WINTER FRUIT & CEDARWOOD FRAGRANCE

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, ETHYL METHYLPHENYLGLYCIDATE, ISOMENTHONE, L-MENTHANONE, LINALYL ACETATE, METHYL CINNAMATE, TRANS-ROSE KETONE-2. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

Hydrocarbon Concentration %: 2.281%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Signal word: Warning 1 Hazard statements: H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, ETHYL Information: METHYLPHENYLGLYCIDATE, ISOMENTHONE, L-MENTHANONE, LINALYL ACETATE, METHYL CINNAMATE, TRANS-ROSE KETONE-2. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: Hydrocarbon Concentration %: 2.281% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 4-TERT- BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 5-<10% SS 1B;H317,- ACETATE 259-174-3, TETRAMETHYL 54464-57-2, ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 5-<10% SCI 2-SS 1B-EH C1; APHTHALENES 68155-67-9 268-979-9, H315-H317-H410,- 915-730-3 1 HEXYL CINNAMAL 101-86-0 202-983-3 5-<10% SS 1B-EH A1-EH C2; H317-H400-H411,- BENZYL ACETATE 140-11-4 205-399-7 5-<10% EH C3;H412,- ETHYL LINALOOL 10339-55-6 233-732-6 01-2119969272-32-xxxx 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- METHYL CINNAMATE 103-26-4 203-093-8 1-<5% SS 1B;H317,- ATO 3-ATD 3-EH A1- ALLYL HEPTANOATE 142-19-8 205-527-1 1-<5% EH C3;H301-H311- H400-H412,- ETHYL HEXANOATE 123-66-0 204-640-3 1-<5% FL 3-SCI 2;H226-H315, - CIS-2-TERT- BUTYLCYCLOHEXYL 20298-69-5 243-718-1 01-2119970713-33-xxxx 1-<5% EH C2;H411,- ACETATE (E)-4-(2,6,6- TRIMETHYL-1- 79-77-6 201-224-3 1-<5% EH C2;H411,- CYCLOHEXEN-1-YL)-3- BUTEN-2-ONE ETHYL SS 1B-EH C2;H317- METHYLPHENYLGLYC 77-83-8 201-061-8 1-<5% H411,- IDATE 3-HEXENOL 928-96-1 213-192-8 1-<5% FL 3-EDI 2;H226-H319, - ALPHA-CEDRENE 469-61-4 207-418-4 0.1-<1% AH 1-EH A1-EH C1; H304-H410,- L-MENTHANONE 14073-97-3 237-926-1 0.1-<1% SCI 2-SS 1B;H315- H317,- TRANS-ROSE 23726-91-2 245-842-1 0.1-<1% SCI 2-SS 1B-EH C2; KETONE-2 H315-H317-H411,- 2-METHYLPENT-2- 3142-72-1 221-552-0 0.1-<1% SCI 1C-EDI 1;H314,- ENOIC ACID FS 2-ATO 4-ATI 4-SCI 2-EDI 1-STO-SE 2-EH CAMPHOR 76-22-2 200-945-0 0.1-<1% C2;H228-H302-H315- H318-H332-H371- H411,- BETA CEDRENE 546-28-1 208-898-8 0.1-<1% AH 1-EH A1-EH C1; H304-H410,- 2,4-DIMETHYL-3- SCI 2-SS 1B-EH C2; CYCLOHEXENE 68039-49-6 268-264-1 0.1-<1% H315-H317-H411,- CARBOXALDEHYDE ISOMENTHONE 491-07-6 207-727-4 0.1-<1% SCI 2-SS 1B;H315- H317,- Substances with Community workplace exposure limits: Name CAS EC % CAMPHOR 76-22-2 200-945-0 0.1-<1% DIETHYL PHTHALATE 84-66-2 201-550-6 20-<50% Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures IF ON SKIN: Wash with plenty of soap and water. 1 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate 1 ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Ingredient CAS EC Description Value Long-term exposure limit (8-hour 5 TWA) (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 Short-term exposure limit (15- 10 minute) (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Not determined Odour: Not determined Odour threshold: Not determined pH: Not determined 1 Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 93 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard Vapour pressure: 0.15526321 mmHg Vapour density: Not determined Relative density: Not determined Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). Acute Toxicity: Based on available data the classification criteria are not met. 1 Acute Toxicity Oral 4725 Acute Toxicity Dermal >5000 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Skin Corrosion / Irritation Category 2 Serious eye damage/irritation: Eye Damage / Irritation Category 2 Respiratory or skin sensitisation: Sensitization - Skin Category 1 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Based on available data the classification criteria are not met. Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE LC50/ATE LC50 Dermal Inhalation Route Not ALLYL HEPTANOATE 142-19-8 205-527-1 218 810 Not available available Refer to Sections 2 and 3 for additional information. Section 12. Ecological information 12.1 Toxicity: Toxic to aquatic life with long lasting effects. 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6 Other adverse effects: Not available Section 13. Disposal considerations 13.1 Waste treatment methods: Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 14. Transport information 14.1 UN number: UN3082 14.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ALPHA-CEDRENE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES) 1 14.3 Transport hazard class(es): 9 Sub Risk: - 14.4. Packing Group: III 14.5 Environmental hazards: This is an environmentally hazardous substance. 14.6 Special precautions for user: None additional 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Section 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture None additional 15.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 16. Other information Concentration % Limits: EH C2=13.00% EH C3=1.29% EH C4=65.32% SCI 2=49.75% EDI 2=66. 67% EDI 2A=66.67% SS 1=10.64% Total Fractional Values: EH C2=7.69 EH C3=77.25 EH C4=1.53 SCI 2=2.01 EDI 2=1.50 EDI 2A=1. 50 SS 1=9.40 Key to revisions: Not applicable Key to abbreviations: Abbreviation Meaning AH 1 Aspiration Hazard Category 1 ATD 3 Acute Toxicity - Dermal Category 3 ATI 4 Acute Toxicity - Inhalation Category 4 ATO 3 Acute Toxicity - Oral Category 3 ATO 4 Acute Toxicity - Oral Category 4 EDI 1 Eye Damage / Irritation Category 1 EDI 2 Eye Damage / Irritation Category 2 EH A1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 EH C1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 FL 3 Flammable Liquid, Hazard Category 3 FS 2 Flammable Solid, Hazard Category 2 H226 Flammable liquid and vapour. H228 Flammable solid. H301 Toxic if swallowed. 1 H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H371 May cause damage to organs (organs, exposure route). H400 Very toxic to aquatic life.