WALLSEAL BASE03

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H331, H400, H410, H411

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

1272/2008 Flash point Information not available No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil and H301 Toxic if swallowed. > 60 °C Note for users: Evaporation Rate waterways. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. Please take all the H311 Toxic in contact with skin. Not available 4.1. Description of first aid measures Not applicable The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the

2.1 Classification of the substance or mixture

Flammability of solids and gases Delayed and immediate effects as well as chronic effects from short and long-term exposure proper measures to reduce harmful effects on aquifers. H331 Toxic if inhaled. Not available Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Vapours may catch fire and an explosion may suitability and thoroughness of provided information according to each specific use of the product. Lower inflammability limit H302 Harmful if swallowed. Not available 14.4. Packing group EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem occur; vapour accumulation is therefore to be avoided by leaving windows and doors open and ensuring good cross ventilation. Without This document must not be regarded as a guarantee on any specific product property. 12.1. Toxicity The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Upper inflammability limit Information not available The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). H314 Causes severe skin burns and eye damage. Not available persists, seek medical advice. adequate ventilation, vapours may accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Lower explosive limit However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data H318 Causes serious eye damage. Not available SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention immediately. Wash contaminated bunching of electrostatic charges. When performing transfer operations involving large containers, connect to an earthing system and wear Not applicable and safety laws and regulations. The producer is relieved from any liability arising from improper uses. sheet with appropriate information, compliant to (EU) Regulation 2015/830. Upper explosive limit Interactive effects sheet with appropriate information, compliant to (EU) Regulation 2015/830. H315 Causes skin irritation. Not available clothing before using it again. antistatic footwear. Vigorous stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic Provide appointed staff with adequate training on how to use chemical products.

Environmental hazards

Vapour pressure ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention immediately. charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they H317 May cause an allergic skin reaction. 23 mmHg Hazard classification and indication: Vapour density Information not available LC50 - for Fish Hazard classification and indication: H400 Very toxic to aquatic life. -- 33 mg/l/96h Pimephales promelas Not available INGESTION: Get medical advice/attention immediately. Do not induce vomiting. Do not administer anything not explicitly authorised by a may be pressurised. Do not eat, drink or smoke during use. Avoid leakage of the product into the environment. Changes to previous review: Relative density EC50 - for Crustacea doctor. Not applicable H410 Very toxic to aquatic life with long lasting effects. 147,8 mg/l/48h Daphnia magna 1,25 The following sections were modified: 7.2. Conditions for safe storage, including any incompatibilities Solubility ACUTE TOXICITY EC50 - for Algae / Aquatic Plants H411 Toxic to aquatic life with long lasting effects. > 57 mg/l/72h Pseudokirchnerella subcapitata WATER

2.2 Label elements

02 / 03 / 07 / 11 / 16. Partition coefficient: n-octanol/water EUH210 Safety data sheet available on request. Not available 4.2. Most important symptoms and effects, both acute and delayed 14.6. Special precautions for user 12.2. Persistence and degradability Auto-ignition temperature LC50 (Inhalation) of the mixture: Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a well ventilated Not available Not classified (no significant component) Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Decomposition temperature LD50 (Oral) of the mixture: Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Not available Not classified (no significant component) Specific information on symptoms and effects caused by the product are unknown. place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any Not applicable Viscosity LD50 (Dermal) of the mixture: LEGEND: 110-120 KU Not classified (no significant component) incompatible materials, see section 10 for details.

Hazard pictograms

Explosive properties CALCIUM CARBONATE - ADR: European Agreement concerning the carriage of Dangerous goods by Road -- Not available 4.3. Indication of any immediate medical attention and special treatment needed 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code 7.3. Specific end use(s) Oxidising properties Solubility in water - CAS NUMBER: Chemical Abstract Service Number 0,1 - 100 mg/l Not available

Signal word

CE50: Effective concentration (required to induce a 50% effect) reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) -- Information not available Information not relevant

Further information

TALC - CE NUMBER: Identifier in ESIS (European archive of existing substances) Information not available LD50 (Oral) 481 mg/kg

Hazard statements

Solubility in water - CLP: EC Regulation 1272/2008 LD50 (Dermal) < 0,1 mg/l > 1,008 mg/kg SECTION 5. Firefighting measures SECTION 15. Regulatory information VOC (Directive 2004/42/EC) : - DNEL: Derived No Effect Level EUH210 LC50 (Inhalation) Safety data sheet available on request. 1,51 % - 18,84 1,23 mg/l/4h g/litre SECTION 8. Exposure controls/personal protection Gloss ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - EmS: Emergency Schedule EUH208

Contains

reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one 3 (60) 4 (85) 5.1. Extinguishing media Solubility in water - GHS: Globally Harmonized System of classification and labeling of chemicals CALCIUM CARBONATE (3:1) 1360 mg/l 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Rapidly degradable - IATA DGR: International Air Transport Association Dangerous Goods Regulation LD50 (Oral) 1,2-Benzoisothiazol-3(2H)-one 6450 mg/kg Rat 8.1. Control parameters SECTION 10. Stability and reactivity SUITABLE EXTINGUISHING EQUIPMENT - IC50: Immobilization Concentration 50% May produce an allergic reaction. 12.3. Bioaccumulative potential The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. Seveso Category - Directive 2012/18/EC: - IMDG: International Maritime Code for dangerous goods ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL None 10.1. Reactivity UNSUITABLE EXTINGUISHING EQUIPMENT TLV of solvent mixture: 1,03 mg/m3 - IMO: International Maritime Organization LD50 (Oral) 6500 mg/kg Rat - Carworth-Wistar

Precautionary statements

None in particular. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 - INDEX NUMBER: Identifier in Annex VI of CLP LD50 (Dermal) -- > 15200 mg/kg Rabbit - New Zeland white 8.2. Exposure controls There are no particular risks of reaction with other substances in normal conditions of use. None ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - LC50: Lethal Concentration 50% 5.2. Special hazards arising from the substance or mixture VOC (Directive 2004/42/EC) : SKIN CORROSION / IRRITATION Partition coefficient: n-octanol/water - LD50: Lethal dose 50% VOC (Directive 2004/42/EC) : 3,2 CALCIUM CARBONATE As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Substances in Candidate List (Art. 59 REACH) Coatings for exterior walls of mineral substrate. BCF - OEL: Occupational Exposure Level Coatings for exterior walls of mineral substrate. 44,1 HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE well aired through effective local aspiration. On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. Decomposes at temperatures above 800°C/1472°F. VOC given in g/litre of product in a ready-to-use condition : Does not meet the classification criteria for this hazard class

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation VOC given in g/litre of product in a ready-to-use condition : 11,74 12.4. Mobility in soil Limit value: Do not breathe combustion products. When choosing personal protective equipment, ask your chemical substance supplier for advice. - PEC: Predicted environmental Concentration Limit value: 40,00 10.2. Chemical stability - Thinned with : Personal protective equipment must be CE marked, showing that it complies with applicable standards. Substances subject to authorisarion (Annex XIV REACH) SERIOUS EYE DAMAGE / IRRITATION - PEL: Predicted exposure level - Thinned with : 10,00 % WATER 5.3. Advice for firefighters HAND PROTECTION None - PNEC: Predicted no effect concentration The product is stable in normal conditions of use and storage. Protect hands with category III work gloves (see standard EN 374). Does not meet the classification criteria for this hazard class ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - REACH: EC Regulation 1907/2006

2.3 Other hazards

GENERAL INFORMATION The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Partition coefficient: soil/water - RID: Regulation concerning the international transport of dangerous goods by train 2,2181 10.3. Possibility of hazardous reactions Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on None RESPIRATORY OR SKIN SENSITISATION - TLV: Threshold Limit Value On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of the duration and type of use. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. EPY 9.6.6 - SDS 1004.9