CABADEX Herbicide

Hazard statements (CLP)

H315, H317, H319, H335, H336, H400, H410

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

1999/45/EC weeds are small and actively growing. 2. Rinse inside of tank with clean water and flush through booms and hoses using at least one tenth of the spray RATE OF APPLICATION AND WEEDS CONTROLLED tank volume. Drain tank completely. NOTES

2.1 Classification of the substance or mixture

One application of CABADEX will control susceptible emerged weeds at the following rates: Broad-leaved weeds not present at application will not be controlled. 3. Half fill tank with clean water and add All Clear Extra at the recommended rate. Agitate and then briefly flush the booms and hoses with the cleaning solution. Top up with water making sure the tank is completely full and

CLP CLASSIFICATION

Clippings from grass treated with CABADEX can be safely used for mulch after the third cut. allow to stand for 15 minutes with agitation. Flush the booms and hoses and drain tank completely. Weed Rate L product/ha Skin corrosion/irritation - Category 2 - H315 An interval of four weeks must elapse between application of CABADEX and re-seeding turf. Rate ml product/100m2 4. Nozzles and filters should be removed and cleaned separately with All Clear Extra solution containing 50 ml of Bird’s-foot trefoil1 Serious eye damage/eye irritation - Category 2 - H319 Do not apply if turfgrass is wet. All Clear Extra per 10 litres of water. Common daisy Skin sensitisation - Category 1 - H317 Do not apply to turf, lawns or grass areas which are under stress. 5. Rinse the tank with clean water and flush through the booms and hoses using at least one tenth of the spray Do not apply if night temperatures are low, if ground frost is imminent, or in periods of prolonged cold or dry weather. Specific target organ toxicity - single exposure - Category 3 - Respiratory tract irritant. - H335 Common dandelion Ensure weeds are actively growing as after periods of prolonged drought, weeds can take a long time to start actively Specific target organ toxicity - repeated exposure - Category 3 - Narcotic effects. - H336 tank volume. Drain tank completely. Common mouse-ear 6. For disposal of washings, follow The Code of Practice for Using Plant Protection Products. Do not spray onto growing again after soil moisture returns. 2.0 20 sensitive crop or land intended for cropping with sensitive crop. Acute aquatic toxicity - Category 1 - H400 Creeping buttercup Take extreme care to avoid drift onto crops and non-target plants e.g. trees, shrubs, bedding, outside the target area. Chronic aquatic toxicity - Category 1 - H410 Note: If it is not possible to drain the tank completely, step 3 must be repeated before going onto step 4. Ribwort plantain1 For the full text of the H-Statements mentioned in this Section, see Section 16. RESISTANCE Dow AgroSciences Conditions of Supply Slender speedwell

EU Classification

Directives 67/548/EEC or 1999/45/EC CABADEX contains active ingredients with differing modes of action and the risk of resistance building is therefore All goods supplied by us are of high grade and we believe them to be suitable but, as we cannot exercise control over Irritant - R36/37/38 reduced. However, as florasulam is an ALS-inhibitor there is a risk of resistance building to this active ingredient their storage, handling, mixing or use, or the weather conditions before, during or after application which may affect White clover R43 and so precautions should be taken to minimise the risk. Therefore, avoid using single action mode of action the performance of the goods, all conditions and warranties, statutory or otherwise, as to the quality or fitness for Yarrow1 119mm R67 herbicides, such as ALS-inhibitors in the same field over a number of years. Users are advised to apply products any purpose of our goods are excluded. No responsibility will be accepted by us or re-sellers for any failure in 1Moderate control only Dangerous for the environment - R50/53 containing herbicides with different modes of action or use sequences or tank mixtures where two or more performance, damage or injury whatsoever arising from their storage, handling, application or use. These conditions For the full text of the R-phrases mentioned in this Section, see Section 16. components are active against the target weeds. cannot be varied by our staff or agents whether or not they supervise or assist in the use of such goods. 127mm WATER VOLUME AREA OF USE

2.2 Label elements

Safety Data Sheet For overall application apply CABADEX in 200 litres of water per hectare. For knapsack application apply CABADEX in CABADEX can be applied to newly sown or established managed amenity turf, including domestic lawns, and amenity Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]: grassland. This Safety Data Sheet does not form part of the approved product label. 2 litres of water per 100 m2.

Hazard pictograms

Ensure newly sown turf has become established before treating. Turf sown in spring or summer may be ready for APPLICATION EQUIPMENT spraying at or after two leaf growth stage, usually two months after sowing, but turf sown in late summer or autumn SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING CABADEX may be applied through tractor-mounted hydraulic sprayers or knapsack sprayers providing they are in should not be sprayed until growth is resumed in the following spring, perhaps eight months after sowing. 1.1 Product identifiers good working order and have been calibrated according to the manufacturers’ recommendations. CABADEX has been tested for selectivity on the following range of turf grass species: Product name: CABADEX® Herbicide 1.2 Relevant identified uses of the substance or mixture and uses advised against Do not apply through CDA applicators. Annual meadow-grass Perennial ryegrass Identified uses: Plant Protection Product MIXING Browntop bent 1.3 Details of the supplier of the safety data sheet Smooth-stalked meadow-grass Half fill the spray tank with water and add the required amount of CABADEX. Fill up the spray tank, agitating COMPANY IDENTIFICATION continuously to ensure thorough mixing, and maintain agitation until spraying is complete. Use only clean water for Chewings fescue Rough stalked bluegrass DOW AGROSCIENCES LIMITED

Signal word

LATCHMORE COURT mixing. Creeping bentgrass BRAND STREET

Hazard statements

HITCHIN SPRAY QUALITY 4mm H315 In view of the large number of turf grass cultivars grown consult manufacturer for current approved list or test Causes skin irritation. England Apply CABADEX as a MEDIUM spray as defined by the BCPC system. H317 May cause an allergic skin reaction. CABADEX for turf safety on a small area of turf before overall application. SG5 1NH H319 Causes serious eye irritation. UNITED KINGDOM H335 ®Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow May cause respiratory irritation. H336 May cause drowsiness or dizziness. Customer Information Number: SDSQuestion@dow.com H410 Very toxic to aquatic life with long lasting effects. 4mm 234mm 7mm 245mm 283090 1608 EU 513 C O L O U R R E F E R E N C E S Q U A TIL Y C H E C K CABADEX 1 Number of Colours used: 4 MANUAL UK CCL FRANCE Cyan Magenta Yellow Black UK (including IRL) DRUSENHEIM DIGITAL PAGE 245mm x 127mm N/A 5L LEAFLET LABEL SV DOCU PAGE Tel: (0044) 191 4917777 BOTTLE 537770A01/420859 Date 24-Aug-16 Issue A 245mm 7mm 234mm 4mm SPECIMEN

Supplemental label elements

CASRN / EUH401 Classification: To avoid risks to human health and the environment, comply with the instructions for use. SECTION 4. FIRST AID MEASURES EC-No. / REACH Registration Concentration 5.3 Advice for firefighters Component REGULATION (EC) Index-No. Number 4mm

Precautionary statements

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Burning liquids may be No 1272/2008 4.1 Description of first aid measures extinguished by dilution with water. Burning liquids may be moved by flushing with water to protect personnel and P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. General advice: First Aid responders should pay attention to self-protection and use the recommended protective P302 + P352 IF ON SKIN: Wash with plenty of soap and water. clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific CASRN 01-2119456809-23 minimize property damage. To extinguish combustible residues of this product use water fog, carbon dioxide, dry P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. < 5.0 % Propylene glycol Not classified 57-55-6 chemical or foam. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental personal protective equipment. P305 + P351 + IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and damage. Review the “Accidental Release Measures” and the “Ecological Information” sections of this (M)SDS. EC-No. P338 easy to do. Continue rinsing. Inhalation: Move person to fresh air. If person is not breathing, call an emergency responder or ambulance, then give 200-338-0 P331 Do NOT induce vomiting. artificial respiration; if by mouth to mouth use rescuer protection (pocket mask etc). Call a poison control centre or Index-No. Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and P501 Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site – protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with except for empty clean containers which can be disposed of as non-hazardous waste. doctor for treatment advice. If breathing is difficult, oxygen should be administered by qualified personnel. For the full text of the H-Statements mentioned in this Section, see Section 16. this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing Skin contact: Take off contaminated clothing. Wash skin with soap and plenty of water for 15-20 minutes. Call a poison

Contains

Hydrocarbons, C9, aromatics with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained

2.3 Other hazards

control centre or doctor for treatment advice. Wash clothing before reuse. Shoes and other leather items which cannot CASRN / EC-No. / Index-No. breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up Concentration Component Classification: no data available be decontaminated should be disposed of properly. situations, refer to the relevant sections.

67/548/EEC

Eye contact: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if CASRN 14.5% SECTION 6. ACCIDENTAL RELEASE MEASURES fluroxypyr-meptyl (ISO) N - R50 - R53