Version

2.0

Revision date

2023-04-18

Product name

Hardener 500AE

Product Synonyms

UFI -

1.2.1 Relevant identified uses

Hardener / Curing agent

Emergency telephone

+49(0)6132/84463, (001) 352 323 3500

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 M011 M017 M022

Company Information

company name

Dunlop Service B.V

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H315, H317, H319, H334, H335, H336, H351, H373

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe mist or vapours. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection.

Response

P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Hazardous Ingredients

ethyl acetate Diphenylmethanediisocyanate, polymeric p-toluenesulphonyl isocyanate methylenediphenyl diisocyanate

Additional information

"As from 24 August 2023 adequate training is required before industrial or pro- fessional use."

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumula- tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regu- lation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Respiratory sensitisation, Category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3, Respiratory system Specific target organ toxicity - single ex- H336: May cause drowsiness or dizziness. posure, Category 3, Central nervous system Specific target organ toxicity - repeated H373: May cause damage to organs through pro- exposure, Category 2 longed or repeated exposure.

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