Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
EC/CAS
811-97-2
Name of the chemical
1,1,1,2-Tetrafluoroethane
Concentration
N/A
General Information
Revision date
2016-06-23
Product name
FROTH-PAK AF 620BF HFC ISO Spray Foam
1.2.1 Relevant identified uses
Component(s) for the manufacture of urethane polymers
Emergency telephone
1-888-226-8832
Icons in SDS
Company Information
company name
DOW CHEMICAL CANADA ULC
e-mail address of the competent person responsible for the Safety Data Sheet
SDSQuestion@dow.com
GHS Information
Signal word
WARNING!!
Section 2
SECTION 2: Hazards identification
Emergency Overview Appearance Physical state Liquid. Color Brown Odor Musty ® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Hazard Summary WARNING!! May cause allergic skin reaction. May cause allergic respiratory reaction. May cause lung injury. May cause eye irritation. May cause skin irritation. Vapor reduces oxygen available for breathing. May cause central nervous system effects. May cause anesthetic effects. May cause respiratory tract irritation. Toxic fumes may be released in fire situations. May react with water. Elevated temperatures can cause hazardous polymerization. Material reacts slowly with water, releasing carbon dioxide which can cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this reaction. Isolate area. Keep upwind of spill. Stay out of low areas. Contents under pressure.
Potential health effects
Eyes: May cause moderate eye irritation. May cause slight temporary corneal injury. Skin: Prolonged contact may cause skin irritation with local redness. May stain skin. Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. Decreased lung function has been associated with overexposure to isocyanates. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). May cause central nervous system effects. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. May cause allergic respiratory reaction. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. Based on physical properties, not likely to be an aspiration hazard. Chronic Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Contains component(s) which did not cause birth defects in animals; other fetal effects occurred only at doses toxic to the mother.