Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent

Hazard statements (CLP)

H225, H226, H304, H312, H315, H317, H319, H332, H361d, H372, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

STYRENE any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency characteristic 74 14.6. Special precautions for user. Odour threshold. Acute effects stinging eyes. Symptoms may include rubescence, edema, pain and lachrymation procedures. CAS. Type 100-42-5 Country 12 - 13,5 TWA/8h Flam. Liq. 3 H226, Repr. 2 H361d, Acute Tox. 4 H332, STOT RE 1 H372, Eye Irrit. 2 H319, Not available. STEL/15min 12.4. Mobility in soil.

2.1 Classification of the substance or mixture

LEGEND: pH. Ingestion may cause health problems, including stomach pain and sting, nausea and sickness. mg/m3 ppm Not available. mg/m3 ppm STYRENE: slightly mobile in soil. - ADR: European Agreement concerning the carriage of Dangerous goods by Road Skin Irrit. 2 H315, Note D 6.2. Environmental precautions. Melting point / freezing point. Acute effects contact with skin may cause irritation, erythema, edema, dryness and chapped skin ADR / RID: EC. VLEP 202-851-5 BEL HIN - Kemler: 30 221 50 Not available. 442 Limited Quantities - 100 Tunnel restriction code - SKIN. - CAS NUMBER: Chemical Abstract Service Number The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments Initial boiling point. Ingestion may cause health disorders, including stomach pain and sting, nausea and sickness. The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments VLA ESP

Special Provisions

221 50 Not available. 442 100 SKIN. The product must not penetrate into the sewer system or come into contact with surface water or ground water. - CE50: Effective concentration (required to induce a 50% effect) and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and INDEX. 601-026-00-0 Boiling range. This product contains sensitizing substance/s and may cause allergic reactions. IMDG: XYLENE (MIXTURE OF ISOMERS) VLEP FRA EMS: F-E, S-E 221 50 Not available. 442 Limited Quantities - 100 SKIN. 6.3. Methods and material for containment and cleaning up. subsequent amendments. XYLENE (MIXTURE OF ISOMERS) - CE NUMBER: Identifier in ESIS (European archive of existing substances) Flash point. IATA: subsequent amendments. WEL GRB Cargo: 220 50 23 ≤ T ≤ 60 441 Maximum quantity: - 100 °C. Packaging instructions: - Partition coefficient: soil/water. - CLP: EC Regulation 1272/2008 CAS. 1330-20-7 0,05 - 0,1 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Skin Irrit. 2 H315, Note C 2,73 Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Evaporation Rate XYLENE (MIXTURE OF ISOMERS): has a toxic effect on the CNS (encephalopathies). Irritating to the skin, conjunctivae, cornea and Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the OEL IRL Pass.: 221 50 Not available. 442 Maximum quantity: - 100 Packaging instructions: - SKIN. - DNEL: Derived No Effect Level EC. 215-535-7 Flammability of solids and gases respiratory apparatus. remainder with inert absorbent material. INDEX. TLV 601-022-00-9 ITA Special Instructions: 221 50 Not available. 442 - 100 SKIN. Hazard classification and indication: STYRENE - EmS: Emergency Schedule Lower inflammability limit. ETHYLBENZENE: like the benzene homologues, may exert an effect on the CNS with depression, narcosis, often preceded by dizziness and Hazard classification and indication: Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed OEL EU 221 50 Not available. 442 100 SKIN. BIS(2-ETILESANOATO) DI COBALTO Partition coefficient: soil/water. - GHS: Globally Harmonized System of classification and labeling of chemicals Flammable liquid, category 3 2,55 H226 Flammable liquid and vapour. 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. Upper inflammability limit. accompanied by headache. It is irritating to the skin, conjunctivae and respiratory apparatus. of in compliance with the provisions set forth in point 13. CAS. TLV-ACGIH 136-52-7 0,05 - 0,1 434 Skin Irrit. 2 H315, Skin Sens. 1A H317 100 Not available. 651 150 - IATA DGR: International Air Transport Association Dangerous Goods Regulation Reproductive toxicity, category 2 H361d Suspected of damaging the unborn child. Lower explosive limit. STYRENE: Acute toxicity following inhalation at 1000 ppm involves the central nervous system with headache and dizziness, lack of Not available.

Results of PBT and vPvB assessment

IC50: Immobilization Concentration 50% Upper explosive limit. coordination; irritation of the mucous membranes of the eyes and respiratory tract occurs at 500 ppm concentrations. Chronic exposure Information not relevant. EC. Specific target organ toxicity - repeated exposure, category Specific target organ toxicity - repeated exposure, category Not available. H372 Causes damage to organs through prolonged or repeated 6.4. Reference to other sections. - IMDG: International Maritime Code for dangerous goods INDEX. 1 exposure. Vapour pressure. produces depression of the Central and peripheral nervous system with loss of memory, headache and somnolence starting at 20 ppm; ETHYLBENZENE Any information on personal protection and disposal is given in sections 8 and 13. Not available. ETHYLBENZENE On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - IMO: International Maritime Organization Threshold Limit Value. Vapour density digestive disorders with nausea and loss of appetite; irritation of the respiratory tract with chronic bronchitis and dermatosis. Eye irritation, category 2 Not available. H319 Causes serious eye irritation. SECTION 15. Regulatory information. - INDEX NUMBER: Identifier in Annex VI of CLP CAS. Skin irritation, category 2 100-41-4 0 - 0,05 Flam. Liq. 2 H225, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373 H315 Causes skin irritation. Relative density. EC. Type 202-849-4 Country TWA/8h Not available. STEL/15min

Other hazards

SECTION 7. Handling and storage. - LC50: Lethal Concentration 50% Solubility mg/m3 ppm Not available. mg/m3 ppm

2.2 Label elements

LD50: Lethal dose 50% INDEX. 601-023-00-4 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. Partition coefficient: n-octanol/water XYLENE (MIXTURE OF ISOMERS) VLEP BEL 442 100 Not available. 551 125 SKIN. 7.1. Precautions for safe handling. Information not available. - OEL: Occupational Exposure Level Auto-ignition temperature. LD50 (Oral). VLA ESP 441 3523 mg/kg Rat 100 Not available. 884 200 SKIN. Note: Upper limit is not included into the range.

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may Decomposition temperature. LD50 (Dermal). Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. VLEP FRA 88,4 4350 mg/kg Rabbit 20 Not available. 442 100 SKIN. Seveso category. The full wording of hazard (H) phrases is given in section 16 of the sheet. - PEC: Predicted environmental Concentration 6 accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. Viscosity LC50 (Inhalation). WEL GRB 441 26 mg/l/4h Rat SECTION 13. Disposal considerations. - PEL: Predicted exposure level

Hazard pictograms

Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which 100 Not available. 552 125 SKIN. Explosive properties Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. - PNEC: Predicted no effect concentration OEL IRL 442 100 Not available. 884 200 SKIN. 13.1. Waste treatment methods.