WALLSEAL WHITE

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H330, H331, H400, H410, H411

Code

Statements

H301

Toxic if swallowed

ECOLOGICAL INFORMATION

Flash point Information not available Skin Irrit. 2 Skin irritation, category 2 > 60 °C - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Evaporation Rate Skin Sens. 1 Skin sensitization, category 1 Not available 4.1. Description of first aid measures 14.2. UN proper shipping name - IFA GESTIS website

2.1 Classification of the substance or mixture

Flammability of solids and gases Delayed and immediate effects as well as chronic effects from short and long-term exposure No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil and Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1 Not available Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Vapours may catch fire and an explosion may - ECHA website Lower inflammability limit waterways. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. Please take all the Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1 Not available EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem occur; vapour accumulation is therefore to be avoided by leaving windows and doors open and ensuring good cross ventilation. Without Not applicable - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Upper inflammability limit Information not available proper measures to reduce harmful effects on aquifers. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2 Not available persists, seek medical advice. adequate ventilation, vapours may accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Lower explosive limit However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data H330 Fatal if inhaled. Not available 14.3. Transport hazard class(es) SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention immediately. Wash contaminated bunching of electrostatic charges. When performing transfer operations involving large containers, connect to an earthing system and wear 12.1. Toxicity sheet with appropriate information, compliant to (EU) Regulation 2015/830. Upper explosive limit Interactive effects sheet with appropriate information, compliant to (EU) Regulation 2015/830. H301 Toxic if swallowed. Not available clothing before using it again. antistatic footwear. Vigorous stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic Note for users: Vapour pressure INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention immediately. charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they Not applicable H311 Toxic in contact with skin. 23 mmHg Hazard classification and indication: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the Vapour density Information not available Hazard classification and indication: H331 Toxic if inhaled. -- Not available INGESTION: Get medical advice/attention immediately. Do not induce vomiting. Do not administer anything not explicitly authorised by a may be pressurised. Do not eat, drink or smoke during use. Avoid leakage of the product into the environment. suitability and thoroughness of provided information according to each specific use of the product. 14.4. Packing group Relative density ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL doctor. H302 Harmful if swallowed. 1,40 This document must not be regarded as a guarantee on any specific product property. 7.2. Conditions for safe storage, including any incompatibilities Solubility ACUTE TOXICITY LC50 - for Fish H314 Causes severe skin burns and eye damage. 33 mg/l/96h Pimephales promelas WATER

2.2 Label elements

The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Partition coefficient: n-octanol/water EC50 - for Crustacea H318 Causes serious eye damage. 147,8 mg/l/48h Daphnia magna Not available 4.2. Most important symptoms and effects, both acute and delayed Not applicable and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Auto-ignition temperature LC50 (Inhalation) of the mixture: EC50 - for Algae / Aquatic Plants Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a well ventilated H315 Causes skin irritation. > 57 mg/l/72h Pseudokirchnerella subcapitata Not available Not classified (no significant component) Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Provide appointed staff with adequate training on how to use chemical products. Decomposition temperature LD50 (Oral) of the mixture: Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. H317 May cause an allergic skin reaction. Not available Not classified (no significant component)

Environmental hazards

Specific information on symptoms and effects caused by the product are unknown. place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any 12.2. Persistence and degradability Viscosity LD50 (Dermal) of the mixture: H400 Very toxic to aquatic life. 110-120 KU Not classified (no significant component) incompatible materials, see section 10 for details. Changes to previous review:

Hazard pictograms

Explosive properties H410 Very toxic to aquatic life with long lasting effects. -- Not available 4.3. Indication of any immediate medical attention and special treatment needed Not applicable The following sections were modified: 7.3. Specific end use(s) Oxidising properties H411 Toxic to aquatic life with long lasting effects. Not available

Signal word

01 / 02 / 03 / 07 / 11 / 16. CALCIUM CARBONATE EUH210 reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) Safety data sheet available on request. -- 14.6. Special precautions for user Information not available

Further information

Solubility in water Information not available LD50 (Oral) 0,1 - 100 mg/l 481 mg/kg

Hazard statements

LD50 (Dermal) > 1,008 mg/kg Not applicable SECTION 5. Firefighting measures VOC (Directive 2004/42/EC) : TALC LEGEND: EUH210 LC50 (Inhalation) Safety data sheet available on request. 1,41 % - 19,70 1,23 mg/l/4h g/litre SECTION 8. Exposure controls/personal protection Gloss Solubility in water - ADR: European Agreement concerning the carriage of Dangerous goods by Road EUH208

Contains

reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one < 0,1 mg/l 3 (60) 14 (85) 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code 5.1. Extinguishing media - CAS NUMBER: Chemical Abstract Service Number CALCIUM CARBONATE (3:1) TITANIUM DIOXIDE - CE50: Effective concentration (required to induce a 50% effect) LD50 (Oral) 1,2-Benzoisothiazol-3(2H)-one 6450 mg/kg Rat 8.1. Control parameters SECTION 10. Stability and reactivity Information not relevant SUITABLE EXTINGUISHING EQUIPMENT Solubility in water - CE NUMBER: Identifier in ESIS (European archive of existing substances) May produce an allergic reaction. < 0,001 mg/l The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. Degradability: information not available - CLP: EC Regulation 1272/2008 TITANIUM DIOXIDE 10.1. Reactivity UNSUITABLE EXTINGUISHING EQUIPMENT TLV of solvent mixture: 1,03 mg/m3 SECTION 15. Regulatory information - DNEL: Derived No Effect Level LD50 (Oral) > 10000 mg/kg Rat

Precautionary statements

None in particular. ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - EmS: Emergency Schedule -- 8.2. Exposure controls There are no particular risks of reaction with other substances in normal conditions of use. Solubility in water - GHS: Globally Harmonized System of classification and labeling of chemicals ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL 1360 mg/l 5.2. Special hazards arising from the substance or mixture 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC (Directive 2004/42/EC) : Rapidly degradable - IATA DGR: International Air Transport Association Dangerous Goods Regulation VOC (Directive 2004/42/EC) : LD50 (Oral) 6500 mg/kg Rat - Carworth-Wistar CALCIUM CARBONATE As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Coatings for exterior walls of mineral substrate. - IC50: Immobilization Concentration 50% Coatings for exterior walls of mineral substrate. LD50 (Dermal) > 15200 mg/kg Rabbit - New Zeland white HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE well aired through effective local aspiration. Seveso Category - Directive 2012/18/EC: Decomposes at temperatures above 800°C/1472°F. None 12.3. Bioaccumulative potential VOC given in g/litre of product in a ready-to-use condition : - IMDG: International Maritime Code for dangerous goods VOC given in g/litre of product in a ready-to-use condition : 11,74 Limit value: Do not breathe combustion products. When choosing personal protective equipment, ask your chemical substance supplier for advice. SKIN CORROSION / IRRITATION - IMO: International Maritime Organization Limit value: 40,00 10.2. Chemical stability - Thinned with : Personal protective equipment must be CE marked, showing that it complies with applicable standards. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 - INDEX NUMBER: Identifier in Annex VI of CLP - Thinned with : 10,00 % WATER 5.3. Advice for firefighters HAND PROTECTION None Does not meet the classification criteria for this hazard class ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - LC50: Lethal Concentration 50% The product is stable in normal conditions of use and storage. Protect hands with category III work gloves (see standard EN 374). Partition coefficient: n-octanol/water - LD50: Lethal dose 50% 3,2

2.3 Other hazards

GENERAL INFORMATION The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Substances in Candidate List (Art. 59 REACH) SERIOUS EYE DAMAGE / IRRITATION BCF - OEL: Occupational Exposure Level 44,1 10.3. Possibility of hazardous reactions Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%.

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of the duration and type of use. Does not meet the classification criteria for this hazard class - PEC: Predicted environmental Concentration On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. EPY 9.6.6 - SDS 1004.9