GREAT STUFF PRO Gaps & Cracks Insulating

DOW CHEMICAL CANADA ULC

Revision date : 2014-04-25

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

EC/CAS

63449-39-8

Name of the chemical

Paraffin waxes, chloro

Concentration

N/A

EC/CAS

75-28-5

Name of the chemical

iso-Butan, enthält  0,1% Butadien

Concentration

N/A

General Information

Revision date

2014-04-25

Product name

GREAT STUFF PRO Gaps & Cracks Insulating

Icons in SDS

Company Information

company name

DOW CHEMICAL CANADA ULC

e-mail address of the competent person responsible for the Safety Data Sheet

SDSQuestion@dow.com

GHS Information

Signal word

DANGER!

Section 2

SECTION 2: Hazards identification

Emergency Overview Color: Orange Physical State: Foam Odor: Odorless ® ™ TRADEMARK OF THE DOW CHEMICAL COMPANY ("DOW") OR AN AFFILIATED COMPANY OF DOW Hazards of product: DANGER! Flammable gas - May cause flash fire. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause anesthetic effects. May cause respiratory tract irritation. Vapors may travel a long distance; ignition and/or flash back may occur. Evacuate area. Keep upwind of spill. Stay out of low areas. Aerosol cans exposed to fire can rupture becoming flaming projectiles. Elevated temperatures can cause hazardous polymerization. Toxic fumes may be released in fire situations. Contents under pressure. Avoid temperatures above 49°C (120.2°F)

Potential health effects

Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation.

Aspiration hazard

Based on physical properties, not likely to be an aspiration hazard Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: Kidney. Liver.

Cancer information

Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother.

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