P370+P378

Hazard statements (CLP)

H226, H304, H312, H317, H318, H336, H351, H361d, H372, H411, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

3.2. Mixtures 12.2. Persistence and degradability - TLV: Threshold Limit Value SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Odour threshold Avoid exposure to: air. LD50 (Dermal) Not available > 2000 mg/kg Rat - Wistar ADR / RID, IMDG, IATA: - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. LC50 (Inhalation) 1993 > 4,3 mg/l/4h Rat

2.1 Classification of the substance or mixture

Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with pH Substances subject to the Rotterdam Convention: Not available 10.5. Incompatible materials - TWA STEL: Short-term exposure limit 1272/2008 (CLP) 0,1 - 100 mg/l Not available 5300 mg/kg Rat STEL/15min SECTION 6. Accidental release measures ADR / RID:

Contains

self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Melting point / freezing point None 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT Not available 14.2. UN proper shipping name - TWA: Time-weighted average exposure limit 1-METHOXY-2-PROPANOL The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments Threshold Limit Value Initial boiling point CALCIUM CARBONATE The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments Not available and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. CALCIUM CARBONATE - VOC: Volatile organic Compounds Identification Boiling range Solubility in water Substances subject to the Stockholm Convention: and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. Type LD50 (Oral) Country x = Conc. % TWA/8h

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation Incompatible with: acids. LD50 (Dermal) FLAMMABLE LIQUID, N.O.S. (NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY) 13000 mg/kg Rabbit Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Flash point None Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. mg/m3 ppm 23 ≤ T ≤ 60 mg/m3 ppm °C IMDG: - WGK: Water hazard classes (German). LC50 (Inhalation) FLAMMABLE LIQUID, N.O.S. (NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY) 54,6 mg/l/4h Rat 6.1. Personal precautions, protective equipment and emergency procedures NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Evaporation Rate TALC IATA: TLV-ACGIH FLAMMABLE LIQUID, N.O.S. (NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY) 5 Not available 10 Hazard classification and indication: 2-BUTANONE OXIME CAS Flammability of solids and gases Solubility in water Healthcare controls Hazard classification and indication: 64742-82-1 10 ≤ x < 20 Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, < 0,1 mg/l Not available Lower inflammability limit Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks Flammable liquid, category 3 Incompatible with: oxidising substances,strong acids. Flammable liquid, category 3 2-BUTANONE OXIME Aquatic Chronic 2 H411, Not available H226 Flammable liquid and vapour. 14.3. Transport hazard class(es) Block the leakage if there is no hazard. GENERAL BIBLIOGRAPHY Specific target organ toxicity - repeated exposure, LD50 (Oral) 2400 mg/kg Rat H372 Causes damage to organs through prolonged or repeated Upper inflammability limit TITANIUM DIOXIDE related to the workers' health and safety are modest and that the 98/24/EC directive is respected. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent Specific target organ toxicity - repeated exposure, Classification note according to Annex VI to the CLP Regulation: P Not available 1-METHOXY-2-PROPANOL H372 1-METHOXY-2-PROPANOL 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament EC Threshold Limit Value Lower explosive limit Solubility in water category 1 LD50 (Dermal) 265-185-4 < 0,001 mg/l Not available > 1000 mg/kg Rabbit exposure. any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency ADR / RID: 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament Incompatible with: oxidising substances,strong acids,alkaline metals. LC50 (Inhalation) Class: 3 Label: 3 20 mg/l/4h Rat May be fatal if swallowed and enters airways. INDEX Upper explosive limit Degradability: information not available VOC (Directive 2004/42/EC) : Aspiration hazard, category 1 Type Aspiration hazard, category 1 649-330-00-2 Country TWA/8h Not available STEL/15min H304 May be fatal if swallowed and enters airways. procedures. 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament May cause drowsiness or dizziness. 2-BUTANONE OXIME Vapour pressure Primers. Specific target organ toxicity - single exposure, mg/m3 ppm Not available mg/m3 H336 ppm H336 May cause drowsiness or dizziness. 10.6. Hazardous decomposition products 4. Regulation (EU) 2015/830 of the European Parliament CAS Vapour density 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT category 3 TLV category 3 NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY 96-29-7 BGR 0 ≤ x < 1 375 Carc. 2 H351, Acute Tox. 4 H312, Eye Dam. 1 H318, Skin Sens. 1 H317 Not available 568 SKIN Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament LD50 (Oral) > 5000 mg/kg Rat 15.2. Chemical safety assessment EC Relative density Solubility in water IMDG: Hazardous to the aquatic environment, chronic TLV Hazardous to the aquatic environment, chronic 202-496-6 CZE Class: 3 270 Label: 3 < 0,1 mg/l 1,50 550 H412 Harmful to aquatic life with long lasting effects. SKIN Harmful to aquatic life with long lasting effects. CALCIUM CARBONATE 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament INDEX Solubility Rapidly degradable toxicity, category 3 VLEP toxicity, category 3 LD50 (Dermal) 616-014-00-0 FRA 188 50 WHITE SPIRIT > 2000 mg/kg Rabbit 375 10 SKIN 6.2. Environmental precautions 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament May develop: calcium oxides,carbon oxides. 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT Partition coefficient: n-octanol/water No chemical safety assessment has been processed for the mixture and the substances it contains. WEL GBR 375 100 Not available 560 150 SKIN

2.2 Label elements

SKIN CORROSION / IRRITATION 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament CAS Auto-ignition temperature 1-METHOXY-2-PROPANOL TLV 22464-99-9 GRC 0,1 ≤ x < 2 360 100 Repr. 2 H361d Not available 1080 300 The product must not penetrate into the sewer system or come into contact with surface water or ground water. 2-BUTANONE OXIME 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament EC Decomposition temperature Solubility in water IATA: NDS 245-018-1 POL Class: 3 180 Label: 3 1000 - 10000 mg/l Not available 360

Further information

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Does not meet the classification criteria for this hazard class 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament INDEX Viscosity Rapidly degradable Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. May develop: nitric oxide,carbon oxides. OEL EU 375 100 100-110 KU 568 150 SKIN 6.3. Methods and material for containment and cleaning up 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament 1-METHOXY-2-PROPANOL Explosive properties Text of hazard (H) indications mentioned in section 2-3 of the sheet: TLV-ACGIH 184 50 Not available 368 100 SERIOUS EYE DAMAGE / IRRITATION 12. Regulation (EU) 2016/1179 (IX Atp. CLP) Does not meet the classification criteria for this hazard class INDEX (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it Entirely degradable 603-064-00-3 Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. - The Merck Index. - 10th Edition Carc. 2 Carcinogenicity, category 2 contains, using the criteria specified in the applicable regulation for classification. Repr. 2 Reproductive toxicity, category 2 RESPIRATORY OR SKIN SENSITISATION ADR / RID, IMDG, IATA: - Handling Chemical Safety The full wording of hazard (H) phrases is given in section 16 of the sheet. TLV of solvent mixture: VOC (Directive 2004/42/EC) : It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY III 184 20,23 % - 303,45 mg/m3 g/litre 6.4. Reference to other sections - INRS - Fiche Toxicologique (toxicological sheet) Acute Tox. 4 Acute toxicity, category 4 VOC (volatile carbon) : toxicological effects of exposure to the product. Rapidly degradable STOT RE 1 Specific target organ toxicity - repeated exposure, category 1 17,83 % - 267,49 g/litre

Hazard pictograms

CAS Oxidising properties 2-BUTANONE OXIME 107-98-2 0,05 ≤ x < 0,1 Flam. Liq. 3 H226, STOT SE 3 H336 Not available

TOXICOLOGICAL INFORMATION

Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of 13. Regulation (EU) 2017/776 (X Atp. CLP) EC Legend: Solubility in water the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Flam. Liq. 3 203-539-1 Flammable liquid, category 3 1000 - 10000 mg/l 14.4. Packing group

Environmental hazards

8.2. Exposure controls May produce an allergic reaction. Gloss - Patty - Industrial Hygiene and Toxicology 2,5 (60) 8,5(85)