BIBLIOGRAPHY

Hazard statements (CLP)

H302, H314, H317, H318, H319, H332, H400, H410, H411, H412

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

286/2011 (II has in the penetrate presence Atp. Wear into of the symptoms criteria not CLP) protective been for of this sewer system the performed European gloves/ contact or a come not class for protective available Parliament doctor into and contact the preparation/for clothing show him mg/kg/d / eye with this the protection surface substances document. water or ground water. / face indicated protection. in section 3. 1.2. 12.4. Partition 6. Relevant In case of more severe symptoms, ask for immediate medical aid. Regulation Mobility P310 Inhalation coefficient: identified in (EU) soil 618/2012 n-octanol/water uses of (III the Immediately Atp. substance CLP) of the call or European a mixture POISON not available and Parliament CENTER uses advised / doctor 2,717 against / . . . 11,02 6.3. 14.4. EYES: Vapour CARCINOGENICITY 7. Regulation Information Methods Packing P264 pressure Remove, and on group (EU) 487/2013 (IV Wash likely material if present, routes for of contact containment exposure Atp. CLP) lenses if and . . . thoroughly of the European the situation cleaning allows not after available up handling. Parliament mg/m3 you to do so easily. Wash immediately with plenty of water for at least 15 SECTION Intended Density Information 8. Regulation P273 Skin and/or use not (EU)

Further information

relative available 944/2013 density (V Atp. Avoid CLP) release mg/m3 of the to European the Primer environment. 1 Parliament epossidico g/cm3 3,125 bicomponente Method:Picnometro 6,25 minutes, opening the eyelids fully. Get medical advice/attention. Relative Does 9. Regulation SKIN: Collect Information ADR Text of / Take P301+P330+P331 not vapour RID, the meet (EU) leaked not IMDG, off (H) the density immediately available indications classification product 605/2014 (VI IF IATA into all mentioned contaminated a suitable criteria Atp. SWALLOWED II CLP) for of this the hazard in container section clothing European Rinse 2-3 Evaluate not class Wash of the immediately available mouth Parliament sheet the compatibility Do NOT mg/kg/d and thoroughly induce vomiting of the container with running to be used, water by (and checking soap if section possible) Absorb mg/kg/d Get the Particle Details medical remainder advice/attention P391 Regulation characteristics of the (EU) with inert absorbent supplier 2015/1221 Avoid material of the (VII further contact with contaminated clothing Collect safety Atp. data spillage CLP) sheet of the European not applicable Parliament Legend INGESTION REPRODUCTIVE Results Make Delayed Environmental Acute Regulation sure and Tox the immediate of PBT Do leakage EU) TOXICITY not hazards and 2016/918 induce site vPvB (VIII effects is vomiting well as Acute assessment well Atp. CLP) of the European Parliament aired unless toxicity, as Contaminated chronic explicitly category effects authorised material from short should by and a doctor be long-term disposed Rinse exposure your of in mouth compliance with running with the water provisions Do not set give forth anything in point by 13 Name C) Regulation CEILING (EU) INHAL 2016/1179 Inhalable IX Atp. Fraction CLP) RESP DRACO Respirable ITALIANA Fraction S.p.A. ; THORA = Thoracic Fraction mouth Skin to Corr an unconscious 1B person. Skin Get corrosion, medical advice/attention category 1B Full VND Does On Contains the Regulation address not hazard basis meet of identified the EU) available classification 2017/776 but data, no (X the DNEL/PNEC M-PHENYLENEBIS criteria Atp. product CLP) for this does available hazard not contain Via METHYLAMINE) class Monte NEA any = Grappa, PBT no exposure or vPvB D-E in expected percentage ≥ NPI than = no 0,1% hazard identified ; LOW = low hazard INHALATION Information ADR Reference Skin RID Corr not to Remove 1C available other sections Environmentally victim to Skin fresh corrosion, air, Hazardous away category from the accident 1C scene. In the event of respiratory symptoms (coughing, wheezing, District MED Regulation and medium Country EU) hazard 2018/669 HIGH XI 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE Atp. = high CLP) hazard. 20067 Tribiano MI) breathing Eye Dam difficulty, asthma) keep Serious the victim eye in damage, a comfortable category position for breathing. If necessary administer oxygen. If the subject stops 12.6. STOT Other breathing, Any Interactive Endocrine Eye Regulation information SINGLE Irrit. administer information effects on personal disrupting EU) EXPOSURE 2019/521 artificial protection properties respiration XII Acido Eye irritation, Atp. grassi CLP) C18 insaturi, prodotti di Italia and Get disposal medical category is advice/attention given in sections 8 and 13 reazione con tetraetilenpentammina 16. Exposure Skin Sens. 1A Delegated controls Regulation (UE) 2018/1480 BENZYL ALCOHOL Skin sensitization, category 1A XIII Atp. CLP) Tel 39 02.90632917 Does Based IMDG Regulation Rescuer Information Skin Sens not on meet protection the available not available the EU) classification 1B 2019/1148 Marine data, the Pollutant Skin sensitization, category 1B criteria product for does this not hazard contain Fax class substances 39 listed 02.90631976 in the main European lists of potential or suspected endocrine SECTION e-mail As disruptors the Aquatic Acute 1 Delegated Information address use with of 7. adequate Regulation environmental of Handling the with competent regard technical UE) and effects to 2020/217 Hazardous to the aquatic environment, acute toxicity, category 1 physical person equipment storage under (XIV hazard evaluation must Atp. classes always CLP) take priority over personal protective equipment, make sure that the workplace is responsible The well STOT Delegated product aired REPEATED through for is Regulation classified the effective Safety EXPOSURE both UE) Data local in 2020/1182 Sheet acute aspiration and (XV long-term Atp. CLP) info@draco-edilizia.it aquatic hazard categories: it is possible to use only hazard statement H410 on the Precautions for safe handling It ACUTE is Aquatic good TOXICITY practice Chronic for 1 rescuers lending Hazardous support to the to a aquatic person environment, who has been chronic exposed toxicity, to a chemical category substance or to a mixture to wear personal 12.7. label When Information 20. Other protective Aquatic equipment Delegated choosing adverse not Regulation Chronic 2 The nature Hazardous available personal effects protective UE) 2021/643 of such protection equipment, XVI Atp. ask CLP) to the aquatic your chemical substance supplier for advice depends

Environmental hazards

on the hazard chronic level toxicity, of the substance category 2 or mixture, on the type of exposure and on Supplier Personal Does IATA 21. Delegated not protective meet Regulation the classification equipment NO (UE) must 2021/849 criteria be CE for (XVII this marked, Atp hazard CLP) showing DRACO class that ITALIANA it complies S.p.A with applicable standards the ATE Aquatic Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the extent Inhalation of Chronic the - contamination mists 3 / powders) In Hazardous of the the absence mixture to the of aquatic other more specific mg/l indications, chronic toxicity, use of category disposable 3 gloves in the event of possible contact Provide Information 22. Delegated with ATE H302 body Inhalation Other an emergency fluids is - vapours) not safety Regulation available recommended characteristics shower UE) with of the Harmful 2022/692 mixture For the if type face and XVIII eye Atp. wash CLP) swallowed of PPE suitable > for 20 mg/l station the characteristics of the substance or mixture, see section 8 environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering HAND ASPIRATION For 23. Emergency Other Delegated Air PROTECTION transport, hazards HAZARD telephone Regulation environmentally number UE) 2023/707 hazardous mark is only mandatory for UN 3077 and UN 3082 ATE H332 places Oral) of the mixture people Harmful if inhaled 1644,11 mg/kg Protect VOC 24. Delegated Directive in hands which with Regulation 2010/75/EU) category eat. (UE) III work 2023/1434 gloves. (XIX Atp. CLP) 20,00 % - 200,00 ATE SECTION Most H314 Dermal) important Disposal considerations g/litre of the symptoms mixture: and Causes effects, severe both skin acute burns and and delayed Not eye classified damage. (no significant component) On For The VOC Does 24. Special the Delegated urgent following volatile not basis meet inquiries precautions of should carbon) Regulation the available classification refer be considered for to data, UE) user the 2023/1435 criteria product when for choosing XX this does Atp hazard not CLP) work UE contain 15,54 class general glove % any material PBT number 155,35 or (see vPvB 112 standard in (Available g/litre percentage EN 374) 24h than compatibility, Safety 0,1%. Data Sheets degradation, Conditions for safe storage, including any incompatibilities H318 or Product permeability Information time Causes serious eye damage Specific The work gloves' resistance to chemical agents should could Corrosive Waste H319 information to treatment the respiratory on methods symptoms tract. Causes and effects serious caused eye irritation by the product are unknown be checked not available before for use, emergency as it can be service) unpredictable. The gloves' wear time depends on The the ADR The Information H317 duration product Merck RID: and Index does on type not other 10th of contain use hazards Edition substances May cause an allergic skin reaction HIN - Kemler with endocrine 80 disrupting Limited SECTION Store only in 10 Protect Handling properties Quantities your Chemical in concentration hands with the original lt Stability Safety gloves of the container 0.1%. Tunnel restriction code: (E) and Store Special reactivity following the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away provision type: 274 SECTION DELAYED Reuse, from any incompatible materials, see section 10 for details IMDG H400 Acido when EFFECTS possible grassi Hazards C18 Based Product insaturi, identification on residues Very the EMS: F-A, prodotti information toxic should di to reazione aquatic currently be considered life con available, tetraetilenpentammina special there hazardous Quantities are no known waste. cases The hazard of delayed level effects of waste following containing exposure this product to this product Material Based INRS on should Reactivity H410 be LD50 Fiche Nitrile the available evaluated Oral): according to Very Toxicologique rubber (NBR) data, (toxicological the product applicable toxic to regulations does sheet) S-B not contain substances aquatic life with > long 2000 lasting Limited listed mg/kg effects in the main lt European lists of potential or suspected endocrine The Composition/information on ingredients disruptors IATA Patty following Industrial with should human of Hygiene the be health considered and effects Toxicology Cargo or when under choosing evaluation. work glove material Maximum compatibility, quantity: 30 L degradation, permeability Packaging time instructions: 855 Disposal Classification H411 must be performed through substance Toxic an to authorised mixture aquatic life waste with long management lasting effects firm, in compliance with national and local regulations Specific end use(s) Thickness N.I. Sax - Dangerous 0,3 mm properties of Passengers Industrial Materials-7, 1989 Edition Maximum quantity: 1 L Packaging instructions: 851 4.3. There Ecological information Waste Mixtures Indication H412 are transportation BENZYL no of particular any ALCOHOL immediate may risks be of subject reaction medical Harmful to ADR with to attention aquatic other restrictions substances and life with special long in treatment normal lasting effects conditions needed of use The Glove IFA product CONTAMINATED EUH071 GESTIS thickness LD50 (Dermal) is website classified must be as selected Special PACKAGING Corrosive to the respiratory tract hazardous based pursuant on provision the minimum to the provisions required A3, set breakthrough 2000 mg/kg Rabbit A803 forth in (EC) time recovered product doctor or thus and disposed requires highly of toxic in a 1230 safety compliance for aquatic mg/kg datasheet Rat organisms with national that complies In waste the long with management term, the provisions it has regulations negative of (EU) effects Regulation on the aquatic 14.7. 2020/878 Glove Database environment. Maritime Decomposes resistance LC50 (Inhalation of transport SDS depends at temperatures models in bulk vapours): above 870°C/1598°F.Possibility on for various chemicals according elements, to Ministry IMO such instruments of Health as temperature and ISS (Istituto 4,1 of mg/l/4h explosion and other Rat Superiore environmental di Sanità) factors Italy SECTION SKIN PROTECTION Any Identification Means LEGEND Chemical additional to ATE have 8. (Inhalation stability information available Exposure vapours) in concerning the controls/personal workplace x the Conc for risks specific % for health and immediate protection and/or Classification mg/l the treatment estimate (EC) should be of the conventional hydrobromic di reazione 20 of classification x chronic acid,iron,oxidising con 40 tetraetilenpentammina FATTY ACIDS and labeling kind: C18 carbon Acute 500 agents,sulphuric mg/kg of Tox UNSAT., chemicals estimate H410 dioxide, H302, acid.Risk REACTION foam, powder from Acute table Very Tox PRODUCTS of 3.1.2 explosion toxic H332, and water WITH of to Annex aquatic Eye on contact spray. TEPA) Irrit I of life the 2 with H319, CLP with: long phosphorus Skin lasting Sens effects 1B H317 concentration CALCULATION (see METHODS EC LC50 Restrictions IATA toxicity, trichloride DGR for Fish category relating International 202-859-9 standard FOR to 1 the Air product Transport EN 14387) CLASSIFICATION or contained Association substances Dangerous 0,19 pursuant LD50 figure mg/l/96h Goods Oral used Regulation to Annex 1230 for calculation mg/kg, XVII to ATE EC of the Regulation Inhalation acute toxicity

2.2 Label elements

FRA Product classification is based on calculation 0,1 methods as per Annex I of CLP, Part 4, unless determined otherwise in pursuant Regulation

Precautionary statements

used (CLP) for 20,3 chemical 2500 mg/l/72h mg/kg products Pseudokirchnerella ratto, should femminile be respected. subcapitata compliance Regulation Section CAS - LD50: LC50 TLV-ACGIH Lethal 12. with environmental standards. (EU) (Inhalation dose 61788-44-1 2019/1148 50% vapours): - on the marketing and use of explosives 158,3 mg/l/4h 0,018 (C) precursors topo, maschile SKIN Do not breathe combustion products. Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. 12.2. REACH BENZYL not - OEL: Persistence applicable Occupational P260 Do not breathe dust / fume / gas / mist / vapours / spray. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P310 Immediately call a POISON CENTER / doctor / . . . P264 Wash . . . thoroughly after handling. P273 Avoid release to the environment. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P391 Collect spillage.

Hazard pictograms

Reg. ALCOHOL 01-2119979575-18-XXXX and degradability Exposure Level Changes to previous review: M-PHENYLENEBIS SKIN

PBT Substances

Avoid CORROSION Persistent, exposure bioaccumulative to: / (METHYLAMINE) IRRITATION air,sources of and heat,naked toxic flames. 5.3. Advice for firefighters The following sections were modified: INDEX 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE Substances - PEC: Predicted in Candidate environmental List (Art. Concentration 59 9 REACH) ≤ x < 20 Acute Tox. 4 H302, Acute Tox. 4 H332, Skin Corr. 1B H314, Eye Dam. 1 H318, 01 / 02 / 03 / 07 / 08 / 09 / 10 / 11 / 12 / 13 / 14 / 15 / 16. Corrosive M-PHENYLENEBIS On - PEL: Avoid the Predicted basis contact for the of available exposure skin with: (METHYLAMINE) strong data, level acids,strong the product oxidants. does not contain any Skin SVHC Sens. in 1B percentage H317, Aquatic ≥ than Chronic SECTION GENERAL INFORMATION 0,1%. 3 H412, EUH071 9. Physical and chemical properties 10.5. EC Solubility - PMT: Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Incompatible Persistent, in water 216-032-5 materials mobile and toxic 1000 ATE - 10000 Oral: mg/l 500 mg/kg, ATE Inhalation mists/powders: 1,5 mg/l CAS Rapidly Substances - PNEC: Acido health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of degradable Predicted subject grassi 1477-55-0 no to C18 effect authorisation insaturi, concentration prodotti (Annex di XIV reazione REACH) con tetraetilenpentammina 9.1. REACH BENZYL None - REACH: contaminated water used for extinction and the remains of the fire according to applicable regulations. Information Corrosive Reg. ALCOHOL Regulation on 01-2119480150-50-xxxx basic to the (EC) physical

Hazard statements

H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract.

Contains

M-PHENYLENEBIS (METHYLAMINE) 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE Acido grassi C18 insaturi, prodotti di reazione con tetraetilenpentammina BENZYL ALCOHOL The product is classified both in acute and long-term aquatic hazard categories: it is possible to use only hazard statement H410 on the label. Identification x = Conc. %

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures

2.1 Classification of the substance or mixture

IATA: into all mentioned contaminated a suitable criteria Atp. SWALLOWED: II CLP) for of this the hazard in container. section clothing. European Rinse 2-3 Evaluate not class Wash of the immediately available mouth. Parliament sheet: the compatibility Do NOT mg/kg/d and thoroughly induce vomiting. of the container with running to be used, water by (and checking soap if section possible). 10. Absorb mg/kg/d Get the 1.3. Particle 10. Details medical remainder advice/attention. P391 Regulation characteristics of the (EU) with inert absorbent supplier 2015/1221 Avoid material. of the (VII further contact with contaminated clothing. Collect safety Atp. data spillage. CLP) sheet of the European not applicable Parliament 12.5. Legend: 14.5. INGESTION: REPRODUCTIVE 11. Results Make Delayed Environmental Acute Regulation sure and Tox. the immediate of PBT Do leakage (EU) TOXICITY 4 not hazards and 2016/918 induce site vPvB (VIII effects is vomiting well as Acute assessment well Atp. CLP) of the European Parliament aired. unless toxicity, as Contaminated chronic explicitly category effects authorised material 4 from short should by and a doctor. be long-term disposed Rinse exposure your of in mouth compliance with running with the water. provisions Do not set give forth anything in point by 13. Name (C) 12. Regulation = CEILING (EU) ; INHAL 2016/1179 = Inhalable (IX Atp. Fraction CLP) ; RESP DRACO = Respirable ITALIANA Fraction S.p.A. ; THORA = Thoracic Fraction. mouth Skin to Corr. an unconscious 1B person. Skin Get corrosion, medical advice/attention. category 1B Full VND Does On 13. Contains: the Regulation address = not hazard basis meet of identified the (EU) available classification 2017/776 but data, no (X the DNEL/PNEC M-PHENYLENEBIS criteria Atp. product CLP) for this does available hazard not contain Via (METHYLAMINE) class ; Monte NEA any = Grappa, PBT no exposure or vPvB 11 D-E in expected percentage ; ≥ NPI than = no 0,1%. hazard identified ; LOW = low hazard 6.4. INHALATION: Information ADR Reference Skin / RID: Corr. not to Remove 1C available other sections Environmentally victim to Skin fresh corrosion, air, Hazardous away category from the accident 1C scene. In the event of respiratory symptoms (coughing, wheezing, District ; 14. MED Regulation and = medium Country (EU) hazard 2018/669 ; HIGH (XI 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE Atp. = high CLP) hazard. 20067 Tribiano (MI) breathing Eye Dam. difficulty, 1 asthma) keep Serious the victim eye in damage, a comfortable category position 1 for breathing. If necessary administer oxygen. If the subject stops 9.2. 12.6. STOT 15. Other breathing, Any Interactive Endocrine Eye Regulation information - SINGLE Irrit. administer information effects 2 on personal disrupting (EU) EXPOSURE 2019/521 artificial protection properties respiration. (XII Acido Eye irritation, Atp. grassi CLP) C18 insaturi, prodotti di Italia and Get disposal medical category is advice/attention. given 2 in sections 8 and 13. reazione con tetraetilenpentammina 8.2. 16. Exposure Skin Sens. 1A Delegated controls Regulation (UE) 2018/1480 BENZYL ALCOHOL Skin sensitization, category 1A (XIII Atp. CLP) Tel. +39 02.90632917 Does Based IMDG: 17. Regulation Rescuer Information Skin Sens. not on meet protection the available not available the (EU) classification 1B 2019/1148 Marine data, the Pollutant Skin sensitization, category 1B criteria product for does this not hazard contain Fax class substances +39 listed 02.90631976 in the main European lists of potential or suspected endocrine SECTION e-mail As 9.2.1. disruptors 18. the Aquatic Acute 1 Delegated Information address use with of 7. adequate Regulation environmental of Handling the with competent regard technical (UE) and effects to 2020/217 Hazardous to the aquatic environment, acute toxicity, category 1 physical person equipment storage under (XIV hazard evaluation. must Atp. classes always CLP) take priority over personal protective equipment, make sure that the workplace is responsible The well STOT 19. Delegated product aired - REPEATED through for is Regulation classified the effective Safety EXPOSURE both (UE) Data local in 2020/1182 Sheet acute aspiration. and (XV long-term Atp. CLP) info@draco-edilizia.it aquatic hazard categories: it is possible to use only hazard statement H410 on the 7.1. Precautions for safe handling It ACUTE is Aquatic good TOXICITY practice Chronic for 1 rescuers lending Hazardous support to the to a aquatic person environment, who has been chronic exposed toxicity, to a chemical category substance 1 or to a mixture to wear personal 12.7. label. When Information 20. Other protective Aquatic equipment. Delegated choosing adverse not Regulation Chronic 2 The nature Hazardous available personal effects protective (UE) 2021/643 of such protection equipment, (XVI Atp. ask CLP) to the aquatic your chemical substance supplier for advice. depends environment, on the hazard chronic level toxicity, of the substance category 2 or mixture, on the type of exposure and on Supplier: Personal Does IATA: 21. Delegated not protective meet Regulation the classification equipment NO (UE) must 2021/849 criteria be CE for (XVII this marked, Atp. hazard CLP) showing DRACO class that ITALIANA it complies S.p.A. with applicable standards. the ATE Aquatic Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the extent (Inhalation of Chronic the - contamination. mists 3 / powders) In Hazardous of the the absence mixture: to the of aquatic other more environment, > specific 5 mg/l indications, chronic toxicity, use of category disposable 3 gloves in the event of possible contact Provide 9.2.2. Information 22. Delegated with ATE H302 body (Inhalation Other an emergency fluids is - vapours) not safety Regulation available recommended. characteristics shower (UE) with of the Harmful 2022/692 mixture: For the if type face and (XVIII eye Atp. wash CLP) swallowed. of PPE suitable > for 20 mg/l station. the characteristics of the substance or mixture, see section 8. 1.4. environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering 2.3. HAND ASPIRATION For 23. Emergency Other Delegated Air PROTECTION transport, hazards HAZARD telephone Regulation environmentally number (UE) 2023/707 hazardous mark is only mandatory for UN 3077 and UN 3082. ATE H332 places (Oral) of the mixture: people Harmful if inhaled. 1644,11 mg/kg Protect VOC 24. Delegated (Directive in hands which with Regulation 2010/75/EU) category eat. (UE) III work 2023/1434 gloves. (XIX Atp. CLP) 20,00 % - 200,00 4.2. ATE SECTION Most H314 (Dermal) important 13. Disposal considerations g/litre of the symptoms mixture: and Causes effects, severe both skin acute burns and and delayed Not eye classified damage. (no significant component) 14.6. On For The VOC Does 24. Special the Delegated urgent following (volatile not basis meet inquiries precautions of should carbon) Regulation the available classification refer be considered for to data, (UE) user the 2023/1435 criteria product when for choosing (XX this does Atp. hazard not CLP) work UE contain 15,54 class general glove % any material - PBT number 155,35 or (see vPvB - 112 standard in (Available g/litre percentage EN 374): 24h. ≥ than compatibility, Safety 0,1%. Data Sheets degradation, 7.2. Conditions for safe storage, including any incompatibilities H318 or Product permeability Information time. Causes serious eye damage. 13.1. Specific The work gloves' resistance to chemical agents should could Corrosive Waste H319 information to treatment the respiratory on methods symptoms tract. Causes and effects serious caused eye irritation. by the product are unknown. be checked not available before for use, emergency as it can be service) unpredictable. The gloves' wear time depends on 11.2. The the ADR - The Information H317 duration product / Merck RID: and Index. does on type not - other 10th of contain use. hazards Edition substances May cause an allergic skin reaction. HIN - Kemler: with endocrine 80 disrupting Limited SECTION Store only in 10. Protect - Handling properties Quantities: your Chemical in concentration hands with the original 1 lt Stability Safety gloves of the container. ≥ 0.1%. Tunnel restriction code: (E) and Store Special reactivity following the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away provision: type: 274 SECTION DELAYED Reuse, from any incompatible materials, see section 10 for details. IMDG: H400 Acido when EFFECTS: 2. possible. grassi Hazards C18 Based Product insaturi, identification on residues Very the EMS: F-A, prodotti information toxic should di to reazione aquatic currently be considered life. con available, tetraetilenpentammina special there hazardous Quantities: are no known waste. cases The hazard of delayed level effects of waste following containing exposure this product to this 10.1. product. Material: Based - INRS on should Reactivity H410 be LD50 - Fiche Nitrile the available evaluated (Oral): according to Very Toxicologique rubber (NBR) data, (toxicological the product applicable toxic to regulations. does sheet) S-B not contain substances aquatic life with > long 2000 lasting Limited listed mg/kg effects. in the main 1 lt European lists of potential or suspected endocrine 2.1. The SECTION 3. Composition/information on ingredients disruptors IATA: - Patty following - Industrial with should human of Hygiene the be health considered and effects Toxicology Cargo: or when under choosing evaluation. work glove material: Maximum compatibility, quantity: 30 L degradation, permeability Packaging time. instructions: 855 Disposal Classification H411 must be performed through substance Toxic an to authorised mixture aquatic life waste with long management lasting effects. firm, in compliance with national and local regulations. 7.3. Specific end use(s) Thickness: - N.I. Sax - Dangerous 0,3 mm properties of Passengers: Industrial Materials-7, 1989 Edition Maximum quantity: 1 L Packaging instructions: 851 3.2. 4.3. There SECTION 12. Ecological information Waste Mixtures Indication H412 are transportation BENZYL no of particular any ALCOHOL immediate may risks be of subject reaction medical Harmful to ADR with to attention aquatic other restrictions. substances and life with special long in treatment normal lasting effects. conditions needed of use. The Glove - IFA product CONTAMINATED EUH071 GESTIS thickness LD50 (Dermal): is website classified must be as selected Special PACKAGING Corrosive to the respiratory tract. hazardous based pursuant on provision: the minimum to the provisions required A3, set breakthrough 2000 mg/kg Rabbit A803 forth in (EC) time. Regulation 1272/2008 (CLP) (and subsequent Information not available Breakthrough - ECHA website time: 30 min amendments Contains: Immediately BENZYL This Contaminated product LD50 ALCOHOL call is and (Oral): packaging dangerous a supplements). POISON must for CENTER the be The environment recovered / product doctor or / thus . and disposed . . requires highly of toxic in a 1230 safety compliance for aquatic mg/kg datasheet Rat organisms. with national that complies In waste the long with management term, the provisions it has regulations. negative of (EU) effects Regulation on the aquatic 14.7. 2020/878. Glove - Database environment. Maritime Decomposes resistance LC50 (Inhalation of transport SDS depends at temperatures models in bulk vapours): above 870°C/1598°F.Possibility on for various chemicals according elements, - to Ministry IMO such instruments of Health as temperature and ISS (Istituto > 4,1 of mg/l/4h explosion. and other Rat Superiore environmental di Sanità) factors. - Italy 10.2. SECTION SKIN PROTECTION Any Identification Means LEGEND: Chemical additional to ATE have 8. (Inhalation stability information available Exposure vapours): in concerning the controls/personal workplace x the = Conc. for risks specific % for health and immediate protection and/or Classification 11 mg/l the treatment environment estimate (EC) from 1272/2008 are table given 3.1.2 in (CLP) of sections Annex 11 I of and the 12 CLP of this sheet. 12.1. - ADR: SECTION Wear Information Toxicity category 14. European Agreement concerning the carriage of Dangerous not II relevant Transport professional long-sleeved information overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body (figure goods used for by calculation Road of the acute toxicity estimate of the mixture) 8.1. with Note soap and water after removing protective clothing. Hazard Acido Running The - ATE: product Control for users: Acute grassi classification water is Toxicity parameters C18 stable for skin insaturi, Estimate and in and normal indication: eye prodotti conditions wash. di reazione of use and con storage. tetraetilenpentammina 14.1. UN number or ID number EYE The information PROTECTION contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the SECTION 15. Regulatory information INDEX - CAS: Acute Chemical 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE toxicity, Abstract category Service 4 Number 25 ≤ x < 40 Skin Corr. H302 1C H314, Eye Dam. Harmful 1 H318, if swallowed. Skin Sens. 1A H317, Aquatic Acute 1 10.3. Fenolo, Regulatory Wear suitability - CE50: Possibility Skin airtight LD50 stirenato Effective corrosion, and references: protective (Oral): thoroughness of hazardous concentration reactions category goggles 1B of provided (required to induce a 50% effect) (see standard information EN ISO according 16321). to each specific use of the product. H400 1030 mg/kg M=1, H314 Aquatic Chronic Causes 2 H411 severe skin burns and eye damage. SECTION ADR / RID, IMDG, IATA: In This the document presence 5. Firefighting must of risks not of be exposure regarded measures UN 2735 to as splashes a guarantee or squirts on any during specific work, product adequate property. mouth, nose and eye protection should be used to prevent EC LC50 - CE: Serious Identifier - for Fish eye in damage, 629-725-6 ESIS (European category archive 1 of existing substances) 5,6 mg/l/96h Brachydanio H318 rerio Causes serious eye damage. 15.1. CAS accidental absorption. FRA The No EC50 - CLP: Regulation 1226892-45-0 Safety, Skin hazardous use - for M-PHENYLENEBIS sensitization, of this product health Crustacea reactions and France (EC) category environmental 1272/2008 is not subject to our Valeurs are foreseeable (METHYLAMINE) 1A regulations/legislation in normal conditions direct control; limites therefore, 4,6 of mg/l/48h d'exposition users use specific and Dafnie professionnelle H317 storage. for the substance must, under aux their agents May or cause own responsibility, mixture chimiques en comply an allergic skin reaction. FranceDécret with the n° current 2021-1849 health 5.1. 14.2. Extinguishing RESPIRATORY and safety laws and UN proper shipping PROTECTION media name regulations. The producer is relieved from any liability arising from improper uses. REACH EC50 - DNEL: Hazardous - for LD50 Reg. Derived Algae (Dermal): to / Aquatic Plants 01-2119487006-38-XXXX No the Effect aquatic Level environment, acute toxicity, du 28 décembre 9,7 2021 3100 mg/l/72h mg/kg Alga H400 Rat Very toxic to aquatic life. Respiratory Provide appointed BENZYL Seveso - EmS: category Emergency LD50 Category ALCOHOL protection 1 (Oral): - Directive staff TLV-ACGIH Schedule 2012/18/EU: devices with adequate must be training used ACGIH if on the how 2023 technical to use measures chemical products. > 200 mg/kg E1 Rat - Sprague-Dawley adopted are not suitable for restricting the worker's exposure to the SUITABLE ADR / RID: EXTINGUISHING threshold values considered. Use a mask with a type A filter whose class (1, 2 or 3) must be chosen according to the limit of use AMINES, EQUIPMENT LIQUID, CORROSIVE, N.O.S. (3-AMINOMETHYL-3,5,5- TRIMETHYLCYCLOHEXYLAMINE INDEX Acido - GHS: The extinguishing equipment Hazardous May grassi Globally ATE react (Oral): C18 dangerously to 603-057-00-5 Harmonized the insaturi, aquatic M-XYLYLENEDIAMINE prodotti with: System environment, should be of the conventional hydrobromic di reazione 20 of classification ≤ x chronic < acid,iron,oxidising con 40 tetraetilenpentammina FATTY ACIDS and labeling kind: C18 carbon Acute