Protect hands with category III work gloves (see standard EN 374)

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) 10.5. Incompatible materials

Environmental hazards

or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. - PEL: Predicted exposure level GENERAL INFORMATION

Aspiration hazard

Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the - PNEC: Predicted no effect concentration Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for threshold values considered. The protection provided by masks is in any case limited. CALCIUM CARBONATE - REACH: EC Regulation 1907/2006 health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Not applicable The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent Does not meet the classification criteria for this hazard class If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an - RID: Regulation concerning the international transport of dangerous goods by train The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent Incompatible with: acids. contaminated water used for extinction and the remains of the fire according to applicable regulations. 10.6. Hazardous decomposition products amendments and supplements). emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing - TLV: Threshold Limit Value amendments and supplements). 14.6. Special precautions for user SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.

ECOLOGICAL INFORMATION

Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with Hazard classification and indication: ENVIRONMENTAL EXPOSURE CONTROLS CALCIUM CARBONATE - TWA STEL: Short-term exposure limit Hazard classification and indication: -- self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Not applicable The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure - TWA: Time-weighted average exposure limit May develop: calcium oxides,carbon oxides. 12.1. Toxicity 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code compliance with environmental standards. - VOC: Volatile organic Compounds

TOXICOLOGICAL INFORMATION

SECTION 6. Accidental release measures

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation 11.1. Information on toxicological effects Information not available - WGK: Water hazard classes (German). Information not relevant 6.1. Personal precautions, protective equipment and emergency procedures

Hazard pictograms

SECTION 9. Physical and chemical properties Metabolism, toxicokinetics, mechanism of action and other information Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in 12.2. Persistence and degradability SECTION 15. Regulatory information

Signal word

GENERAL BIBLIOGRAPHY -- emergency procedures. 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament 9.1. Information on basic physical and chemical properties Information not available

Hazard statements

2. Regulation (EC) 1272/2008 (CLP) of the European Parliament -- 6.2. Environmental precautions 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture CALCIUM CARBONATE 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament Properties Information on likely routes of exposure Value Information

Precautionary statements

Solubility in water 4. Regulation (EU) 2015/830 of the European Parliament -- 0,1 - 100 mg/l Appearance The product must not penetrate into the sewer system or come into contact with surface water or ground water. Seveso Category - Directive 2012/18/EC: liquid None 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament Colour Information not available white 12.3. Bioaccumulative potential 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament Odour no odour 6.3. Methods and material for containment and cleaning up VOC (Directive 2004/42/EC) : Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament VOC (Directive 2004/42/EC) : Odour threshold Delayed and immediate effects as well as chronic effects from short and long-term exposure None Not available Primers. Information not available 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Primers. pH Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material 8,20 VOC given in g/litre of product in a ready-to-use condition : 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament VOC given in g/litre of product in a ready-to-use condition : 1,33 Melting point / freezing point Information not available should be disposed of in compliance with the provisions set forth in point 13. Substances in Candidate List (Art. 59 REACH) Not available Limit value: 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament Limit value: 30,00 Initial boiling point Not available 12.4. Mobility in soil - Thinned with : On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament - Thinned with : 300,00 % WATER 6.4. Reference to other sections Boiling range Interactive effects Not available 12. Regulation (EU) 2016/1179 (IX Atp. CLP) Flash point > 60 °C Substances subject to authorisation (Annex XIV REACH) Information not available 13. Regulation (EU) 2017/776 (X Atp. CLP) Evaporation rate Information not available Any information on personal protection and disposal is given in sections 8 and 13. None Not available

2.3 Other hazards

14. Regulation (EU) 2018/669 (XI Atp. CLP) Flammability (solid, gas) Not available 15. Regulation (EU) 2018/1480 (XIII Atp. CLP) Lower inflammability limit ACUTE TOXICITY Not available

Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: 16. Regulation (EU) 2019/521 (XII Atp. CLP) On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. SECTION 7. Handling and storage Upper inflammability limit None Not available Lower explosive limit LC50 (Inhalation) of the mixture: Not available Not classified (no significant component) 7.1. Precautions for safe handling On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - The Merck Index. - 10th Edition Upper explosive limit LD50 (Oral) of the mixture: