OEL

Hazard statements (CLP)

H225, H226, H302, H304, H312, H315, H319, H332, H335, H336, H360D, H372, H373, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Does not meet the classification criteria for this hazard class Changes to previous review: 20 NDS and transient erythema. Oral and inhalation trials on mice and rats revealed no teratogenic effects at non embryotoxic doses. Not 270 POL 40 100 300 7.3. Specific end use(s)

Further information

2-BUTOXYETHANOL H411 Toxic to aquatic life with long lasting effects.

2.1 Classification of the substance or mixture

10.5. Incompatible materials SECTION 5. Firefighting measures Legend: The following sections were modified: Identification Solubility in water Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product OEL H412 mutagenic in the Ames test. EU x = Conc. % Harmful to aquatic life with long lasting effects. 133 20 1272/2008 (CLP) 1000 - 10000 mg/l 333 50 SKIN SECTION 15. Regulatory information (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. GERM CELL MUTAGENICITY 02. Information not available VOC (Directive 2004/42/EC) : Rapidly degradable should be evaluated according to applicable regulations. TLV-ACGIH EUH066 Repeated exposure may cause skin dryness or cracking. 131 20 32,19 % - 450,66 g/litre 5.1. Extinguishing media 2-METHOXY-1-METHYLETHYL ACETATE ETHYLBENZENE The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments 2-METHOXY-1-METHYLETHYL ACETATE VOC (volatile carbon) : Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments 22,83 % - 319,56 g/litre TLV of solvent mixture: Does not meet the classification criteria for this hazard class and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. Incompatible with: oxidising substances,strong acids,alkaline metals. As the counterparts of benzene, may have an acute effect on the central nervous system, with depression, narcosis, often preceded 258 mg/m3 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture CAS Gloss ETHYL ACETATE Waste transportation may be subject to ADR restrictions. 108-65-6 10 ≤ x < 25 Flam. Liq. 3 H226 88(20) 99 (60) 102(85) SECTION 8. Exposure controls/personal protection SUITABLE EXTINGUISHING EQUIPMENT NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. EC Solubility in water CONTAMINATED PACKAGING LEGEND: Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. by dizziness and associated with headache (Ispesl). Is irritating for skin, conjunctiva and respiratory tract. 203-603-9 > 10000 mg/l 8.2. Exposure controls Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can Threshold Limit Value N-METHYL-2-PYRROLIDONE CARCINOGENICITY 8.1. Control parameters INDEX Rapidly degradable Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. - ADR: European Agreement concerning the carriage of Dangerous goods by Road be used to disperse flammable vapours and protect those trying to stem the leak. Seveso Category - Directive 2012/18/EC: 607-195-00-7 P5c SECTION 10. Stability and reactivity Hazard classification and indication: Interactive effects XYLENE (MIXTURE OF ISOMERS) - CAS NUMBER: Chemical Abstract Service Number Hazard classification and indication: Type Incompatible with sulphur,carbon disulphide,oxidising substances,aluminium,metals.Incompatible materials natural rubbers,plastic Country TWA/8h STEL/15min UNSUITABLE EXTINGUISHING EQUIPMENT As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Does not meet the classification criteria for this hazard class materials. mg/m3 ppm mg/m3 ppm CAS BUTYLGLYCOL ACETATE - CE50: Effective concentration (required to induce a 50% effect) Flammable liquid, category 3 1330-20-7 5 ≤ x < 10 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, H226 Flammable liquid and vapour. 10.1. Reactivity Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent Regulatory References: Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 well aired through effective local aspiration. NDS XYLENE (MIXTURE OF ISOMERS) POL 300 900 SECTION 14. Transport information Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Rapidly degradable - CE NUMBER: Identifier in ESIS (European archive of existing substances) Aspiration hazard, category 1 H304 May be fatal if swallowed and enters airways. explosions. When choosing personal protective equipment, ask your chemical substance supplier for advice. ETHYL ACETATE Product Intake of alcohol interferes with the metabolism of the substance, inhibiting it. Ethanol consumption (0.8 g/kg) before a 4-hour XYLENE (MIXTURE OF ISOMERS) - CLP: EC Regulation 1272/2008 Specific target organ toxicity - repeated exposure, Classification note according to Annex VI to the CLP Regulation: C H373 May cause damage to organs through prolonged or 1272/2008 (CLP) 2-METHOXY-1-METHYLETHYL ACETATE CAS 108-65-6 10 ≤ x < 25 Flam. Liq. 3 H226 EC 203-603-9 INDEX 607-195-00-7 XYLENE (MIXTURE OF ISOMERS) CAS 1330-20-7 5 ≤ x < 10 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Classification note according to Annex VI to the CLP Regulation: C EC 215-535-7 INDEX 601-022-00-9 BUTYLGLYCOL ACETATE CAS 112-07-2 2 ≤ x < 5 Acute Tox. 4 H312, Acute Tox. 4 H332 EC 203-933-3 INDEX 607-038-00-2 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM CAS 64742-95-6 0 ≤ x < 2,5 Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, Aquatic Chronic 2 H411, Classification note according to Annex VI to the CLP Regulation: P EC 265-199-0 INDEX 649-356-00-4 NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY CAS 64742-82-1 1 ≤ x < 2,5 Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, Aquatic Chronic 2 H411, Classification note according to Annex VI to the CLP Regulation: P EC 265-185-4 INDEX 649-330-00-2 ETHYLBENZENE CAS 100-41-4 0,1 ≤ x < 2 Flam. Liq. 2 H225, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373 EC 202-849-4 INDEX 601-023-00-4 SECTION 3. Composition/information on ingredients ... / >> N-METHYL-2-PYRROLIDONE CAS 872-50-4 0 ≤ x < 0,3 Repr. 1B H360D, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335 EC 212-828-1 INDEX 606-021-00-7 ETHYL ACETATE CAS 141-78-6 0,05 ≤ x < 0,1 Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336, EUH066 EC 205-500-4 INDEX 607-022-00-5 2-BUTOXYETHANOL CAS 111-76-2 0 ≤ x < 0,05 Acute Tox. 4 H302, Acute Tox. 4 H312, Acute Tox. 4 H332, Eye Irrit. 2 H319, Skin Irrit. 2 H315 EC 203-905-0 INDEX 603-014-00-0 The full wording of hazard (H) phrases is given in section 16 of the sheet.

UN Number

BGR There are no particular risks of reaction with other substances in normal conditions of use. Personal protective equipment must be CE marked, showing that it complies with applicable standards. Point Incompatible with acids,bases,strong oxidants,aluminium,nitrates,chlorosulphuric acid.Incompatible materials plastic materials exposure to xylene vapours (145 and 280 ppm) causes a 50% reduction in the excretion of methyl hippuric acid, whereas the Classified in Group 3 (not classifiable as a human carcinogen) by the International Agency for Research on Cancer (IARC). България 3 - 40 МИНИСТЕРСТВО НА ТРУДА И СОЦИАЛНАТА ПОЛИТИКА МИНИСТЕРСТВО НА repeated exposure. EC NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY - DNEL: Derived No Effect Level category 2 215-535-7 5.2. Special hazards arising from the substance or mixture Exposure levels must be kept as low as possible to avoid significant build-up in the organism. Manage personal protective equipment so as to Contained substance concentration of xylenes in the blood increases approx. 1.5-2 times. At the same time there is an increase in the secondary side The US Environmental Protection Agency (EPA) affirms that "the data is inadequate for an assessment of the carcinogenic potential". ЗДРАВЕОПАЗВАНЕТО НАРЕДБА No 13 от 30 декември 2003 г ETHYLBENZENE INDEX Rapidly degradable - EmS: Emergency Schedule Hazardous to the aquatic environment, chronic 601-022-00-9 H412 Harmful to aquatic life with long lasting effects. 10.6. Hazardous decomposition products CZE 2-METHOXY-1-METHYLETHYL ACETATE ADR / RID, IMDG, IATA: Threshold Limit Value guarantee maximum protection (e.g. reduction in replacement times). Point effects of the ethanol. The metabolism of the xylenes is increased by phenobarbital and 3-methyl-colantrene type enzyme inducers. Česká Republika 30 1263 Nařízení vlády č. 361/2007 Sb. kterým se stanoví podmínky ochrany zdraví při práci N-METHYL-2-PYRROLIDONE BUTYLGLYCOL ACETATE - GHS: Globally Harmonized System of classification and labeling of chemicals toxicity, category 3 HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE FRA HAND PROTECTION Stable in normal conditions of use and storage. Type Aspirin and xylenes mutually inhibit their conjugation with the glycine, which results in a decrease in urinary excretion of methyl ETHYLBENZENE France Country TWA/8h JORF n°0109 du 10 mai 2012 page 8773 texte n° 102 STEL/15min 14.2. UN proper shipping name CAS SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM - IATA DGR: International Air Transport Association Dangerous Goods Regulation Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. GBR Substances in Candidate List (Art. 59 REACH) 112-07-2 United Kingdom 2 ≤ x < 5 EH40/2005 Workplace exposure limits Acute Tox. 4 H312, Acute Tox. 4 H332

2.2 Label elements

Protect hands with category III work gloves (see standard EN 374). In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. EC Rapidly degradable - IC50: Immobilization Concentration 50% hippuric acid. Other industrial products can interfere with the metabolism of xylenes. Classified in Group 2B (possible human carcinogen) by the International Agency for Research on Cancer (IARC) - (IARC, 2000). 203-933-3 mg/m3 ppm mg/m3 ppm GRC With the air it may slowly develop peroxides that explode with an increase in temperature. N-METHYL-2-PYRROLIDONE The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. TLV Classified in Group D (not classifiable as a human carcinogen) by the US Environmental Protection Agency (EPA) - (US EPA file Ελλάδα BGR 435 ΕΦΗΜΕΡΙΣ ΤΗΣ ΚΥΒΕΡΝΗΣΕΩΣ -ΤΕΥΧΟΣ ΠΡΩΤΟ Αρ. Φύλλου 19 - 9 Φεβρουαρίου 2012 545 SKIN 5.3. Advice for firefighters INDEX - IMDG: International Maritime Code for dangerous goods POL ADR / RID: 607-038-00-2 Polska PAINT or PAINT RELATED MATERIAL ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 7 czerwca 2017 r The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on ETHYLBENZENE Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. TLV N-METHYL-2-PYRROLIDONE on-line 2014). CZE 200 500 12.3. Bioaccumulative potential SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM - IMO: International Maritime Organization EU N-METHYL-2-PYRROLIDONE IMDG: Substances subject to authorisarion (Annex XIV REACH) SKIN OEL EU PAINT or PAINT RELATED MATERIAL Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; the duration and type of use. VLEP May develop: methane,styrene,hydrogen,ethane. The substance enhances the skin permeability of many other substances. FRA 88,4 20 442 CAS - INDEX NUMBER: Identifier in Annex VI of CLP GENERAL INFORMATION IATA: None Decomposes at temperatures above 300°C/572°F.Dissolves various plastic materials. 100 64742-95-6 SKIN PAINT or PAINT RELATED MATERIAL 0 ≤ x < 2,5 Directive 2004/37/EC; Directive 2000/39/EC; Directive 91/322/EEC. Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336,

Hazard pictograms

SKIN PROTECTION REPRODUCTIVE TOXICITY - LC50: Lethal Concentration 50% WEL GBR 441 100 Aquatic Chronic 2 H411, 552 125 SKIN Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body N-METHYL-2-PYRROLIDONE ACUTE TOXICITY TLV TLV-ACGIH GRC 435 ACGIH 2017 100 545 125 XYLENE (MIXTURE OF ISOMERS) - LD50: Lethal dose 50% health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of When exposed to the air it oxidates slowly to develop hydroperoxides. Completely mixable with water with a neutral or slightly basic reaction. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Classification note according to Annex VI to the CLP Regulation: P with soap and water after removing protective clothing. Does not meet the classification criteria for this hazard class EC Partition coefficient: n-octanol/water - OEL: Occupational Exposure Level NDS May develop: nitric oxide,carbon oxides. 265-199-0 POL 200 3,12 400 contaminated water used for extinction and the remains of the fire according to applicable regulations. It does not attack common materials. None OEL Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. LC50 (Inhalation) of the mixture: EU 442 100 > 20 mg/l 884 200 SKIN INDEX BCF

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS 649-356-00-4 25,9 EYE PROTECTION 2-BUTOXYETHANOL LD50 (Oral) of the mixture: STOT - SINGLE EXPOSURE NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY - PEC: Predicted environmental Concentration TLV-ACGIH 87 20 Not classified (no significant component) Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with ETHYL ACETATE Substances subject to the Rotterdam Convention: Wear airtight protective goggles (see standard EN 166). LD50 (Dermal) of the mixture: May develop: hydrogen. >2000 mg/kg CAS 2-METHOXY-1-METHYLETHYL ACETATE - PEL: Predicted exposure level self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Decomposes slowly into acetic acid and ethanol under the effect of light, air and water. None 64742-82-1 1 ≤ x < 2,5 Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, STOT SE 3 H336, RESPIRATORY PROTECTION Does not meet the classification criteria for this hazard class Partition coefficient: n-octanol/water - PNEC: Predicted no effect concentration Aquatic Chronic 2 H411, 1,2 If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type - REACH: EC Regulation 1907/2006 Classification note according to Annex VI to the CLP Regulation: P

TOXICOLOGICAL INFORMATION

2-BUTOXYETHANOL Substances subject to the Stockholm Convention: A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases STOT - REPEATED EXPOSURE XYLENE (MIXTURE OF ISOMERS) SECTION 6. Accidental release measures EC N-METHYL-2-PYRROLIDONE - RID: Regulation concerning the international transport of dangerous goods by train None Decomposes under the effect of heat. 265-185-4

Signal word

or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. INDEX In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it Partition coefficient: n-octanol/water - TLV: Threshold Limit Value LD50 (Oral) 649-330-00-2 Danger -0,46 3523 mg/kg Rat 6.1. Personal precautions, protective equipment and emergency procedures Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the May cause damage to organs ETHYLBENZENE contains, using the criteria specified in the applicable regulation for classification. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. LD50 (Dermal) 4350 mg/kg Rabbit 10.2. Chemical stability

Hazard statements

threshold values considered. The protection provided by masks is in any case limited. Healthcare controls CAS It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the ETHYLBENZENE - TWA STEL: Short-term exposure limit LC50 (Inhalation) 100-41-4 0,1 ≤ x < 2 Flam. Liq. 2 H225, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373 26 mg/l/4h Rat Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks Block the leakage if there is no hazard. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an

Aspiration hazard

H226 Flammable liquid and vapour. EC toxicological effects of exposure to the product. Partition coefficient: n-octanol/water - TWA: Time-weighted average exposure limit The product is stable in normal conditions of use and storage. related to the workers' health and safety are modest and that the 98/24/EC directive is respected. 202-849-4 3,6 Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing INDEX - VOC: Volatile organic Compounds H304 601-023-00-4 May be fatal if swallowed and enters airways. any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. Toxic for aspiration

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation H373 May cause damage to organs through prolonged or repeated exposure. EPY 9.6.6 - SDS 1004.9 H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P301+P310 IF SWALLOWED: immediately call a POISON CENTER / doctor / . . . P331 Do NOT induce vomiting. P370+P378 In case of fire: use . . . to extinguish.

Contains

XYLENE (MIXTURE OF ISOMERS) NAPHTHA (PETROL.) HYDRODESULFURIZED HEAVY SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM ETHYLBENZENE VOC (Directive 2004/42/EC) : Two-pack performance coatings. VOC given in g/litre of product in a ready-to-use condition : 427,36 Limit value: 500,00 - Catalysed with : 50,00 % POOLGLOSS COMPONENT Β - Thinned with : 5,00 % THINNER 120 Identification x = Conc. %

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. SECTION 3. Composition/information on ingredients 3.1. Substances Information not relevant 3.2. Mixtures