P273

Hazard statements (CLP)

H226, H304, H312, H315, H319, H332, H335, H336, H372, H373, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Seveso Category - Directive 2012/18/EC: Not available 400 SKIN P5c-E2 - LD50: Lethal dose 50% self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Lower inflammability limit Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. VLEP FRA 221 50 Not available 442 100 SKIN

2.1 Classification of the substance or mixture

OEL: Occupational Exposure Level 1272/2008 (CLP) Not available and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. - PEL: Predicted exposure level and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. Point 3 - 40 6.1. Personal precautions, protective equipment and emergency procedures

Contains

Upper inflammability limit WEL XYLENE (MIXTURE OF ISOMERS) GBR 220

ECOLOGICAL INFORMATION

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation 50 Not available 441 100 Lower explosive limit TLV Toxic effect on the central nervous system (encephalopathy); irritating for the skin, conjunctiva, cornea and respiratory apparatus. GRC 435 100 Not available 650 150 SECTION 6. Accidental release measures SECTION 14. Transport information The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments - PEC: Predicted environmental Concentration Identification Upper explosive limit This product is dangerous for the environment and is toxic for aquatic organisms. In the long term, it have negative effects on acquatic The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments Product NDS POL x = Conc. % 100

UN Number

Vapour pressure Interactive effects environment. OEL EU 221 50 Not available 442 100 SKIN Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. - PNEC: Predicted no effect concentration XYLENE (MIXTURE OF ISOMERS) Vapour density Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. TLV-ACGIH 434 100 Not available 651 150 Substances in Candidate List (Art. 59 REACH) - REACH: EC Regulation 1907/2006 12.1. Toxicity CAS Relative density Block the leakage if there is no hazard. ADR / RID, IMDG, IATA: XYLENE (MIXTURE OF ISOMERS) 1330-20-7 1993 25 ≤ x < 50 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, 0,90 Hazard classification and indication: On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. - RID: Regulation concerning the international transport of dangerous goods by train Solubility Hazard classification and indication: Intake of alcohol interferes with the metabolism of the substance, inhibiting it. Ethanol consumption (0.8 g/kg) before a 4-hour Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Not available Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent - TLV: Threshold Limit Value Partition coefficient: n-octanol/water Flammable liquid, category 3 exposure to xylene vapours (145 and 280 ppm) causes a 50% reduction in the excretion of methyl hippuric acid, whereas the Classification note according to Annex VI to the CLP Regulation: C Not available H226 Flammable liquid and vapour. 14.2. UN proper shipping name any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Substances subject to authorisarion (Annex XIV REACH) - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. May be fatal if swallowed and enters airways. EC Auto-ignition temperature NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Aspiration hazard, category 1 concentration of xylenes in the blood increases approx. 1.5-2 times. At the same time there is an increase in the secondary side 215-535-7 NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Not available H304 procedures. None - TWA STEL: Short-term exposure limit INDEX Threshold Limit Value Decomposition temperature LC50 - for Fish Specific target organ toxicity - repeated exposure, effects of the ethanol. The metabolism of the xylenes is increased by phenobarbital and 3-methyl-colantrene type enzyme inducers. 601-022-00-9 8,2 mg/l/96h Pimephales promelas Not available H373 May cause damage to organs through prolonged or ADR / RID: - TWA: Time-weighted average exposure limit FLAMMABLE LIQUID, N.O.S. (XYLENE (MIXTURE OF ISOMERS); ETHYL,3-ETHOXY PROPIONATE) repeated exposure. SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM Viscosity EC50 - for Crustacea category 2 Type Aspirin and xylenes mutually inhibit their conjugation with the glycine, which results in a decrease in urinary excretion of methyl Country TWA/8h 4,5 mg/l/48h Daphnia magna Not available STEL/15min Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. IMDG: Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: - VOC: Volatile organic Compounds FLAMMABLE LIQUID, N.O.S. (XYLENE (MIXTURE OF ISOMERS); ETHYL,3-ETHOXY PROPIONATE; SOLVENT CAS Explosive properties EC50 - for Algae / Aquatic Plants Eye irritation, category 2 hippuric acid. Other industrial products can interfere with the metabolism of xylenes. 64742-95-6 10 ≤ x < 20 mg/m3 ppm Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, 3,1 mg/l/72h Pseudokirchnerella subcapitata Not available mg/m3 H319 ppm H319 Causes serious eye irritation.

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation NAPHTHA (PETROLEUM), LIGHT AROM) None Skin irritation, category 2 Oxidising properties NDS Skin irritation, category 2 POL 300 Aquatic Chronic 2 H411, Not available 900 H315 Causes skin irritation. 6.2. Environmental precautions IATA: - WGK: Water hazard classes (German). FLAMMABLE LIQUID, N.O.S. (XYLENE (MIXTURE OF ISOMERS); ETHYL,3-ETHOXY PROPIONATE) 12.2. Persistence and degradability ACUTE TOXICITY Specific target organ toxicity - single exposure, Classification note according to Annex VI to the CLP Regulation: P H335 May cause respiratory irritation. Substances subject to the Rotterdam Convention: EC category 3 265-199-0

Further information

14.3. Transport hazard class(es) Legend: The product must not penetrate into the sewer system or come into contact with surface water or ground water. None Specific target organ toxicity - single exposure, H336 May cause drowsiness or dizziness. INDEX (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. LC50 (Inhalation) of the mixture: 649-356-00-4 > 20 mg/l GENERAL BIBLIOGRAPHY NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY VOC (Directive 2010/75/EC) : LD50 (Oral) of the mixture: XYLENE (MIXTURE OF ISOMERS) category 3 99,70 % - 894,31 Not classified (no significant component) g/litre 6.3. Methods and material for containment and cleaning up ADR / RID: Substances subject to the Stockholm Convention: 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament Class: 3 Label: 3 CAS TLV of solvent mixture: VOC (volatile carbon) : LD50 (Dermal) of the mixture: Solubility in water Hazardous to the aquatic environment, chronic 64742-82-1 2,5 ≤ x < 5,5 434 Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, 100 - 1000 mg/l 83,93 % - 752,88 mg/m3 >2000 mg/kg H411 g/litre Toxic to aquatic life with long lasting effects. None 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament Degradability: information not available toxicity, category 2 Aquatic Chronic 2 H411, Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 8.2. Exposure controls the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Classification note according to Annex VI to the CLP Regulation: P

2.2 Label elements

SECTION 10. Stability and reactivity Healthcare controls 4. Regulation (EU) 2015/830 of the European Parliament EC ETHYL,3-ETHOXY PROPIONATE IMDG: XYLENE (MIXTURE OF ISOMERS) 265-185-4 Class: 3 Label: 3 Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament 10.1. Reactivity INDEX As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Solubility in water LD50 (Oral) 649-330-00-2 > 10000 mg/l 3523 mg/kg Rat related to the workers' health and safety are modest and that the 98/24/EC directive is respected. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament well aired through effective local aspiration. Rapidly degradable Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. LD50 (Dermal) 4350 mg/kg Rabbit 6.4. Reference to other sections 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament The full wording of hazard (H) phrases is given in section 16 of the sheet. When choosing personal protective equipment, ask your chemical substance supplier for advice. There are no particular risks of reaction with other substances in normal conditions of use. LC50 (Inhalation) 26 mg/l/4h Rat 15.2. Chemical safety assessment

Hazard pictograms

8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Personal protective equipment must be CE marked, showing that it complies with applicable standards. NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY IATA: Class: 3 Label: 3 Any information on personal protection and disposal is given in sections 8 and 13. 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament Provide an emergency shower with face and eye wash station. Rapidly degradable NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY 10.2. Chemical stability