Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
General Information
Revision date
2011-02-24
Product name
Modralit 3K Härter
CAS No.
9016-87-9
1.2.1 Relevant identified uses
Hardening agent/ Curing agent
Icons in SDS
Company Information
company name
Dreve Dentamid GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
sicherheitsdatenblatt@dreve.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
CLP CLASSIFICATION
GHS08 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. GHS07 Acute Tox. 4 H332 Harmful if inhaled. STOT SE 3 H335 May cause respiratory irritation. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction.
EU Classification
Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R20-40-48/20: Harmful by inhalation. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Xn; Sensitising R42/43: May cause sensitisation by inhalation and skin contact. Xi; Irritant R36/37/38: Irritating to eyes, respiratory system and skin. · Information concerning particular hazards for human and environment: Not applicable.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation.
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Hazardous Ingredients
diphenylmethanediisocyanate,isomeres and homologues
Hazard statements
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. Contains isocyanates. May produce an allergic reaction. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 40 Limited evidence of a carcinogenic effect. 42/43 May cause sensitisation by inhalation and skin contact. 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Precautionary statements
P285 In case of inadequate ventilation wear respiratory protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. · Code letter and hazard designation of product: Xn Harmful 1/2 Keep locked up and out of the reach of children. 23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). 36/37 Wear suitable protective clothing and gloves. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Special rules for supplemental label elements for certain mixtures
Contains isocyanates. See information supplied by the manufacturer
PBT Substances
Not applicable
vPvB Substances
Not applicable