JIFFY Liquid Dish Detergent

SECTION 2: Hazards identification

OSHA EMERGENCY OVERVIEW DANGER. CORROSIVE TO EYES. CAUSES EYE BURNS. CAUSES SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED.

Principle Routes of Exposure

Skin contact. Inhalation. Ingestion. Eye contact. Eye contact: Corrosive. Causes permanent eye damage, including blindness. Skin contact: Severe skin irritation. Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Ingestion: May be irritating to mouth, throat and stomach. Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation - (mg/kg) Rabbit Rat Sodium dodecylbenzene sulfonate 25155-30-0 10 - 20% 438 Not available Ethyl alcohol 64-17-5 1 - 5% 7060 Not available =124.7 mg/L (4 h) 4. FIRST AID MEASURES Eye contact: Immediately flush eyes with running water for 15-20 minutes, keeping eyelids open. Get medical attention immediately. Skin contact: Immediately flush with plenty of water for at least 15 minutes. Get medical attention. Inhalation: If breathing is affected, remove to fresh air. Get medical attention immediately. Ingestion: If swallowed, give a cupful of water or milk. THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.

Medical Conditions Generally Aggravated by Exposure

Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may be more susceptible to irritating effects. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Extinguishing media which must not be used for safety reasons: No information available. Specific hazards: Not applicable. Unusual hazards: None known. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Put on appropriate personal protective equipment (see Section 8.). Environmental precautions Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in and clean-up methods: a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.

Storage

Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels Respiratory protection is not required if good ventilation is maintained. Personal Protective Equipment Eye protection: Chemical-splash goggles. Hand protection: Chemical-resistant gloves Skin and body protection: If major exposure is possible, wear suitable protective clothing and footwear. Respiratory protection: If aerosols, mists, vapors, or dust are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over-exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Ingredient(s) CAS # ACGIH

TOXICOLOGICAL INFORMATION

Acute toxicity: Corrosive to eyes. Oral LD50 estimated to be 3000 - 4000 mg/kg. Dermal LD50 estimated to be > 2000 mg/kg. Component Information: See Section 3. Chronic toxicity: None known Specific effects Carcinogenic effects: • None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known Ingredient(s) CAS # NTP IARC

ECOLOGICAL INFORMATION

Environmental Information: No data available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations. RCRA Hazard Class (undiluted product): Not Regulated 14. TRANSPORT INFORMATION DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information. DOT (Ground) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID IMDG (Ocean) Bill of Lading Description: CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID 15. REGULATORY INFORMATION International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations

WHMIS Classification

D2B Toxic materials Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X

Further information

Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: • Contains an added fragrance, see "Odor" heading in section 9 for specific description • This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Greenfield Industries Inc. SAFETY DATA SHEET SDS # 01 date of issue December 2019 Supersedes: February 2018 SECTION 1 - /DENT/FICATION Product Name: High Speed Steel Cutting Tools Chemical Name: Ferrous Alloys Synonyms: Tool Steel Product Use: Metalworking Tools Manufacturer: Greenfield Industries Inc., 2501 Davis Creek Rd., Seneca, SC 29678 EMERGENCY TELEPHONE NUMBER: CHEM-TEL INC. 1-800-255-3924 SECTION 2 - HAZARD(S) /DENT/FICATION

2.3 Other hazards

We do not consider this product in the solid form it is sold to constitute a physical hazard or a health hazard. Subsequent operations such as grinding, melting, welding, cutting or processing in other fashion may produce potential hazards such as dust or fumes which can be inhaled, swallowed or come in contact with the skin or eyes. Consequently, the only foreseeable physical hazard or health hazard is as a result from downstream use, this product may have hazards not otherwise classified. Health effects listed below are for exposure to metallurgical powders, dust, vapor or mist from altering this tool. If exposure limits described in section 8 are exceeded from the above operations, they should be performed in a well ventilated area and/or with alternate protective measures. Inhalation Irritant/Sensitizer 250 mg(Cr)/m3 , 35 mg(V)/m3 or 10 mg(Co)/m3 is immediately dangerous to life and health. Acute Overexposure: Symptoms of metal fume fever including chills, fever, sweating, nausea, and cough may appear. Metal fume fever begins 4 to 12 hours after exposure and lasts 24 hours without causing permanent damage. Other effects caused by dust and fume inhalation include metallic taste, eyes, nose, and throat irritation, wheezing, difficulty breathing, and chest pain. Chronic Overexposure: May cause respiratory irritation, bronchitis, allergic respiratory reaction, obstructed airways, build-up of dust in the lungs, damage to lung tissue, and lung disease, with symptoms as described in acute overexposure, especially inflammation of the respiratory tract, nose and throat irritation, violent coughing, wheezing, rasping, and shortness of breath. There may also be blood changes, liver and kidney damage, and an increased susceptibility to respiratory changes. Skin Contact: Irritant. Acute Overexposure: May cause irritation. Chronic Overexposure: May cause inflammation and/or rash (irritant or allergic contact dermatitis). Eye Contact: Irritant. Acute Overexposure: May cause irritation with redness, pain, and itching. Chronic Overexposure: May cause conjunctivitis. Ingestion: Irritant. Acute Overexposure: Ingestion of large amounts of steel dust is highly unlikely. However, ingestion of small amounts may occur by eating or smoking with contaminated hands. Chronic Overexposure: May produce the same symptoms as for acute overexposure. May also adversely affect the pancreas, thyroid gland, heart, or bone marrow. No animal derivatives are used in the manufacture of this product. SDS # 01