PURPLE RAIN FRAGRANCE

Hazard statements (CLP)

H317, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, 2-HEXYL-1,3-DIOXOLANE, CITRAL, CITRONELLAL, LAURALDEHYDE, METHYLUNDECANAL, TETRAHYDROLINALOOL. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

Hydrocarbon Concentration %: 1.977%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Sensitization - Skin Category 1 danger: Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, Information: 2-HEXYL-1,3-DIOXOLANE, CITRAL, CITRONELLAL, LAURALDEHYDE, METHYLUNDECANAL, TETRAHYDROLINALOOL. May produce an allergic reaction. 20 Precautionary P261, Avoid breathing vapour or dust. statements: P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: Hydrocarbon Concentration %: 1.977% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 GAMMA 104-67-6 203-225-4 1-<5% EH C3;H412,- UNDECALACTONE (E)-4-(2,6,6- TRIMETHYL-1- 79-77-6 201-224-3 1-<5% EH C2;H411,- CYCLOHEXEN-1-YL)-3- BUTEN-2-ONE ETHYL SS 1B-EH C2;H317- METHYLPHENYLGLYC 77-83-8 201-061-8 1-<5% H411,- IDATE FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 1-<5% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-SS 1B;H315- H317,- FL 3-SCI 2-EDI 2-EH OCTANAL 124-13-0 204-683-8 1-<5% C2;H226-H315-H319- H411,- DECANAL 112-31-2 203-957-4 1-<5% EDI 2-EH C3;H319- H412,- CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 1-<5% SCI 2-EDI 2-SS 1; H315-H317-H319,- ATO 4-ATI 4-EDI 2- BENZALDEHYDE 100-52-7 202-860-4 01-2119455540-44-xxxx 1-<5% STO-SE 3(RI);H302- H319-H332-H335,- 20 BUTYL ACETATE 123-86-4 204-658-1 01-2119485493-29-xxxx 1-<5% FL 3-STO-SE 3(NE); H226-H336,EUH066 TETRAHYDROLINALO 78-69-3 201-133-9 01-2119454788-21-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; OL H315-H317-H319,- 4-METHYL-3-DECEN-5- 81782-77-6 279-815-0 01-2119983528-21-xxxx 0.1-<1% EH A1-EH C2;H400- OL H411,- 2-HEXYL-1,3- 1708-34-5 216-959-5 0.1-<1% SS 1B;H317,- DIOXOLANE LAURALDEHYDE 112-54-9 203-983-6 01-2119969441-33-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- ATO 4-SCI 1B-EDI 1- THYMOL 89-83-8 201-944-8 0.1-<1% EH C2;H302-H314- H411,- ATO 4-SCI 2-SS 1A- DELTA-DAMASCONE 57378-68-4 260-709-8 0.1-<1% EH A1-EH C1;H302- H315-H317-H410,- SCI 2-SS 1B-EH A1- METHYLUNDECANAL 110-41-8 203-765-0 0.1-<1% EH C1;H315-H317- H410,- CITRONELLAL 106-23-0 203-376-6 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- (E)-1-(2,6,6- TRIMETHYL-1,3- 23726-93-4 245-844-2 01-2120105798-49-xxxx <0.1% SCI 2-SS 1A-EH C2; CYCLOHEXADIEN-1- H315-H317-H411,- YL)-2-BUTEN-1-ONE Substances with Community workplace exposure limits: Name CAS EC % BUTYL ACETATE 123-86-4 204-658-1 1-<5% DIETHYL PHTHALATE 84-66-2 201-550-6 50-100% Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures IF ON SKIN: Wash with plenty of soap and water. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 20 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: 20 Ingredient CAS EC Description Value Long-term exposure limit (8-hour 724 TWA) (mg/m3) Short-term exposure limit (15- 200 minute) (ppm) BUTYL ACETATE 123-86-4 204-658-1 Short-term exposure limit (15- 966 minute) (mg/m3) Long-term exposure limit (8-hour 150 TWA) (ppm) Long-term exposure limit (8-hour 5 TWA) (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 Short-term exposure limit (15- 10 minute) (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Clear pale yellow to yellow liquid Odour: Not determined Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 71 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard 20 Vapour pressure: Not determined Vapour density: Not determined Relative density: 1.0360 - 1.0400 Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). Acute Toxicity: Based on available data the classification criteria are not met. Acute Toxicity Oral >5000 Acute Toxicity Dermal >5000 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Based on available data the classification criteria are not met. Serious eye damage/irritation: Based on available data the classification criteria are not met. Respiratory or skin sensitisation: Sensitization - Skin Category 1 20 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Based on available data the classification criteria are not met. Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE LC50/ATE LC50 Dermal Inhalation Route BENZALDEHYDE 100-52-7 202-860-4 1430 2500 1.5 Dust/mist Refer to Sections 2 and 3 for additional information. Section 12. Ecological information 12.1 Toxicity: Toxic to aquatic life with long lasting effects. 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6 Other adverse effects: Not available Section 13. Disposal considerations 13.1 Waste treatment methods: Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 14. Transport information 14.1 UN number: UN3082 14.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (LIMONENE, (E)-4-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-3-BUTEN- 2-ONE) 14.3 Transport hazard class(es): 9 Sub Risk: - 14.4. Packing Group: III 14.5 Environmental hazards: This is an environmentally hazardous substance. 14.6 Special precautions for user: None additional 20 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Section 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture None additional 15.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 16. Other information Concentration % Limits: EH C2=92.31% EH C3=9.06% SS 1=50.00% Total Fractional Values: EH C2=1.08 EH C3=11.03 SS 1=2.00 Key to revisions: 14.2. UN proper shipping name SECTION 3: Composition/information on ingredients Key to abbreviations: Abbreviation Meaning AH 1 Aspiration Hazard Category 1 ATI 4 Acute Toxicity - Inhalation Category 4 ATO 4 Acute Toxicity - Oral Category 4 EDI 1 Eye Damage / Irritation Category 1 EDI 2 Eye Damage / Irritation Category 2 EH A1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 EH C1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 EUH066 Repeated exposure may cause skin dryness or cracking. FL 3 Flammable Liquid, Hazard Category 3 H226 Flammable liquid and vapour.