P370+P378

Hazard statements (CLP)

H226, H304, H312, H315, H317, H318, H319, H332, H335, H336, H351, H360D, H361d, H372, H411, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

EC50 - for Algae / Aquatic Plants SUITABLE EXTINGUISHING EQUIPMENT H372 Special Instructions: Causes damage to organs through prolonged or repeated exposure. 3,1 mg/l/72h Pseudokirchnerella subcapitata A3

Results of PBT and vPvB assessment

3.2. Mixtures 10.1. Reactivity When choosing personal protective equipment, ask your chemical substance supplier for advice. suitability and thoroughness of provided information according to each specific use of the product. Metabolism, toxicokinetics, mechanism of action and other information H304 2-BUTANONE OXIME May be fatal if swallowed and enters airways. Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can Regulatory References: Personal protective equipment must be CE marked, showing that it complies with applicable standards. This document must not be regarded as a guarantee on any specific product property. LD50 (Oral) 2400 mg/kg Rat

2.1 Classification of the substance or mixture

12.2. Persistence and degradability 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code H318 Causes serious eye damage. be used to disperse flammable vapours and protect those trying to stem the leak. Exposure levels must be kept as low as possible to avoid significant build-up in the organism. Manage personal protective equipment so as to On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health LD50 (Dermal) > 1000 mg/kg Rabbit 1272/2008 (CLP) explosions. CZE Protect hands with category III work gloves (see standard EN 374). NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Česká Republika Nařízení vlády č. 361/2007 Sb. kterým se stanoví podmínky ochrany zdraví při práci Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Solubility in water Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Decomposes under the effect of heat. H317 May cause an allergic skin reaction. 100 - 1000 mg/l SECTION 15. Regulatory information FRA The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Information not available Changes to previous review: LD50 (Oral) France JORF n°0109 du 10 mai 2012 page 8773 texte n° 102 > 5000 mg/kg Rat 5.2. Special hazards arising from the substance or mixture NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Degradability: information not available GBR H336 XYLENE (MIXTURE OF ISOMERS) United Kingdom May cause drowsiness or dizziness. EH40/2005 Workplace exposure limits Hazard classification and indication: The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on The following sections were modified: CAS N-METHYL-2-PYRROLIDONE Hazard classification and indication: H411 LD50 (Dermal) WORKERS: inhalation; contact with the skin. 64742-82-1 20 ≤ x < 25 Toxic to aquatic life with long lasting effects. Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, > 2000 mg/kg Rabbit GRC the duration and type of use. Ελλάδα ΕΦΗΜΕΡΙΣ ΤΗΣ ΚΥΒΕΡΝΗΣΕΩΣ -ΤΕΥΧΟΣ ΠΡΩΤΟ Αρ. Φύλλου 19 - 9 Φεβρουαρίου 2012 01 / 02 / 03 / 04 / 06 / 07 / 09 / 10 / 11 / 12 / 14 / 15. Aquatic Chronic 2 H411, CALCIUM BIS 2-ETHYLHEXANOATE Flammable liquid, category 3 Decomposes at temperatures above 300°C/572°F.Dissolves various plastic materials. H412 Flammable liquid, category 3 POPULATION: ingestion of contaminated food or water; inhalation of ambient air. Harmful to aquatic life with long lasting effects. H226 Flammable liquid and vapour. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture SECTION 13. Disposal considerations HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE POL SKIN PROTECTION SKIN CORROSION / IRRITATION Polska ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 7 czerwca 2017 r Causes damage to organs through prolonged or repeated Solubility in water Specific target organ toxicity - repeated exposure, Classification note according to Annex VI to the CLP Regulation: P > 10000 mg/l H372 Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. EU Wear category III professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body OEL EU Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; exposure. 13.1. Waste treatment methods EC When exposed to the air it oxidates slowly to develop hydroperoxides. Completely mixable with water with a neutral or slightly basic reaction. Rapidly degradable category 1 N-METHYL-2-PYRROLIDONE 265-185-4 Seveso Category - Directive 2012/18/EC: with soap and water after removing protective clothing. Does not meet the classification criteria for this hazard class Directive 2004/37/EC; Directive 2000/39/EC; Directive 91/322/EEC. P5c INDEX It does not attack common materials. LEGEND: Aspiration hazard, category 1 WORKERS: inhalation; contact with the skin. 649-330-00-2 H304 May be fatal if swallowed and enters airways. 5.3. Advice for firefighters Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. TLV-ACGIH ACGIH 2017 BARIUM SULFATE AMORPHOUS SILICATE HYDRATE Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product - ADR: European Agreement concerning the carriage of Dangerous goods by Road Specific target organ toxicity - single exposure, POPULATION: ingestion of contaminated food or water; inhalation of envoronmental air. H336 May cause drowsiness or dizziness. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 EYE PROTECTION SERIOUS EYE DAMAGE / IRRITATION 10.2. Chemical stability CAS Solubility in water should be evaluated according to applicable regulations. - CAS NUMBER: Chemical Abstract Service Number category 3 7727-43-7 10 ≤ x < 25 Substance with a community workplace exposure limit. 0,1 - 100 mg/l GENERAL INFORMATION Wear airtight protective goggles (see standard EN 166). Product NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY EC Delayed and immediate effects as well as chronic effects from short and long-term exposure Degradability: information not available Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. - CE50: Effective concentration (required to induce a 50% effect) Hazardous to the aquatic environment, chronic 231-784-4 H412 Harmful to aquatic life with long lasting effects. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Threshold Limit Value In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent Does not meet the classification criteria for this hazard class Point 3 - 40 INDEX The product is stable in normal conditions of use and storage. Waste transportation may be subject to ADR restrictions. - CE NUMBER: Identifier in ESIS (European archive of existing substances) toxicity, category 3 health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of accidental absorption. Contained substance Type Country TWA/8h STEL/15min CALCIUM BIS 2-ETHYLHEXANOATE BARIUM SULFATE CONTAMINATED PACKAGING - CLP: EC Regulation 1272/2008 contaminated water used for extinction and the remains of the fire according to applicable regulations. Point XYLENE (MIXTURE OF ISOMERS) 30 mg/m3 N-METHYL-2-PYRROLIDONE ppm mg/m3 ppm 1272/2008 (CLP) NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY CAS 64742-82-1 20 ≤ x < 25 Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, Aquatic Chronic 2 H411, Classification note according to Annex VI to the CLP Regulation: P EC 265-185-4 INDEX 649-330-00-2 BARIUM SULFATE CAS 7727-43-7 10 ≤ x < 25 Substance with a community workplace exposure limit. EC 231-784-4 INDEX CALCIUM BIS 2-ETHYLHEXANOATE CAS 136-51-6 0 ≤ x < 1 Repr. 2 H361d, Eye Dam. 1 H318 EC 205-249-0 INDEX 2-BUTANONE OXIME CAS 96-29-7 0 ≤ x < 1 Carc. 2 H351, Acute Tox. 4 H312, Eye Dam. 1 H318, Skin Sens. 1 H317 EC 202-496-6 INDEX 616-014-00-0 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT CAS 22464-99-9 0,1 ≤ x < 2 Repr. 2 H361d EC 245-018-1 INDEX XYLENE (MIXTURE OF ISOMERS) CAS 1330-20-7 0,1 ≤ x < 2 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Classification note according to Annex VI to the CLP Regulation: C EC 215-535-7 INDEX 601-022-00-9 SECTION 3. Composition/information on ingredients ... / >> N-METHYL-2-PYRROLIDONE CAS 872-50-4 0 ≤ x < 0,3 Repr. 1B H360D, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335 EC 212-828-1 INDEX 606-021-00-7 The full wording of hazard (H) phrases is given in section 16 of the sheet.

Contains

There are no particular risks of reaction with other substances in normal conditions of use. Information not available H319 Causes serious eye irritation. UNSUITABLE EXTINGUISHING EQUIPMENT BGR guarantee maximum protection (e.g. reduction in replacement times). and safety laws and regulations. The producer is relieved from any liability arising from improper uses. LC50 (Inhalation) България МИНИСТЕРСТВО НА ТРУДА И СОЦИАЛНАТА ПОЛИТИКА МИНИСТЕРСТВО НА 20 mg/l/4h Rat The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments Information not relevant The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments H315 Causes skin irritation. 2-BUTANONE OXIME N-METHYL-2-PYRROLIDONE 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT - IATA DGR: International Air Transport Association Dangerous Goods Regulation There are no reported cases of acute or chronic intoxication or sensitisation. On volunteers, repeated skin applications caused modest Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the 2-BUTANONE OXIME 2-BUTANONE OXIME May produce an allergic reaction. NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY XYLENE (MIXTURE OF ISOMERS) VOC (Directive 2004/42/EC) : Interior/exterior trim and cladding paints for wood, metal or plastic. VOC given in g/litre of product in a ready-to-use condition : 299,68 Limit value: 300,00 - Thinned with : 3,00 % WHITE SPIRIT Identification x = Conc. %

Other hazards

Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent HAND PROTECTION Provide appointed staff with adequate training on how to use chemical products. ЗДРАВЕОПАЗВАНЕТО НАРЕДБА No 13 от 30 декември 2003 г and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. Identification 2-BUTANONE OXIME Information on likely routes of exposure XYLENE (MIXTURE OF ISOMERS) and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. H335 x = Conc. % May cause respiratory irritation.

2.2 Label elements

RESPIRATORY PROTECTION RESPIRATORY OR SKIN SENSITISATION CAS 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT Solubility in water Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. - DNEL: Derived No Effect Level Toxic effect on the central nervous system (encephalopathy); irritating for the skin, conjunctiva, cornea and respiratory apparatus. 136-51-6 0 ≤ x < 1 Repr. 2 H361d, Eye Dam. 1 H318 0,1 - 100 mg/l SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type NDS POL 300 900 EC Degradability: information not available - EmS: Emergency Schedule Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with Substances in Candidate List (Art. 59 REACH) SADT = 210°C/410°F. 205-249-0 Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases May produce an allergic reaction. INDEX N-METHYL-2-PYRROLIDONE - GHS: Globally Harmonized System of classification and labeling of chemicals Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. SECTION 14. Transport information self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). N-METHYL-2-PYRROLIDONE or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.

UN Number

CAS Solubility in water - IC50: Immobilization Concentration 50% Substances subject to authorisarion (Annex XIV REACH) Is stable up to 315°C/599°F. and transient erythema. Oral and inhalation trials on mice and rats revealed no teratogenic effects at non embryotoxic doses. Not 96-29-7 0 ≤ x < 1 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT Carc. 2 H351, Acute Tox. 4 H312, Eye Dam. 1 H318, Skin Sens. 1 H317 < 0,1 mg/l threshold values considered. The protection provided by masks is in any case limited. SECTION 6. Accidental release measures EC Rapidly degradable - IMDG: International Maritime Code for dangerous goods Threshold Limit Value None mutagenic in the Ames test. 202-496-6 10.3. Possibility of hazardous reactions If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an GERM CELL MUTAGENICITY INDEX - IMO: International Maritime Organization 616-014-00-0 6.1. Personal precautions, protective equipment and emergency procedures ADR / RID, IMDG, IATA: emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing Type Country 1993 TWA/8h STEL/15min 2-ETHYLHEXANOIC ACID, ZIRCONIUM SALT Interactive effects N-METHYL-2-PYRROLIDONE - INDEX NUMBER: Identifier in Annex VI of CLP Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: mg/m3 ppm mg/m3 ppm apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. Does not meet the classification criteria for this hazard class CAS The vapours may also form explosive mixtures with the air. Solubility in water - LC50: Lethal Concentration 50% 22464-99-9 0,1 ≤ x < 2 Repr. 2 H361d 1000 - 10000 mg/l 14.2. UN proper shipping name None ENVIRONMENTAL EXPOSURE CONTROLS Block the leakage if there is no hazard. TLV-ACGIH 5 10 EC Rapidly degradable - LD50: Lethal dose 50% XYLENE (MIXTURE OF ISOMERS) 245-018-1 The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure CARCINOGENICITY INDEX Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent 2-BUTANONE OXIME - OEL: Occupational Exposure Level Intake of alcohol interferes with the metabolism of the substance, inhibiting it. Ethanol consumption (0.8 g/kg) before a 4-hour ADR / RID: Substances subject to the Rotterdam Convention: any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency compliance with environmental standards. FLAMMABLE LIQUID, N.O.S. (NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY) XYLENE (MIXTURE OF ISOMERS) 2-BUTANONE OXIME

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation IMDG: None Reacts violently with: strong oxidising agents,acids. exposure to xylene vapours (145 and 280 ppm) causes a 50% reduction in the excretion of methyl hippuric acid, whereas the FLAMMABLE LIQUID, N.O.S. (NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY) Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. Does not meet the classification criteria for this hazard class CAS procedures. Solubility in water - PEC: Predicted environmental Concentration concentration of xylenes in the blood increases approx. 1.5-2 times. At the same time there is an increase in the secondary side 1330-20-7 0,1 ≤ x < 2 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, 1000 - 10000 mg/l IATA: FLAMMABLE LIQUID, N.O.S. (NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY)

Signal word

Above the flash point (69°C/156°F), explosive mixtures can form with air. Entirely degradable - PEL: Predicted exposure level effects of the ethanol. The metabolism of the xylenes is increased by phenobarbital and 3-methyl-colantrene type enzyme inducers. Danger Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Substances subject to the Stockholm Convention: Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. XYLENE (MIXTURE OF ISOMERS) SECTION 9. Physical and chemical properties - PNEC: Predicted no effect concentration None Aspirin and xylenes mutually inhibit their conjugation with the glycine, which results in a decrease in urinary excretion of methyl Classification note according to Annex VI to the CLP Regulation: C

Hazard statements

EC XYLENE (MIXTURE OF ISOMERS) NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY - REACH: EC Regulation 1907/2006 Classified in Group 3 (not classifiable as a human carcinogen) by the International Agency for Research on Cancer (IARC). hippuric acid. Other industrial products can interfere with the metabolism of xylenes. 215-535-7 6.2. Environmental precautions INDEX Rapidly degradable - RID: Regulation concerning the international transport of dangerous goods by train H226 Stable in normal conditions of use and storage.Reacts violently with: strong oxidants,strong acids,nitric acid,perchlorates.May form H226 The US Environmental Protection Agency (EPA) affirms that "the data is inadequate for an assessment of the carcinogenic potential". 601-022-00-9 Flammable liquid and vapour. Healthcare controls H372 Causes damage to organs through prolonged or repeated exposure. 9.1. Information on basic physical and chemical properties - TLV: Threshold Limit Value Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks explosive mixtures with: air. N-METHYL-2-PYRROLIDONE 12.3. Bioaccumulative potential The product must not penetrate into the sewer system or come into contact with surface water or ground water. REPRODUCTIVE TOXICITY - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. H304 The substance enhances the skin permeability of many other substances. May be fatal if swallowed and enters airways. related to the workers' health and safety are modest and that the 98/24/EC directive is respected. H336 May cause drowsiness or dizziness. Appearance N-METHYL-2-PYRROLIDONE - TWA STEL: Short-term exposure limit liquid Does not meet the classification criteria for this hazard class Colour ACUTE TOXICITY - TWA: Time-weighted average exposure limit H412 May react dangerously with: strong oxidants,strong acids. H412 Harmful to aquatic life with long lasting effects. white EPY 9.6.6 - SDS 1004.9 EUH208

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P301+P310 IF SWALLOWED: immediately call a POISON CENTER / doctor / . . . P331 Do NOT induce vomiting. P370+P378 In case of fire: use . . . to extinguish.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. SECTION 3. Composition/information on ingredients 3.1. Substances Information not relevant 3.2. Mixtures