POLACRYL 320

Hazard statements (CLP)

H225, H302, H312, H314, H315, H317, H318, H319, H331, H332, H335, H372, H400, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 2 Skin Corr. 1A H314, Eye Dam. 1 H318, STOT SE 3 H335 17 4 SKIN

Further information

Does not meet the classification criteria for this hazard class Hazardous to the aquatic environment, chronic H412 Harmful to aquatic life with long lasting effects. There are no particular risks of reaction with other substances in normal conditions of use. Not applicable 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament ACUTE TOXICITY 3-iodo-2-propynyl butylcarbamate toxicity, category 3 7.2. Conditions for safe storage, including any incompatibilities EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem Text of hazard (H) indications mentioned in section 2-3 of the sheet: As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 14.2. UN proper shipping name LC50 - for Fish persists, seek medical advice. 2-BUTOXYETHANOL 0,067 mg/l/96h

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation EC VOC (Directive 2004/42/EC) : TLV 204-469-4 GRC 40 10 60 15

2.1 Classification of the substance or mixture

WGK: Water hazard classes (German). INDEX Minimal build woodstains. NDS 2-(2-BUTOXYETHOXY)ETHANOL 612-004-00-5 POL 3 9 SECTION 7. Handling and storage SECTION 14. Transport information VOC (Directive 2004/42/EC) : OEL May be absorbed by inhalation, ingestion and skin contact; is irritating for the skin and especially for the eyes. May cause damage to EU 8,4 2 2,62 % - 26,46 12,6 3 g/litre SKIN

ECOLOGICAL INFORMATION

TLV-ACGIH 0,5 1 SKIN 15.2. Chemical safety assessment The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments The full wording of hazard (H) phrases is given in section 16 of the sheet. The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments the spleen. At room temperature the danger of inhalation is unlikely, due to the low vapour pressure of the substance. 7.1. Precautions for safe handling The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail GENERAL BIBLIOGRAPHY and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. This product is dangerous for the environment and the aquatic organisms. In the long term, it have negative effects on aquatic environment. and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. SECTION 10. Stability and reactivity (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. Legend: 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Interactive effects No chemical safety assessment has been processed for the mixture and the substances it contains. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. SECTION 4. First aid measures Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament 12.1. Toxicity 10.1. Reactivity

UN Number

environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering Hazard classification and indication: 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament Information not available Hazard classification and indication: 4.1. Description of first aid measures 8.2. Exposure controls places in which people eat. 4. Regulation (EU) 2015/830 of the European Parliament

2.2 Label elements

well aired through effective local aspiration. 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament LC50 (Inhalation) of the mixture: EC50 - for Crustacea 0,16 mg/l/48h > 20 mg/l SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Wash contaminated clothing before using it again. Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away When choosing personal protective equipment, ask your chemical substance supplier for advice. 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Decomposes under the effect of heat. Flam. Liq. 2 Flammable liquid, category 2 LD50 (Oral) of the mixture: EC50 - for Algae / Aquatic Plants INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention immediately. from any incompatible materials, see section 10 for details. Not applicable Acute Tox. 3 Acute toxicity, category 3 0,022 mg/l/72h Not classified (no significant component) Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Personal protective equipment must be CE marked, showing that it complies with applicable standards. 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament LD50 (Dermal) of the mixture: Chronic NOEC for Fish Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 0,049 mg/l Not classified (no significant component) 10.2. Chemical stability INGESTION: Get medical advice/attention immediately. Do not induce vomiting. Do not administer anything not explicitly authorised by a HAND PROTECTION 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament Acute Tox. 4 Acute toxicity, category 4 Chronic NOEC for Algae / Aquatic Plants 0,0046 mg/l 7.3. Specific end use(s) 14.3. Transport hazard class(es) doctor. Protect hands with category III work gloves (see standard EN 374). 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament STOT RE 1 Specific target organ toxicity - repeated exposure, category 1

Hazard pictograms

The product is stable in normal conditions of use and storage. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. 12. Regulation (EU) 2016/1179 (IX Atp. CLP) Skin Corr. 1A Skin corrosion, category 1A 12.2. Persistence and degradability 4.2. Most important symptoms and effects, both acute and delayed Information not available Not applicable Eye Dam. 1 2-(2-BUTOXYETHOXY)ETHANOL Serious eye damage, category 1

Signal word

The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on 13. Regulation (EU) 2017/776 (X Atp. CLP) LD50 (Oral) -- 3384 mg/kg Rat 10.3. Possibility of hazardous reactions the duration and type of use. Eye Irrit. 2 Eye irritation, category 2 14.4. Packing group Specific information on symptoms and effects caused by the product are unknown. Skin Irrit. 2 LD50 (Dermal) Skin irritation, category 2 2700 mg/kg Rabbit SECTION 8. Exposure controls/personal protection

Hazard statements

SKIN PROTECTION - The Merck Index. - 10th Edition 2-(2-BUTOXYETHOXY)ETHANOL No hazardous reactions are foreseeable in normal conditions of use and storage. Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body - Handling Chemical Safety STOT SE 3 Specific target organ toxicity - single exposure, category 3 Solubility in water H412 2-BUTOXYETHANOL Harmful to aquatic life with long lasting effects. 1000 - 10000 mg/l 4.3. Indication of any immediate medical attention and special treatment needed 8.1. Control parameters Not applicable - INRS - Fiche Toxicologique (toxicological sheet) with soap and water after removing protective clothing. Skin Sens. 1 Skin sensitization, category 1 Rapidly degradable EUH208 LD50 (Oral)

Contains

3-iodo-2-propynyl butylcarbamate 615 mg/kg Rat EYE PROTECTION 2-(2-BUTOXYETHOXY)ETHANOL - Patty - Industrial Hygiene and Toxicology Aquatic Acute 1 May produce an allergic reaction. Hazardous to the aquatic environment, acute toxicity, category 1

Environmental hazards

Information not available May react with oxidising substances.May form peroxides with oxygen.Develops hydrogen on contact with aluminium.May form explosive Aquatic Chronic 1 LD50 (Dermal) Hazardous to the aquatic environment, chronic toxicity, category 1 405 mg/kg Rabbit Regulatory References: Wear airtight protective goggles (see standard EN 166). - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition 2-BUTOXYETHANOL LC50 (Inhalation) 2,2 mg/l/4h Rat RESPIRATORY PROTECTION - IFA GESTIS website mixtures with: air. Aquatic Chronic 3 Hazardous to the aquatic environment, chronic toxicity, category 3 Solubility in water Not applicable H225 Highly flammable liquid and vapour. 1000 - 10000 mg/l SECTION 5. Firefighting measures

Precautionary statements

BGR If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type - ECHA website Rapidly degradable TRIETHYLAMINE България МИНИСТЕРСТВО НА ТРУДА И СОЦИАЛНАТА ПОЛИТИКА МИНИСТЕРСТВО НА 2-BUTOXYETHANOL A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy H331 Toxic if inhaled. ЗДРАВЕОПАЗВАНЕТО НАРЕДБА No 13 от 30 декември 2003 г P101 LD50 (Oral) If medical advice is needed, have product container or label at hand. 460 mg/kg Rat 14.6. Special precautions for user 5.1. Extinguishing media CZE or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. May react dangerously with aluminium,oxidising agents.Forms peroxides with air H302 Česká Republika Harmful if swallowed. Nařízení vlády č. 361/2007 Sb. kterým se stanoví podmínky ochrany zdraví při práci TRIETHYLAMINE P102 LD50 (Dermal) Keep out of reach of children. 580 mg/kg Rabbit FRA Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the H312 France Harmful in contact with skin. JORF n°0109 du 10 mai 2012 page 8773 texte n° 102 Solubility in water P103 LC50 (Inhalation) Read label before use. > 10000 mg/l 14,5 mg/l/4h Rat 10.4. Conditions to avoid Not applicable SUITABLE EXTINGUISHING EQUIPMENT GBR threshold values considered. The protection provided by masks is in any case limited. Note for users: H332 United Kingdom Harmful if inhaled. EH40/2005 Workplace exposure limits Rapidly degradable P273 Avoid release to the environment. The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. GRC If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the H372 Ελλάδα Causes damage to organs through prolonged or repeated exposure. ΕΦΗΜΕΡΙΣ ΤΗΣ ΚΥΒΕΡΝΗΣΕΩΣ -ΤΕΥΧΟΣ ΠΡΩΤΟ Αρ. Φύλλου 19 - 9 Φεβρουαρίου 2012 P501 3-iodo-2-propynyl butylcarbamate Dispose of contents / container in accordance with local / regional / national / international regulation 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code None in particular. However the usual precautions used for chemical products should be respected. UNSUITABLE EXTINGUISHING EQUIPMENT POL emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing suitability and thoroughness of provided information according to each specific use of the product. H314 Polska Causes severe skin burns and eye damage. ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 7 czerwca 2017 r 3-iodo-2-propynyl butylcarbamate H318 LD50 (Oral) Causes serious eye damage. 4100 mg/kg Rat VOC (Directive 2004/42/EC) : None in particular. EU apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. This document must not be regarded as a guarantee on any specific product property. Degradability: information not available VOC (Directive 2004/42/EC) : LD50 (Dermal) OEL EU Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; > 2000 mg/kg Rat-Rabbit 2-(2-BUTOXYETHOXY)ETHANOL Information not relevant The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health ENVIRONMENTAL EXPOSURE CONTROLS H319 Causes serious eye irritation. Minimal build woodstains. LC50 (Inhalation) Directive 2004/37/EC; Directive 2000/39/EC; Directive 91/322/EEC. 763 mg/l/4h Rat 5.2. Special hazards arising from the substance or mixture The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Avoid exposure to: air. H315 TLV-ACGIH Causes skin irritation. ACGIH 2017 12.3. Bioaccumulative potential VOC given in g/litre of product in a ready-to-use condition : 26,46 compliance with environmental standards. Provide appointed staff with adequate training on how to use chemical products. H335 May cause respiratory irritation. Limit value: SKIN CORROSION / IRRITATION Limit value: 130,00 2-BUTOXYETHANOL HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. H317 May cause an allergic skin reaction. Do not breathe combustion products. Changes to previous review: Avoid exposure to: sources of heat,naked flames. H400 Very toxic to aquatic life. Does not meet the classification criteria for this hazard class EPY 9.6.6 - SDS 1004.9

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.