controls/personal

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H319, H330, H335, H341, H350

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

assessment skin, number classes eyes (German). products May and criteria personal cause for this respiratory clothing. hazard Value class irritation. These Safety Data Sheet Quartz indications (Crystalline apply for Silica) both processing Information staff and those involved in emergency procedures. Threshold Appearance H317 Limit Value May cause an allergic powder skin reaction. SECTION 4. First aid measures Colour FORMALDEHYDE ASPIRATION not A GENERAL chemical EUH203 Type applicable BIBLIOGRAPHY safety assessment Country has Contains Temperature: 25 °C According to Annex II to REACH - Regulation (EU) 2020/878 and to Annex II to UK REACH TWA/8h not been chromium performed (VI). Red-Brown for May the produce preparation/for STEL/15min an allergic the substances reaction. indicated

Remarks

Temperature: in / section Observations 25 °C 3. 6.2. Odour 4.1. Description of first aid measures 1. Environmental Regulation When heated (EC) to precautions with / the Observations provisions set forth in point 13. INGESTION: Acute Tox. Do 3 not induce vomiting Acute unless toxicity, explicitly category authorised 3 by a doctor. Do not give anything by mouth to an unconscious person. Get / Observations Name On 19. the Delegated basis of Regulation available data, (UE) the 2020/1182 mg/m3 product (XV does Atp. not ppm CLP) DRUCKFARBEN contain any PBT mg/m3 or HELLAS vPvB in SA percentage ppm ≥ than 0,1%. the Before Skin extent handling Sens. of the 1B the contamination. product, consult In Skin the all sensitization, absence the other of sections other category more of 1B this specific material indications, safety data use sheet. of disposable Avoid leakage gloves of in the the product Full not 20. TLV event of into Delegated applicable address possible the Regulation contact BGR (UE) 2021/643 1 (XVI Atp. CLP) MEGARIDOS AVENUE 2 with environment. Information H350 body fluids not Do available is not recommended. eat, drink or May smoke For cause the during type cancer. of use. PPE Remove suitable any for the contaminated characteristics clothes of the and substance personal protective or mixture, equipment District The 21. AGW see section before Delegated product and Country 8. does Regulation entering not DEU

Hazard statements

freezing

Further information

not 2020/878 EU penetrate name (II Annex IF into 0,1 IN of the EYES: information of the sewer REACH Rinse substance/mixture system Regulation) cautiously not or available come with into water contact for and with several of surface the minutes. water company/undertaking Remove or RESP ground contact water. lenses, if present and easy to In case of doubt or in the presence of symptoms contact a doctor and show him this document. 11.2. Flammability 11.1. In Text case 4. Regulation Information TLV-ACGIH (EC) on 790/2009 of hazard of more (H) on severe indications

2.3 Other hazards

symptoms, classes (I Atp. mentioned do. 0,025 ask as for defined CLP) Continue in immediate of the rinsing. section European in Regulation 2-3 medical not available of the sheet: Parliament

Potential health effects

into (IV a Avoid Atp. suitable under CLP) breathing container. of evaluation. the > dust European Ground Evaluate CM911140000 60 / fume Parliament Granulated / °C the gas compatibility / mist / Blast vapours of Furnace the / spray. container Slag to be used, by checking section 10. Absorb the SKIN: Muta. Take 2 off immediately all contaminated Germ cell mutagenicity, clothing. Wash category immediately 2 and thoroughly with running water (and soap if possible). Get 14.3. Product remainder Threshold Auto-ignition 8. Regulation medical Information Transport P403+P233 Acute advice/attention. name Tox. with Limit not available temperature (EU) inert Value 2 944/2013 absorbent class(es) Avoid further (V material. Atp. Store CLP) Acute contact in a of well-ventilated toxicity, with the European category contaminated KRAFT not available 2 place. Parliament RUST Keep BLOCKER clothing. container Powder tightly closed.

ECOLOGICAL INFORMATION

Make Decomposition 9. Regulation P264 Type sure the (EU) leakage temperature 605/2014 Country site is (VI well Wash Atp. TWA/8h aired. CLP) hands Contaminated of the thoroughly European not material after available Parliament handling. should STEL/15min be disposed of in compliance

Contains

OEL Skin Corr. Regulation difficulty, viscosity identified not 1C (EU) 2016/1179 available asthma) keep Skin EU uses of the (IX Cement the corrosion, 0,1 Atp. substance victim in a category CLP) Portland or mixture comfortable not available 1C position for breathing. If necessary administer oxygen. If the subject stops and uses advised against RESP 14.4. Any 12.1. breathing, Solubility 13. Packing Toxicity TLV-ACGIH Skin Corr. Regulation information administer group 1 (EU) on personal 2017/776 protection artificial respiration. (X Flue Skin corrosion, Atp. 0,025 Dust CLP) and disposal is not given Get medical category advice/attention. available 1 in sections 8 and 13. RESP Intended Partition 14. Regulation coefficient: use (EU) 2018/669 n-octanol/water (XI Atp. CLP) Concrete not available protection and repair product for use in buildings and civil engeenering Delayed Eye Dam. and immediate 1 effects as Serious well as eye chronic damage, effects category from short 1 and long-term exposure Vapour not 15. Regulation Rescuer Information Eye Irrit. applicable pressure (EU) 2019/521 (XII Atp. CLP) protection not 2 available Eye irritation, category 2 works not available SECTION 7. Handling and storage Density 16. Delegated and/or Regulation relative density (UE) 2018/1480 (XIII Atp. CLP) 1.20-1.30 FORMALDEHYDE g/cm3 Temperature: 25 °C Information Skin Irrit. not 2 available Skin irritation, category 2 1.3. 2.3. Threshold 7.1. It Precautions Relative 17. Details Other is STOT Regulation good practice vapour of Limit SE 3 for for safe rescuers the (EU) density supplier Value 2019/1148 handling of the safety data sheet not available lending Specific support target to organ a person toxicity who - single has been exposure, exposed category to a chemical 3 substance or to a mixture to wear personal 14.5. Particle 12.2. protective 18. Environmental Interactive Persistence Type Skin Sens. Delegated characteristics equipment. effects 1 and degradability Regulation Country The nature Skin (UE) 2020/217 TWA/8h (XIV Atp. CLP) of such sensitization, protection category depends 1 on the hazard level of the substance or mixture, on the type of exposure and on not applicable STEL/15min (UE) substances 2021/849 0,37 (XVII with Atp. endocrine 0,3 CLP) 19300 disrupting ASPROPYRGOS 0,74 properties in concentration 0,6 ≥ 0.1%. (ATTIKI) places FORMALDEHYDE H341 in which people eat. Suspected of causing genetic defects. 4.2. ACUTE 22. MAK Solubility Most H330 important Delegated Regulation TOXICITY in water symptoms and DEU (UE) 2022/692 Fatal effects, 0,37 if inhaled. (XVIII Atp. 0,3 CLP) both acute and 55000 delayed mg/l GREECE 0,74 0,6 C = 1,2 mg/m3 9.2. 14.6. 23. Other 7.2. Rapidly Conditions Special TLV H301 degradable Delegated information product. Maritime OEL Merck Index. H318 transport - 10th EU in Edition bulk according Causes serious eye damage. 0,37 to IMO 0,3 instruments 0,74 0,6 1.4. Information 7.3. FORMALDEHYDE - Handling Emergency Specific TLV-ACGIH H319 end use(s) Chemical not telephone available Safety number Causes serious eye irritation. 0,1 0,3 4.3. Identification Information - INRS - Fiche not Toxicologique Partition Indication H315 Ferrous coefficient: of any relevant Sulfate immediate n-octanol/water (toxicological sheet) medical Causes x = Conc. skin attention irritation. % and special 0,35 Classification treatment needed 50 ≤ x chromium < 100 (VI). May Eye produce Dam. an 1 H318, allergic Skin reaction. Irrit. 2 H315, STOT SE 3 H335, Skin Sens. 1B H317 - ECHA Exposure website EC Means to FORMALDEHYDE have available 266-043-4 in the workplace for specific and immediate treatment 2.1. - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy 15.1. CAS 8.1. SECTION Information Classification Safety, LD50 health not (Dermal) Stability and reactivity available 65997-15-1 of and the environmental substance or mixture regulations/legislation 270 specific mg/kg Rabbit for the substance or mixture As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Control parameters Quartz Running LEGEND: (Crystalline LD50 water (Oral) for skin Silica) and eye wash 100 mg/kg Rat INDEX The well aired through effective local aspiration Seveso ADR Reactivity product European LC50 Category is (Inhalation classified Agreement Directive vapours) as hazardous 2012/18/EU concerning 30 pursuant the x < carriage 50 to the of provisions Dangerous Substance 0,588 set mg/l/4h goods forth None with by Rat in Road EC) a community Regulation workplace Cement Portland Flue Dust Identification x = Conc. %

Precautionary statements

for safe storage, Toxic Regulation GRC for (UE) user 2023/707 including 0,37 if swallowed. any incompatibilities 0,3 Tel. SECTION 3. Composition/information +30 0,74 210 5519500 0,6 24. TLV Delegated Regulation ROU (UE) 2023/1434 0,37 (XIX Atp. 0,3 CLP) Fax on ingredients +30 0,74 210 5519501 0,6 Specific ATE H311 (Inhalation) information of the on mixture: symptoms Toxic and in effects contact caused with skin. by the product Not classified are unknown. (no significant component) e-mail not 24. ПДК Delegated applicable address Regulation of the RUS competent (UE) 2023/1435 person (XX Atp. CLP) 0,5 п, O, A 3.2. 12.3. Store ATE Mixtures Bioaccumulative H302 (Oral) only in of the the original mixture: potential container. Harmful Store if the swallowed. containers sealed, >2000 in a mg/kg well ventilated place, away from direct sunlight. Keep containers away responsible 9.2.1. WEL Information for the with Safety GBR regard Data to Sheet physical 2,5 P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves / eye protection / face protection. P310 Immediately call a POISON CENTER or a doctor P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P264 Wash hands thoroughly after handling.

Hazard categories

2 psafety@druckfarben.gr 2,5 2 DELAYED from ATE H314 any (Dermal) incompatible EFFECTS: of the mixture: Based materials, on Causes the see information section severe 10 for skin currently details. burns available, and Not eye classified damage. there are (no no significant known cases component) of delayed effects following exposure to this 14.7. - The

Environmental hazards

or vPvB in percentage are given in ≥ than sections 0,1%. 11 and 12 of this sheet Extinguishing media HAND This document PROTECTION must not be regarded as a guarantee on any specific product property СВЪРЗАНИ С ЕКСПОЗИЦИЯ НА ХИМИЧНИ АГЕНТИ ПРИ РАБОТА (изм. ДВ. бр.5 от 17 INDEX FORMALDEHYDE Causes CE: Point Identifier skin irritation in ESIS (European archive ≤ x of < existing Януари 2020г.) substances) Acute Tox. 4 H302, Eye Irrit. 2 H319, Skin Irrit. 2 H315 EC Hazard Protect The use hands with category III work gloves CLP Contained Endocrine Decomposes Regulation classification of this product substance disrupting 231-753-5 under EC) and is the PROTECTION Россия products Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in ПОСТАНОВЛЕНИЕ от 13 февраля 2018 г. N 25 ОБ УТВЕРЖДЕНИИ ГИГИЕНИЧЕСКИХ INDEX No GERM LC50 hazardous CELL Lethal MUTAGENICITY reactions Concentration are foreseeable 50% ≤ x in < normal НОРМАТИВОВ ГН 2.2.5.3532-18 "ПРЕДЕЛЬНО ДОПУСТИМЫЕ КОНЦЕНТРАЦИИ (ПДК) conditions Substance of use and storage with a community workplace exposure limit SECTION Hazard Respiratory protection EC Substances LD50: labelling Lethal subject Disposal dose 266-002-0 pursuant to 50% authorisation devices must to EC Regulation considerations be used if the technical measures adopted are not suitable for restricting the worker's exposure to the

Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures

2.1 Classification of the substance or mixture

10. Stability and reactivity available 65997-15-1 of and the environmental substance or mixture regulations/legislation 270 specific mg/kg Rabbit for the substance or mixture As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Control parameters Quartz Running LEGEND: (Crystalline LD50 water (Oral): for skin Silica) and eye wash. 100 mg/kg Rat 10.1. INDEX The well aired through effective local aspiration. Seveso - ADR: Reactivity product European LC50 Category is (Inhalation classified Agreement - Directive vapours): as hazardous 2012/18/EU: concerning 30 pursuant ≤ the x < carriage 50 to the of provisions Dangerous Substance 0,588 set mg/l/4h goods forth None with by Rat in Road (EC) a community Regulation workplace 1272/2008 exposure (CLP) (and limit. Regulatory references: When Note for choosing subsequent users: personal protective equipment, ask your chemical substance supplier for advice. 12.5. EC amendments - ATE: Results Acute of Toxicity and PBT 238-878-4 supplements). and Estimate vPvB assessment The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation SECTION 2020/878. Personal The information CAS There SKIN Restrictions - CAS: CORROSION are Chemical protective no relating 5. Firefighting particular 14808-60-7 contained Abstract equipment / to IRRITATION risks the Service in the must product of reaction present measures Number or contained be CE sheet with other substances marked, are based substances pursuant showing on that our own in normal to conditions it complies knowledge Annex XVII of to use. EC Regulation 1907/2006 with on applicable the date standards. of the last version. Users must verify the BGR Provide suitability an emergency shower with face and eye wash station. and thoroughness България of provided НАРЕДБА № 13 ОТ 30 ДЕКЕМВРИ 2003 Г. ЗА ЗАЩИТА НА РАБОТЕЩИТЕ ОТ РИСКОВЕ, according to each specific use of the product. Any Ferrous On - CE50: Product the additional basis Effective Sulfate of information available concentration data, concerning the (required product the information to risks does induce for not a health contain 50% effect) and/or any PBT the environment or vPvB in percentage are given in ≥ than sections 0,1%. 11 and 12 of this sheet. 5.1. Extinguishing media HAND This document PROTECTION must not be regarded as a guarantee on any specific product property. СВЪРЗАНИ С ЕКСПОЗИЦИЯ НА ХИМИЧНИ АГЕНТИ ПРИ РАБОТА (изм. ДВ. бр.5 от 17 INDEX FORMALDEHYDE Causes - CE: Point Identifier skin irritation in ESIS (European 3 archive 1 ≤ x of < existing Януари 2020г.) 5 substances) Acute Tox. 4 H302, Eye Irrit. 2 H319, Skin Irrit. 2 H315 12.6. EC Hazard Protect The use hands with category III work gloves. - CLP: Contained Endocrine Decomposes Regulation classification of this product substance disrupting 231-753-5 under (EC) and is the 1272/2008 indication: not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health properties effect of heat. ATE Oral: 500 mg/kg SUITABLE DEU The and following should be considered when choosing work glove material (see standard EN 374): compatibility, degradation, permeability time. safety laws EXTINGUISHING and regulations. Deutschland EQUIPMENT Forschungsgemeinschaft MAK- und BAT-Werte-Liste 2022 Ständige Senatskommission zur arising from improper CAS SERIOUS - DNEL: The extinguishing equipment should be of the Prüfung Serious Acqueous Point Derived EYE eye solutions damage, DAMAGE 7720-78-7 No Effect are category The / Level stabilised IRRITATION 75 1 producer is relieved from any liability with methanol but tend to polymerise H318 conventional gesundheitsschädlicher kind: carbon dioxide, over time. Arbeitsstoffe foam, powder Causes uses. Mitteilung and 58 water spray. serious eye damage. The Provide REACH Based - EmS: Skin Point on Emergency work appointed irritation, Reg. gloves' resistance the available 01-2119513203-xxxx category staff with adequate Schedule data, 2 72-77 to chemical training the product does not contain FORMALDEHYDE agents on should how to be use checked substances listed chemical before products. H315 in the main Causes use, as it can be unpredictable. The gloves' wear time depends on European skin lists irritation. of potential or suspected endocrine UNSUITABLE GRC the duration and type of use. EXTINGUISHING Ελλάδα EQUIPMENT Π.Δ. 26/2020 (ΦΕΚ 50/Α` 6.3.2020) Εναρμόνιση της ελληνικής νομοθεσίας προς τις διατάξεις των 10.2. Flue Causes disruptors - GHS: None Chemical Specific Dust Globally serious with target stability environmental eye Harmonized organ damage toxicity System effects - single under of classification exposure, evaluation. and labeling of chemicals οδηγιών 2017/2398/EΕ, 2019/130/ΕΕ και 2019/983/ΕΕ «για την τροποποίηση της οδηγίας H335 May cause respiratory irritation. SKIN CALCULATION category PROTECTION in particular. METHODS FOR CLASSIFICATION INDEX Regulation - IATA DGR: (EU) 3 International 2019/1148 Air - Transport on the marketing 1 ≤ Association x < 3 and Dangerous 2004/37/ΕΚ use of explosives ’’σχετικά Eye Goods με την Dam. precursors Regulation 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335, Skin Sens. 1 H317 προστασία τους κινδύνους Wear Chemical Skin category sensitization, and physical II professional hazards: long-sleeved 1 Product classification overalls and derives safety from footwear 12.7. EC 5.2. Special hazards arising from the substance criteria The RESPIRATORY not - IC50: Other applicable product H317 (see established Immobilization adverse Regulation is stable των by εργαζομένων 270-659-9 OR effects SKIN May cause an allergic skin reaction. 2016/425 in category the CLP and Concentration normal SENSITISATION Regulation, conditions από standard 50% of use and storage. Annex την έκθεση EN ISO or mixture I, Part 20344). που 2. συνδέονται σε καρκινογόνους ή μεταλλαξιγόνους παράγοντες κατά την εργασία’’» The Wash data body for με with evaluation CAS - IMDG: International soap and of chemical-physical water after removing 68475-76-3 Maritime Code for dangerous goods properties protective are clothing. reported in section 9. ROU EYE Health PROTECTION hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 3, unless determined otherwise in Section România Hotărârea nr. 53/2021 pentru modificarea hotărârii guvernului nr. 1.218/2006, precum și pentru 10.3. REACH Sensitising Information Substances - IMO: HAZARDS CAUSED BY EXPOSURE IN THE modificarea Possibility International Reg. for not in the of Candidate available 01-2119486767-17-0071 hazardous skin Maritime List Organization reactions (Art. 59 REACH) EVENT OF și FIRE completarea hotărârii guvernului nr. 1.093/2006 2.2. Wear 11. Ground On - INDEX: Label the basis airtight protective goggles (see standard EN ISO 16321). elements Granulated Identifier of available in Annex Blast data, Furnace VI of the CLP product Slag does not contain any SVHC in percentage ≥ than 0,1%. Do RUS not breathe combustion RESPIRATORY Environmental hazards: PROTECTION Россия products. Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in ПОСТАНОВЛЕНИЕ от 13 февраля 2018 г. N 25 ОБ УТВЕРЖДЕНИИ ГИГИЕНИЧЕСКИХ INDEX No GERM - LC50: hazardous CELL Lethal MUTAGENICITY reactions Concentration are foreseeable 50% 1 ≤ x in < normal НОРМАТИВОВ ГН 2.2.5.3532-18 "ПРЕДЕЛЬНО ДОПУСТИМЫЕ КОНЦЕНТРАЦИИ (ПДК) 5 conditions Substance of use and storage. with a community workplace exposure limit. SECTION Hazard Respiratory Section 12. protection EC Substances - LD50: labelling Lethal subject 13. Disposal