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Hazard statements (CLP)

H315, H317, H318, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Association Dangerous Goods Regulation the modificarea conventional effects 10,5 și from completarea kind: short carbon and hotărârii long-term dioxide, guvernului foam, exposure powder nr. 1.093/2006 and Concentration: water spray. 71 % 1.3. 14.7. On 12.3. UNSUITABLE - Chemical EU Bioaccumulative IC50: Details Maritime the Immobilization basis of and the transport of physical EXTINGUISHING available supplier OEL potential Concentration in hazards: data, of bulk the the EU according safety Product EQUIPMENT

2.1 Classification of the substance or mixture

substances is based with endocrine on calculation DRUCKFARBEN disrupting methods properties HELLAS as per Annex in SA concentration I of CLP, Part ≥ 0.1%. 3, unless determined otherwise in Section Solubility Information not available 2006/15/EC; not Directive available 2004/37/EC; Directive 2000/39/EC; Directive 98/24/EC; Directive Full - 11. INDEX: address Identifier in Annex VI of CLP MEGARIDOS AVENUE 5.2. Partition Interactive Special coefficient: hazards effects arising n-octanol/water from the substance 91/322/EEC. or mixture not available District - Environmental LC50: and Lethal Country Concentration hazards: Product 50% classification is based 19300 on calculation ASPROPYRGOS methods as per Annex I of CLP, Part 4, unless SECTION 3. 15. Composition/information (ATTIKI) Vapour pressure determined otherwise in Regulatory information on ingredients TLV-ACGIH ACGIH 2023 not available 12.4. HAZARDS - Section Density Information LD50: Lethal Mobility 12. and/or CAUSED not in soil dose 50% relative available BY density EXPOSURE IN THE EVENT 1,25-1,30 OF FIRE GREECE g/cm3 Temperature: 25 °C 3.2. Do - OEL: Occupational Exposure Level Relative Mixtures not breathe vapour combustion density products. The product is Ground Tel. combustible not available Granulated and, when +30 210 5519500 Blast the Furnace powder is Slag released into the air in sufficient concentrations 15.1. and - PBT: Persistent, bioaccumulative and toxic Threshold Particle ACUTE Information Safety, in the characteristics TOXICITY presence health Limit not available Value and of environmental a source of ignition, regulations/legislation it can create Fax not explosive available specific mixtures +30 210 5519501 for with the air. substance Fires may or start mixture or get worse by leakage of the solid e-mail - PEC: address Predicted of environmental the competent Concentration person Contains: product Type from the container, Country when it TWA/8h reaches high temperatures or through STEL/15min contact with sources of Remarks ignition. / Observations responsible - PEL: Predicted for the exposure Safety Data level Sheet psafety@druckfarben.gr ATE Seveso (Inhalation) Category of - the Directive mixture: 2012/18/EU: mg/m3 ppm Not classified mg/m3 None (no significant ppm component) 5.3. 12.5. Identification

Contains

derives any from PBT criteria or vPvB established in percentage by the ≥ CLP than Regulation, Temperature: 0,1%. (EU) 2019/130; 25 °C Annex I, Part 2. The data for Directive (EU) - evaluation None Kinematic Information IMDG: International in particular. viscosity of chemical-physical not available Maritime Code properties for dangerous are reported 2019/983; not goods Directive in section 9. available (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive Name The Information - Health IMO: product International not does relevant Product not Maritime classification Organization substances is based with endocrine on calculation DRUCKFARBEN disrupting methods properties HELLAS as per Annex in SA concentration I of CLP, Part 0.1% 3, unless determined otherwise in Section Solubility Information not available 2006/15/EC; not Directive available 2004/37/EC; Directive 2000/39/EC; Directive 98/24/EC; Directive Full INDEX address Identifier in Annex VI of CLP MEGARIDOS AVENUE Partition Interactive Special coefficient hazards effects arising n-octanol/water from the substance 91/322/EEC or mixture not available District Environmental LC50: and Lethal Country Concentration hazards: Product 50% classification is based 19300 on calculation ASPROPYRGOS methods as per Annex I of CLP, Part 4, unless 15. Composition/information ATTIKI) Vapour pressure determined otherwise in Regulatory information on ingredients TLV-ACGIH ACGIH 2023 not available HAZARDS Section Density Information LD50: Lethal Mobility 12 and/or CAUSED not in soil dose 50% relative available BY density EXPOSURE IN THE EVENT 1,25-1,30 OF FIRE GREECE g/cm3 Temperature: 25 °C Do OEL: Occupational Exposure Level Relative Mixtures not breathe vapour combustion density products. The product is Ground Tel combustible not available Granulated and, when 30 210 5519500 Blast the Furnace powder is Slag released into the air in sufficient concentrations and PBT: Persistent, bioaccumulative and toxic Threshold Particle ACUTE Information Safety, in the characteristics TOXICITY presence health Limit not available Value and of environmental a source of ignition, regulations/legislation it can create Fax not explosive available specific mixtures 30 210 5519501 for with the air substance Fires may or start mixture or get worse by leakage of the solid e-mail PEC: address Predicted of environmental the competent Concentration person Contains product Type from the container, Country when it TWA/8h reaches high temperatures or through STEL/15min contact with sources of Remarks ignition. / Observations responsible PEL: Predicted for the exposure Safety Data level Sheet psafety@druckfarben.gr ATE Seveso Inhalation) Category of - the Directive mixture: 2012/18/EU mg/m3 ppm Not classified mg/m3 None no significant ppm component) 12.5. Identification PMT: Persistent, mobile and toxic ATE Advice Results TLV Oral) for of of firefighters the PBT mixture and ROU vPvB assessment 0,1 x = Conc. % Classification Not classified (no (EC) significant Cement Portland Identification x = Conc. %

Environmental hazards

of risk assessment are given The in sections above values and are 12 of not this Personal precautions, protective equipment and emergency procedures GENERAL BIBLIOGRAPHY TLVs, sheet but guide values, to be used for particles that do not have their own TLV and that are insoluble or poorly soluble in water and have low toxicity SECTION Hazard Regulation 10 Sensitising Substances classification for subject 13 EC) Stability the skin Disposal

2.2 Label elements

exposed material 14. pursuant Transport TOXICITY to must this chemical be to EC chosen information Regulation agent according

Hazard statements

Does not meet the classification criteria for this hazard class 4.2. Most Before Eye important Dam. 1 symptoms and Serious effects, all the eye both damage, acute category sections and delayed of this material safety data sheet. Avoid leakage of the product into the 1 H318 handling the product, consult Causes serious other eye damage. environment. - The H315 Skin Irrit. 2 Merck Index. Do not - 10th eat, drink Edition or Causes Skin irritation, category 2 smoke skin during irritation. use. Remove any contaminated clothes and personal protective equipment before entering ... / >> H335 May cause respiratory irritation. H317 May cause an allergic skin reaction.

Precautionary statements

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves / eye protection / face protection. P310 Immediately call a POISON CENTER or a doctor P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P264 Wash hands thoroughly after handling.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures