- OEL: Occupational Exposure Level

DGK-PELLACHROM

Revision date : 2019-03-02

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GHS05 GHS06 GHS07 GHS09
Health risk rating 5
Safety risk rating 1
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

220-120-9/2634-33-5

Name of the chemical

1,2-Benzisothiazol-3(2H)-one

Concentration

0≤x<0,05

General Information

Revision date

2019-03-02

Product name

- OEL: Occupational Exposure Level

Substance name

9.1. Information on basic physical and chemical properties

CAS No.

2634-33-5

1.2.1 Relevant identified uses

- PNEC: Predicted no effect concentration

1.2.2. Uses advised against

None SECTION 7. Handling and storage

Emergency telephone

GENERAL BIBLIOGRAPHY

Icons in SDS

Company Information

company name

DGK-PELLACHROM

e-mail address of the competent person responsible for the Safety Data Sheet

info@pellachrom.gr

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H302, H315, H317, H318, H330, H400, H411

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. None

Further information

5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament Specific information on symptoms and effects caused by the product are unknown. 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. - INRS - Fiche Toxicologique (toxicological sheet)

2.1 Classification of the substance or mixture

SKIN CORROSION / IRRITATION Information not available Healthcare controls Information not available 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament VOC (Directive 2010/75/EC) : Information not available 0 4.3. Indication of any immediate medical attention and special treatment needed 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). VOC (volatile carbon) : Does not meet the classification criteria for this hazard class The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). 0 8.2. Exposure controls SECTION 13. Disposal considerations 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Gloss VOC (Directive 2004/42/EC) : However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data 34 (20) 82 (60) 89(85) Information not available 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament sheet with appropriate information, compliant to (EU) Regulation 2015/830. SERIOUS EYE DAMAGE / IRRITATION Binding primers. sheet with appropriate information, compliant to (EU) Regulation 2015/830. 13.1. Waste treatment methods As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament well aired through effective local aspiration. 12. Regulation (EU) 2016/1179 (IX Atp. CLP) 15.2. Chemical safety assessment SECTION 10. Stability and reactivity SECTION 5. Firefighting measures Hazard classification and indication: Does not meet the classification criteria for this hazard class Hazard classification and indication: -- When choosing personal protective equipment, ask your chemical substance supplier for advice. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. 13. Regulation (EU) 2017/776 (X Atp. CLP) 10.1. Reactivity 5.1. Extinguishing media Personal protective equipment must be CE marked, showing that it complies with applicable standards. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. RESPIRATORY OR SKIN SENSITISATION No chemical safety assessment has been processed for the mixture and the substances it contains. HAND PROTECTION CONTAMINATED PACKAGING

2.2 Label elements

The Merck Index. - 10th Edition Protect hands with category III work gloves (see standard EN 374). There are no particular risks of reaction with other substances in normal conditions of use. Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. SUITABLE EXTINGUISHING EQUIPMENT - Handling Chemical Safety May produce an allergic reaction. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.

Contains

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 10.2. Chemical stability The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on UNSUITABLE EXTINGUISHING EQUIPMENT - Patty - Industrial Hygiene and Toxicology SECTION 14. Transport information 1,2-Benzoisothiazol-3(2H)-one the duration and type of use. Text of hazard (H) indications mentioned in section 2-3 of the sheet: None in particular. - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition 1,2-Benzoisothiazol-3(2H)-one 10.4. Conditions to avoid 5.3. Advice for firefighters If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1 Does not meet the classification criteria for this hazard class May produce an allergic reaction. 14.2. UN proper shipping name B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases suitability and thoroughness of provided information according to each specific use of the product. Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2 or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. None in particular. However the usual precautions used for chemical products should be respected. GENERAL INFORMATION This document must not be regarded as a guarantee on any specific product property. H330 Fatal if inhaled. REPRODUCTIVE TOXICITY Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the H302 Harmful if swallowed.

Hazard pictograms

SKIN PROTECTION The product is stable in normal conditions of use and storage. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail - IFA GESTIS website GERM CELL MUTAGENICITY Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body Acute Tox. 2 Acute toxicity, category 2 5.2. Special hazards arising from the substance or mixture

Signal word

RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. - ECHA website -- 10.3. Possibility of hazardous reactions with soap and water after removing protective clothing. - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy Acute Tox. 4 Acute toxicity, category 4 Does not meet the classification criteria for this hazard class EYE PROTECTION Eye Dam. 1 Serious eye damage, category 1

Hazard statements

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Wear airtight protective goggles (see standard EN 166). No hazardous reactions are foreseeable in normal conditions of use and storage. Skin Irrit. 2 Skin irritation, category 2 Do not breathe combustion products. CARCINOGENICITY EUH210 Safety data sheet available on request. RESPIRATORY PROTECTION Note for users: Skin Sens. 1 Skin sensitization, category 1 Not applicable EUH208

Precautionary statements

Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Not applicable The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health -- 10.5. Incompatible materials threshold values considered. The protection provided by masks is in any case limited. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of and safety laws and regulations. The producer is relieved from any liability arising from improper uses. H318 Causes serious eye damage. Does not meet the classification criteria for this hazard class If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an H315 Causes skin irritation. 14.3. Transport hazard class(es) VOC (Directive 2004/42/EC) : contaminated water used for extinction and the remains of the fire according to applicable regulations. Provide appointed staff with adequate training on how to use chemical products. VOC (Directive 2004/42/EC) : emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing Information not available SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS H317 May cause an allergic skin reaction. Binding primers. STOT - SINGLE EXPOSURE Binding primers. apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with Not applicable Changes to previous review: H400 Very toxic to aquatic life. VOC given in g/litre of product in a ready-to-use condition : 0,00 10.6. Hazardous decomposition products ENVIRONMENTAL EXPOSURE CONTROLS self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). The following sections were modified: H411 Toxic to aquatic life with long lasting effects. Limit value: Does not meet the classification criteria for this hazard class Limit value: 30,00 14.4. Packing group The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure 01 / 02 / 03 / 04 / 08 / 09 / 11 / 12 / 14 / 15 / 16. EUH210 Safety data sheet available on request. - Thinned with : 50,00 % WATER compliance with environmental standards. Information not available SECTION 6. Accidental release measures STOT - REPEATED EXPOSURE Not applicable LEGEND:

2.3 Other hazards

6.1. Personal precautions, protective equipment and emergency procedures

Other hazards

Does not meet the classification criteria for this hazard class

Environmental hazards

ADR: European Agreement concerning the carriage of Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in

Aspiration hazard

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - CE50: Effective concentration (required to induce a 50% effect) Not applicable emergency procedures. - CE NUMBER: Identifier in ESIS (European archive of existing substances) Does not meet the classification criteria for this hazard class EPY 9.6.6 - SDS 1004.9

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