Organization

Hazard statements (CLP)

H315, H317, H318, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

sections of arising the Exposure were mixture: from modified: Level Immediately the substance call a or POISON mixture CENTER Not classified or a doctor (no significant component) Temperature: 25 °C 12.5. SECTION Kinematic ATE - 01 PBT: Regulatory references: Results / P501 02 (Oral) Persistent, / 03 viscosity of of / 05 the PBT 1. Identification / mixture: 08 bioaccumulative and / 09 vPvB / 10 / assessment 11 / and Dispose 15. toxic of the of contents substance/mixture not available / container to an approved Not classified (no significant component) and waste of the

Disposal

company/undertaking plant or recycled in accordance with local / Solubility ATE - PEC: (Dermal) Substances = CEILING must subject be ; performed INHAL to the = Rotterdam Inhalable through an Fraction Convention: authorised ; RESP waste = management Respirable Fraction firm, in compliance ; THORA with = Thoracic national Fraction. and local regulations. 3.2. If CONTAMINATED CARCINOGENICITY 3. Regulation (EU) 2020/878 (II Annex of REACH Regulation) None Mixtures there are no contraindications, PACKAGING spray powder with water to prevent the formation of dust. Fax SECTION +30 210 5519501 e-mail address 10. of Stability 4. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament the competent and person reactivity Wear During Contaminated suitable the risk protective packaging assessment equipment must process, be recovered (including it is essential or personal disposed to take protective of into in compliance consideration equipment with the referred national ACGIH to waste occupational under management Section exposure 8 of the regulations. safety levels for responsible Does 5. Regulation data particulate not meet sheet) to not for (EU) the 286/2011 Safety Data prevent (II Atp. Sheet criteria CLP) for of this the hazard European psafety@druckfarben.gr class Parliament

Prevention

limit gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Quartz (Crystalline Silica) Intended contaminated Information - VOC: Volatile use not water organic available used Compounds for extinction and the remains Waterproofing of the fire according Mortar to applicable regulations. Threshold On the basis Limit of available Value data, the product does not contain any SVHC in percentage ≥ than 0,1%. 2.3. SPECIAL 9.2.1. RESPIRATORY

Further information

Type Very PROTECTIVE persistent OR with SKIN Country regard and EQUIPMENT SENSITISATION very to bioaccumulative physical FOR hazard TWA/8h FIRE-FIGHTERS classes STEL/15min

Remarks

/ Observations 1.3. Normal - vPvM: Substances subject to authorisation mg/m3 Details fire Very of fighting the persistent supplier clothing and of very i.e. the fire safety mobile kit (BS (Annex XIV ppm REACH) data EN sheet 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with mg/m3 ppm SECTION 13. Disposal considerations On self-contained Information Sensitising - WGK: the basis Water for not of open the available skin circuit classes data, positive (German). the pressure product does compressed not contain air breathing any PBT or apparatus vPvB in percentage (BS EN 137). ≥ than 0,1%. None TLV ROU 0,1 RESP Name DRUCKFARBEN HELLAS SA 13.1. Waste OEL treatment EU methods 0,1 RESP Full The 9.2.2. GERM address product Other CELL safety does MUTAGENICITY not characteristics contain substances with endocrine MEGARIDOS disrupting AVENUE properties in concentration ≥ 0.1%. SECTION Substances TLV-ACGIH 6. Accidental release measures subject to exportation 0,025 reporting pursuant to Regulation (EU) 649/2012: RESP District GENERAL and BIBLIOGRAPHY Country 19300 ASPROPYRGOS (ATTIKI) Reuse, None when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product 6.1. Legend: Total Does 1. Regulation should Personal solids not meet be evaluated

Precautionary statements

250°C (EC) on (EC) request. for No rescue Toxicity on use(s) basic Estimate physical for user of provided and chemical information properties according to each specific use of the product. 12.2. Persistence and degradability 4.3. Information CAS: Indication Chemical on of likely any Abstract immediate routes exposure medical Number treatment - This document must not be Service of regarded as a attention guarantee and on special any specific product needed property. Information Properties not - CE50: Signal The use words: applicable Effective of this product is not subject not available concentration (required to induce a Value Danger to our direct control; therefore, users must, under their own responsibility, comply with the current health 50% effect) Information Information not available Information Appearance - CE: Identifier not in available ESIS (European archive of existing powder substances) Temperature: 25 °C and safety laws and regulations. The producer is relieved from any liability arising from improper uses. 14.7. Colour - CLP: Provide appointed staff with adequate training on how to use chemical products. Maritime Regulation transport P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves / eye protection / face protection. P310 Immediately call a POISON CENTER or a doctor P501 Dispose of contents / container to an approved waste disposal plant or recycled in accordance with local / national / international regulations. P102 Keep out of reach of children. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P302+P352 IF ON SKIN: wash with plenty of water and soap P333+P313 If skin irritation or rash occurs: Get medical advice / attention.

Contains

any otherwise Substances Reactivity contamination classified subject of (PNOC to skin, the eyes Stockholm respirable and personal Convention: fraction: clothing. 3 mg/m3; These PNOC indications inhalable apply fraction: for both 10 mg/m3). processing For staff values and above those these involved limits, in use emergency a P type 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament procedures. filter, None whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment. The above values are not TLVs, but guide values, 1.4. SECTION REPRODUCTIVE 7. Emergency Identification to There Regulation 14. be used are no for particular (EU) telephone particles risks Transport TOXICITY 487/2013 number that do of reaction (IV information not have Atp. CLP) of the European Parliament x = with Conc. their other own % TLV substances and that in are normal insoluble conditions (EC) or poorly Cement Portland Identification x = Conc. %

Hazard pictograms

with should should soil environmental

TOXICOLOGICAL INFORMATION

or vegetation. standards. the product be checked reach to waterways ensure or INHALATION: - ECHA website H317 Get medical advice/attention May cause an immediately. allergic skin reaction. Remove victim to fresh air, away from the accident scene. If the subject stops 7.2. 11.1. 14.5. breathing, - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy Conditions Information Environmental EUH210 administer for on safe artificial

Storage

classes respiration. Safety including as defined data Take any sheet suitable incompatibilities in available Regulation

Hazard statements

Derived immediate No Effect effects Level as well as chronic effects odourless from short and long-term exposure SECTION 5. Firefighting Melting Information - EmS: Emergency Bioaccumulative point not / freezing relevant Schedule potential measures point not available CALCULATION H318 METHODS FOR Causes serious eye damage. 5.1. Chemical Initial Information - GHS: boiling Extinguishing Globally not point available Harmonized System of classification not media hazards: Causes Product skin irritation. derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for and applicable labeling of chemicals Information not available H315 and physical Flammability - IATA DGR: International Air Transport Association Dangerous evaluation of chemical-physical properties May cause are an reported not available in section Goods Regulation 9. H317 allergic skin reaction. Lower Interactive - IC50: explosive SUITABLE

Health hazards

Immobilization effects limit Concentration 50% EXTINGUISHING

2.1 Classification of the substance or mixture

(EU) classification the substance 2017/776 (X criteria Atp. CLP) for this hazard class 2.1. 10.3. Cement When not applicable Possibility choosing Portland of personal of hazardous protective reactions or equipment, mixture ask your chemical substance supplier for advice. 14. Regulation (EU) 2018/669 (XI Atp. CLP) INDEX Collect Personal the protective leaked product equipment and must place be 10 it in CE ≤ x containers marked, < 20 showing for recovery Eye that or Dam. it complies disposal. 1 H318, with If there Skin applicable are Irrit. no 2 contraindications, standards. H315, STOT SE 3 use H335, jets Skin of water Sens. to eliminate 1B H317 15.2. EC The STOT 15. Regulation product Provide Chemical powders product - REPEATED residues. an emergency is are safety (EU) EXPOSURE classified 266-043-4 potentially 2019/521 (XII Atp. CLP) assessment shower as explosive hazardous with face when pursuant and mixed eye wash to with the station. air. provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments 16. Delegated Regulation (UE) 2018/1480 (XIII Atp. CLP) CAS Make HAND sure PROTECTION the and leakage 65997-15-1 supplements). site is well The aired. product Evaluate thus the requires compatibility a safety of datasheet the container that to complies be used, with by the checking provisions section 14.2. UN proper shipping name of (EU) Does 17. Regulation 10. Contaminated not meet the Regulation (EU) classification 2019/1148 material criteria for this hazard class 10.4. should 2020/878. In A chemical the Conditions case be disposed safety of prolonged to avoid assessment of in compliance contact has with not with the been the product, performed provisions protect for set the the forth hands preparation/for in point with 13. penetration-resistant the substances indicated work gloves in section (see standard 3. EN 374). Any 18. Delegated Regulation (UE) 2020/217 (XIV Atp. CLP) The Work additional full glove wording material information of hazard must be concerning (H) chosen phrases according the is given risks in for to section the health use 16 and/or process of the the sheet. and environment the products are that given may in form. sections Latex 11 gloves and 12 may not applicable ASPIRATION 19. Delegated HAZARD of this cause sheet. sensitivity Regulation (UE) 2020/1182 (XV Atp. CLP) 6.4. reactions. Avoid Reference environmental to other dust sections build-up. SECTION Hazard 20. Delegated 16. Regulation SKIN PROTECTION classification and indication: Other (UE) information 2021/643 (XVI Atp. CLP) 10.5. Any Does 21. Delegated Wear Incompatible Serious information not meet Regulation category eye II damage, the classification on professional materials personal category (UE) 2021/849 protection long-sleeved criteria for (XVII 1 and disposal this Atp. overalls is and given hazard CLP) class safety in sections footwear 8 H318 (see and Regulation 13. Causes 2016/425 serious and standard eye damage. EN ISO 20344). Wash body 14.3. Text Transport SECTION 22. Delegated Regulation (UE) 2022/692 (XVIII Atp. CLP) of hazard hazard 4. First (H) indications class(es) mentioned in section 2-3 of the sheet: aid with Skin soap irritation, and water category after removing 2 measures protective clothing. H315 Causes skin irritation. 11.2. 23. Information EYE Information Skin PROTECTION Delegated Regulation sensitization, not available on other hazards category 1B (UE) 2023/707 H317 May cause an allergic skin reaction. 4.1. not Description SECTION 7. Handling and storage Wear airtight protective goggles (see standard EN ISO 16321). Eye applicable Dam. 1 of first aid measures Serious eye damage, category 1 Based - The Skin Merck on Irrit. the Index. 2 available - 10th data, Edition the Skin product irritation, does category not contain 2 substances listed in the main European lists of potential or suspected endocrine 10.6. RESPIRATORY 7.1. EYES: Precautions Hazardous decomposition STOT Remove SE 3 for PROTECTION products contact safe handling lenses, Specific present. target Wash organ toxicity immediately - single with exposure, plenty of category water 3 for at least 30-60 minutes, opening the eyelids fully. Get disruptors - Handling elements with Chemical human Safety health effects if under 2.2. Use Label

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures