ODALISQUE FRAGRANCE

Hazard statements (CLP)

H226, H304, H315, H317, H319, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains C12H240, L CARVONE, Ligustral, NEROLEX (SRS) NEROL 900 (BBA), NERYL ACETATE, citronellol, coumarin, geraniol, geranyl acetate, hydroxycitronellal, iso eugenol, pinenes. May produce an allergic reaction.

Precautionary statements

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

None

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Flammable Liquid, Hazard Category 3 danger: Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 2 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains C12H240, L CARVONE, Ligustral, NEROLEX (SRS) NEROL 900 (BBA), Information: NERYL ACETATE, citronellol, coumarin, geraniol, geranyl acetate, hydroxycitronellal, iso eugenol, pinenes. May produce an allergic reaction. Precautionary P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. statements: P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. 2 Pictograms: 2.3 Other hazards Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 FL 3-SCI 2-SS 1B-AH limonene 5989-27-5 227-813-5 23.62% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- linalool 78-70-6 201-134-4 15.17% SCI 2-EDI 2-SS 1B; H315-H317-H319,- Phenyl Ethyl Alcohol 60-12-8 200-456-2 10.40% ATO 4-EDI 2;H302- H319,- Linalyl Acetate 115-95-7 204-116-4 7.40% SCI 2-SS 1B;H315- H317,- citral 5392-40-5 226-394-6 2.08% SCI 2-EDI 2-SS 1; H315-H317-H319,- Methyl Anthranilate 134-20-3 205-132-4 2.00% EDI 2;H319,- NEROLEX (SRS) 106-25-2 203-378-7 1.80% SCI 2-EDI 2-SS 1B; NEROL 900 (BBA) H315-H317-H319,- DIHYDRO MYRCENOL 18479-58-8 242-362-4 1.70% SCI 2-EDI 2;H315- H319,- citronellol 106-22-9 203-375-0 0.80% SCI 2-EDI 2-SS 1B; H315-H317-H319,- geraniol 106-24-1 203-377-1 0.71% SCI 2-EDI 1-SS 1B; H315-H317-H318,- geranyl acetate 105-87-3 203-341-5 0.70% SCI 2-SS 1B-EH C3; H315-H317-H412,- hydroxycitronellal 107-75-5 203-518-7 0.60% EDI 2-SS 1B;H317- H319,- FL 3-ATO 4-SCI 2-SS pinenes 80-56-8 201-291-9 0.52% 1B-AH 1-EH A1-EH C1;H226-H302-H304- H315-H317-H410,- coumarin 91-64-5 202-086-7 0.40% ATO 4-SS 1B;H302- H317,- NERYL ACETATE 141-12-8 205-459-2 0.40% SS 1B;H317,- Gamma-Terpinene 99-85-4 202-794-6 0.34% FL 3-REP 2-AH 1; H226-H304-H361,- 2 ATO 4-ATD 4-ATI 4- SCI 2-EDI 2-SS 1A- iso eugenol 97-54-1 202-590-7 0.20% STO-SE 3(RI);H302- H312-H315-H317- H319-H332-H335,- SCI 2-SS 1B-EH A1- C12H240 110-41-8 203-765-0 0.10% EH C1;H315-H317- H410,- L CARVONE 6485-40-1 229-352-5 0.10% SS 1B;H317,- SCI 2-EDI 2-SS 1B-EH Ligustral 68039-49-6 268-264-1 0.10% C2;H315-H317-H319- H411,- Substances with Community workplace exposure limits: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 2 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. 7.2 Conditions for safe storage, including any incompatibilities: Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection 2 Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Not determined Odour: Not determined Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 46 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard Vapour pressure: Not determined Vapour density: Not determined Relative density: Not determined Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 2 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). Acute Toxicity: Based on available data the classification criteria are not met. Acute Toxicity Oral >5000 Acute Toxicity Dermal >5000 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Skin Corrosion / Irritation Category 2 Serious eye damage/irritation: Eye Damage / Irritation Category 2 Respiratory or skin sensitisation: Sensitization - Skin Category 1 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Aspiration Hazard Category 1 Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE LC50/ATE LC50 Dermal Inhalation Route Not Phenyl Ethyl Alcohol 60-12-8 200-456-2 1610 2500 Not available available Refer to Sections 2 and 3 for additional information. Section 12. Ecological information 12.1 Toxicity: Toxic to aquatic life with long lasting effects. 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 2 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6 Other adverse effects: Not available Section 13. Disposal considerations 13.1 Waste treatment methods: Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 14. Transport information 14.1 UN number: UN1169 14.2 UN Proper Shipping Name: EXTRACTS, AROMATIC, LIQUID 14.3 Transport hazard class(es): 3 Sub Risk: - 14.4. Packing Group: III 14.5 Environmental hazards: This is an environmentally hazardous substance. 14.6 Special precautions for user: None additional 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Section 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture None additional 15.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 16. Other information Concentration % Limits: EH C2=10.31% EH C3=1.03% SCI 2=19.32% EDI 2=24.85% SS 1=4.23% AH 1=40.60% Total Fractional Values: EH C2=9.70 EH C3=96.96 SCI 2=5.18 EDI 2=4.02 SS 1=23.62 AH 1=2.46 Key to revisions: SECTION 3: Composition/information on ingredients Key to abbreviations: Abbreviation Meaning AH 1 Aspiration Hazard Category 1 ATD 4 Acute Toxicity - Dermal Category 4 ATI 4 Acute Toxicity - Inhalation Category 4 2 ATO 4 Acute Toxicity - Oral Category 4 EDI 1 Eye Damage / Irritation Category 1 EDI 2 Eye Damage / Irritation Category 2 EH A1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 EH C1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 FL 3 Flammable Liquid, Hazard Category 3 H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H361 Suspected of damaging fertility or the unborn child (exposure route). H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical, ventilating and lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing vapour or dust. P264 Wash hands and other contacted skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/eye protection/face protection. P301/310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301/312 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. P302/352 IF ON SKIN: Wash with plenty of soap and water. P303/361/353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. 2 P305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308/313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P312 Call a POISON CENTRE or doctor/physician if you feel unwell. P330 Rinse mouth. P331 Do not induce vomiting. P332/313 If skin irritation occurs: Get medical advice/attention. P333/313 If skin irritation or rash occurs: Get medical advice/attention. P337/313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391 Collect spillage. P403/233 Store in a well-ventilated place. Keep container tightly closed. P403/235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container to approved disposal site, in accordance with local regulations. REP 2 Toxic to Reproduction Category 2 SCI 2 Skin Corrosion / Irritation Category 2 SS 1 Sensitization - Skin Category 1 SS 1A Sensitization - Skin Category 1A SS 1B Sensitization - Skin Category 1B STO-SE 3(RI) Specific Target Organ Toxicity (Single Exposure) Category 3 The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions, recommendations and/or suggestions are made without guarantee.