Monel Based Alloys

Hazard statements (CLP)

H317, H334, H335, H351, H360D, H370, H372, H373

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

WHMIS 2015 EU/EEC According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 2015/830]

2.1 Classification of the substance or mixture

CLP • Skin Sensitization 1 - H317 Respiratory Sensitization 1 - H334 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation - H335 Carcinogenicity 2 - H351 Reproductive Toxicity 1B - H360D Specific Target Organ Toxicity Single Exposure 1 - H370 Specific Target Organ Toxicity Repeated Exposure 1 - H372 Specific Target Organ Toxicity Repeated Exposure 2 - H373 UN GHS • Skin Sensitization 1 Respiratory Sensitization 1 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation Carcinogenicity 2 Reproductive Toxicity 1B Specific Target Organ Toxicity Single Exposure 1 Specific Target Organ Toxicity Repeated Exposure 1 Specific Target Organ Toxicity Repeated Exposure 2 OSHA HCS 2012 • Skin Sensitization 1 Respiratory Sensitization 1 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation Carcinogenicity 2 Reproductive Toxicity 1B Specific Target Organ Toxicity Single Exposure 1 Specific Target Organ Toxicity Repeated Exposure 1 Specific Target Organ Toxicity Repeated Exposure 2 Combustible Dust WHMIS 2015 • Skin Sensitization 1 Respiratory Sensitization 1 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation Carcinogenicity 2 Reproductive Toxicity 1B Specific Target Organ Toxicity Single Exposure 1 Specific Target Organ Toxicity Repeated Exposure 1 Specific Target Organ Toxicity Repeated Exposure 2 Combustible Dusts 1

2.2 Label elements

CLP DANGER UN GHS DANGER OSHA HCS 2012 DANGER WHMIS 2015 DANGER

Hazard statements

H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation H351 - Suspected of causing cancer. H360D - May damage the unborn child. H370 - Causes damage to organs. H372 - Causes damage to organs through prolonged or repeated exposure. H373 - May cause damage to organs through prolonged or repeated exposure. May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Suspected of causing cancer. May damage fertility or the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure. May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Suspected of causing cancer. May damage fertility or the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure. May form combustible dust concentrations in air. May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Suspected of causing cancer. May damage fertility or the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure. May form combustible dust concentrations in air. Heating above the melting point releases metallic oxides which may cause metal fume fever by inhalation. The symptoms are shivering, fever, malaise and muscular pain.

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust or fume. P264 - Wash thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P284 - In case of inadequate ventilation wear respiratory protection. Obtain special instructions before use Do not handle until all safety precautions have been read and understood. Do not breathe dust or fume. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. Obtain special instructions before use Do not handle until all safety precautions have been read and understood. Do not breathe dust or fume. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. Obtain special instructions before use Do not handle until all safety precautions have been read and understood. Do not breathe dust or fume. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection.

Response

P304+P340 - IF INHALED Remove person to fresh air and keep comfortable for breathing. P312 - Call a POISON CENTER/doctor if you feel unwell. P302+P352 - IF ON SKIN: Wash with plenty of water. P321 - Specific treatment, see supplemental first aid information. P362+P364 - Take off contaminated clothing and wash it before reuse. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P308+P311 - IF exposed or concerned: Call a POISON CENTER or doctor/physician. P308+P313 - IF exposed or concerned: Get medical advice/attention. P314 - Get medical advice/attention if you feel unwell. Storage/Disposal • P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. Specific treatment, see supplemental first aid information. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. IF exposed: Call POISON CENTER or doctor/physician. IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Storage/Disposal • Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. IF INHALED Remove person to fresh air and keep comfortable for breathing Call a POISON CENTER/doctor. If on skin: Wash with plenty of water. Specific treatment, see supplemental first aid information. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. IF exposed: Call POISON CENTER or doctor/physician. IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Storage/Disposal • Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. IF INHALED Remove person to fresh air and keep comfortable for breathing Call a POISON CENTER/doctor if you feel unwell. IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. Specific treatment, see supplemental first aid information. If skin irritation or rash occurs: Get medical advice/attention. IF exposed or concerned: Call a POISON CENTER/doctor. IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Storage/Disposal • Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

2.3 Other hazards

CLP • May form combustible dust concentrations in air. Heating above the melting point releases metallic oxides which may cause metal fume fever by inhalation. The symptoms are shivering, fever, malaise and muscular pain. According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. UN GHS Revision 3 According to UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Third Revised Edition OSHA HCS 2012 • Heating above the melting point releases metallic oxides which may cause metal fume fever by inhalation. The symptoms are shivering, fever, malaise and muscular pain. Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to: WHMIS 2015 WHMIS 2015 • In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS).

Other hazards

UN GHS • May form combustible dust concentrations in air. Heating above the melting point releases metallic oxides which may cause metal fume fever by inhalation. The symptoms are shivering, fever, malaise and muscular pain. According to the Globally Harmonized System for Classification and Labeling (GHS) this product is considered hazardous United States (US) According to: OSHA 29 CFR 1910.1200 HCS

Health hazards

Metal fume fever Not Otherwise Classified 1