Peel Away 1 Paint Remover

Hazard statements (CLP)

H314

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Appearance: Light Grey Paste Physical state: Paste Odor: None Classification Skin corrosion/irritation Category 1 Sub-category A Serious eye damage/eye irritation Category 1

Signal word

Danger Hazard statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

2.1 Classification of the substance or mixture

Classification Skin corrosion/irritation Category 1 Sub-category A Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Calcium Hydroxide 1305-62-0 25-30 Sodium hydroxide 1310-73-2 5-10 Silica, Quartz 14808-60-7 0.001-0.5 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES Description of first aid measures Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician immediately. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention if irritation occurs. Inhalation Remove to fresh air. Immediate medical attention is required. Ingestion Rinse mouth. Do NOT induce vomiting. If conscious, give water or milk. Get medical attention if necessary. Most important symptoms and effects, both acute and delayed Symptoms May cause severe chemical burns with reddening and pain. May cause dermatitis or irritation in some individuals upon prolonged contact. May cause irritation to the mucous membranes and upper respiratory tract. Ingestion may cause severe burns to mouth, throat or stomach. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Individuals with chronic respiratory or skin diseases may be at risk from exposure. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. _____________________________________________________________________________________________ Specific Hazards Arising from the Chemical At elevated temperatures, containers may rupture. Contents are corrosive and all personal contact must be avoided. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Cool containers with flooding quantities of water until well after fire is out. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Do not allow into any sewer, on the ground or into any body of water. See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. Wash spill area with plenty of water. Spills and releases may have to be reported to Federal and/or local authorities. See section 15. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray. Use only in well-ventilated areas. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Conditions Store in a cool, well ventilated area away from acids and other incompatible substances. Store locked up. Incompatible Materials Acids. Organic halogen compounds. Nitromethane. Flammable liquid. Metals such as aluminum, tin, and zinc. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Calcium Hydroxide TWA: 5 mg/m3 TWA: 15 mg/m3 total dust TWA: 5 mg/m3 1305-62-0 TWA: 5 mg/m3 respirable fraction (vacated) TWA: 5 mg/m3 not in effect as a result of reconsideration Sodium hydroxide Ceiling: 2 mg/m3 TWA: 2 mg/m3 IDLH: 10 mg/m3 1310-73-2 (vacated) Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 Silica, Quartz TWA: 0.025 mg/m3 respirable TWA: 50 µg/m3 IDLH: 50 mg/m3 respirable dust 14808-60-7 particulate matter (vacated) TWA: 0.1 mg/m3 TWA: 0.05 mg/m3 respirable respirable dust dust : (250)/(%SiO2 + 5) mppcf TWA respirable fraction : (10)/(%SiO2 + 2) mg/m3 TWA respirable fraction Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Use in a well- ventilated location (eg. local exhaust ventilation, fans). Showers. Eyewash stations. Individual protection measures, such as personal protective equipment Eye/Face Protection Chemical safety goggles/faceshield. Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Wear suitable protective clothing. Rubber, neoprene, or other impervious gloves are recommended to prevent skin contact. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Reference Wiley's "Quick Selection Guide to Chemical Protective Clothing". Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Ensure adequate ventilation, especially in confined areas. For spray application, a NIOSH approved dust respirator and eye protection. Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance White paste Odor None Color White Odor Threshold Not determined Property Values Remarks • Method pH 12 Melting point / freezing point Not determined Boiling point / boiling range > 100 °C / 212 °F Flash point None Evaporation Rate Same as water Flammability (Solid, Gas) Not determined Flammability Limit in Air Upper flammability or explosive Not determined limits Lower flammability or explosive Not determined limits Vapor Pressure Same as water Vapor Density Same as water Relative Density Not determined Water Solubility Completely soluble Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined Other information VOC Content (%) 50% 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials Acids. Organic halogen compounds. Nitromethane. Flammable liquid. Metals such as aluminum, tin, and zinc. Hazardous decomposition products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Avoid breathing vapors or mists. May cause irritation of respiratory tract. Ingestion May be harmful if swallowed. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Calcium Hydroxide = 7340 mg/kg ( Rat ) > 2500 mg/kg ( Rat ) - Sodium hydroxide = 325 mg/kg ( Rat ) = 1350 mg/kg ( Rabbit ) - Proprietary 1 = 27000 mg/kg ( Rat ) - > 5800 mg/m3 ( Rat ) 4 h Proprietary 3 = 1219 mg/kg ( Rat ) - Proprietary 4 = 4090 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) - Symptoms related to the physical, chemical and toxicological characteristics Symptoms May cause dermatitis or irritation in some individuals upon prolonged contact. May cause severe chemical burns with reddening and pain. May cause skin and eye irritation. May cause irritation to the mucous membranes and upper respiratory tract. May cause burns to mouth and gastrointestinal corrosion. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Causes severe skin burns. Serious eye damage/eye Causes severe eye damage. irritation Carcinogenicity This ingredient is a possible carcinogen when it appears as a respirable dust. Chemical name ACGIH IARC NTP OSHA Proprietary 2 A2 Group 1 Known X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present STOT - repeated exposure Respirable crystalline silica causes damage to organs (lung effects, immune system effects, and kidney effects) through prolonged or repeated exposure. Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document Oral LD50 3,852.6 mg/kg Dermal LD50 6,127.0 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical name Algae/aquatic plants Fish Crustacea Sodium hydroxide 45.4: 96 h Oncorhynchus mykiss 1310-73-2 mg/L LC50 static Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical name California Hazardous Waste Status Calcium Hydroxide Corrosive 1305-62-0 Sodium hydroxide Toxic 1310-73-2 Corrosive 14. TRANSPORT INFORMATION Note Based on package size, product may be eligible for limited quantity exception. DOT UN/ID No UN1823 Proper Shipping Name Sodium hydroxide, solid, mixture Hazard class 8 Packing Group II IATA UN number UN1823 Proper Shipping Name Sodium hydroxide, solid, mixture Transport hazard class(es) 8 Packing Group II IMDG UN number UN1823 Proper Shipping Name Sodium hydroxide, solid, mixture Transport hazard class(es) 8 Packing Group II 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory DSL/NDSL EINECS/ELI ENCS IECSC KECL PICCS AICS Status NCS Calcium Hydroxide X ACTIVE X Sodium hydroxide X ACTIVE X Proprietary 1 X ACTIVE X Silica, Quartz X ACTIVE X Proprietary 2 X ACTIVE X Proprietary 3 X ACTIVE X Proprietary 4 X ACTIVE X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Sodium hydroxide 1000 lb RQ 1000 lb final RQ 1310-73-2 RQ 454 kg final RQ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances Sodium hydroxide 1000 lb X US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical name California Proposition 65 Silica, Quartz Carcinogen U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Calcium Hydroxide X 1305-62-0 Sodium hydroxide X 1310-73-2 Silica, Quartz X 14808-60-7 16. OTHER INFORMATION NFPA Health Hazards Flammability Instability Special Hazards Not determined HMIS Health Hazards Flammability Physical hazards Personal Protection 3 0 Not determined Issue Date: 01-Jan-2008 Revision Date: 17-Apr-2023 Revision Note: Regulatory update Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet