May develop: calcium oxides,carbon oxides

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H330, H331, H400, H410, H411

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

1272/2008 Upper inflammability limit Information not available waterways. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. Please take all the Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2 Not available 4.1. Description of first aid measures 14.3. Transport hazard class(es) Lower explosive limit proper measures to reduce harmful effects on aquifers. H330 Fatal if inhaled. Not available

2.1 Classification of the substance or mixture

Upper explosive limit Interactive effects H301 Toxic if swallowed. Not available Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the Note for users: 12.1. Toxicity Vapour pressure H311 Toxic in contact with skin. 23 mmHg EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering Not applicable The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Vapour density Information not available The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). H331 Toxic if inhaled. Not available persists, seek medical advice. places in which people eat. suitability and thoroughness of provided information according to each specific use of the product. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Relative density However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data H302 Harmful if swallowed. 1,41 14.4. Packing group SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention immediately. Wash contaminated This document must not be regarded as a guarantee on any specific product property. sheet with appropriate information, compliant to (EU) Regulation 2015/830. Solubility ACUTE TOXICITY ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL sheet with appropriate information, compliant to (EU) Regulation 2015/830. H314 Causes severe skin burns and eye damage. WATER 7.2. Conditions for safe storage, including any incompatibilities clothing before using it again. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Partition coefficient: n-octanol/water LC50 - for Fish INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention immediately. Not applicable H318 Causes serious eye damage. 33 mg/l/96h Pimephales promelas Not available Hazard classification and indication: and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Auto-ignition temperature LC50 (Inhalation) of the mixture: EC50 - for Crustacea Hazard classification and indication: H315 Causes skin irritation. -- 147,8 mg/l/48h Daphnia magna Not available Not classified (no significant component) INGESTION: Get medical advice/attention immediately. Do not induce vomiting. Do not administer anything not explicitly authorised by a Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Provide appointed staff with adequate training on how to use chemical products.

Environmental hazards

Decomposition temperature LD50 (Oral) of the mixture: EC50 - for Algae / Aquatic Plants doctor. from any incompatible materials, see section 10 for details. H317 May cause an allergic skin reaction. > 57 mg/l/72h Pseudokirchnerella subcapitata Not available Not classified (no significant component) Viscosity LD50 (Dermal) of the mixture: H400 Very toxic to aquatic life. 110-120 KU Not classified (no significant component)

2.2 Label elements

12.2. Persistence and degradability Changes to previous review: Explosive properties H410 Very toxic to aquatic life with long lasting effects. Not available 4.2. Most important symptoms and effects, both acute and delayed 7.3. Specific end use(s) Not applicable The following sections were modified: Oxidising properties H411 Toxic to aquatic life with long lasting effects. Not available Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 01 / 02 / 03 / 04 / 08 / 09 / 10 / 11 / 12 / 14 / 15 / 16. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. EUH210 reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) Safety data sheet available on request. 14.6. Special precautions for user Specific information on symptoms and effects caused by the product are unknown. Information not available

Further information

CALCIUM CARBONATE LD50 (Oral) 481 mg/kg

Hazard pictograms

Solubility in water LD50 (Dermal) -- 0,1 - 100 mg/l > 1,008 mg/kg 4.3. Indication of any immediate medical attention and special treatment needed Not applicable SECTION 8. Exposure controls/personal protection VOC (Directive 2004/42/EC) : LEGEND: LC50 (Inhalation) 1,50 % - 21,15 1,23 mg/l/4h g/litre

Signal word

Gloss TALC - ADR: European Agreement concerning the carriage of Dangerous goods by Road -- 3,5 (60) 14,6 (85) 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Information not available Solubility in water - CAS NUMBER: Chemical Abstract Service Number CALCIUM CARBONATE < 0,1 mg/l 8.1. Control parameters

Hazard statements

CE50: Effective concentration (required to induce a 50% effect) LD50 (Oral) 6450 mg/kg Rat Information not relevant SECTION 10. Stability and reactivity SECTION 5. Firefighting measures TITANIUM DIOXIDE - CE NUMBER: Identifier in ESIS (European archive of existing substances) EUH210 Safety data sheet available on request. TLV of solvent mixture: Solubility in water - CLP: EC Regulation 1272/2008 EUH208 TITANIUM DIOXIDE

Contains

reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one 1 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one < 0,001 mg/l mg/m3 10.1. Reactivity 5.1. Extinguishing media SECTION 15. Regulatory information Degradability: information not available - DNEL: Derived No Effect Level LD50 (Oral) (3:1) > 10000 mg/kg Rat 8.2. Exposure controls - EmS: Emergency Schedule 1,2-Benzoisothiazol-3(2H)-one There are no particular risks of reaction with other substances in normal conditions of use. SUITABLE EXTINGUISHING EQUIPMENT ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - GHS: Globally Harmonized System of classification and labeling of chemicals ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL May produce an allergic reaction. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Solubility in water - IATA DGR: International Air Transport Association Dangerous Goods Regulation LD50 (Oral) 1360 mg/l 6500 mg/kg Rat - Carworth-Wistar CALCIUM CARBONATE UNSUITABLE EXTINGUISHING EQUIPMENT well aired through effective local aspiration. Rapidly degradable - IC50: Immobilization Concentration 50% Decomposes at temperatures above 800°C/1472°F. LD50 (Dermal) > 15200 mg/kg Rabbit - New Zeland white

Precautionary statements

None in particular. When choosing personal protective equipment, ask your chemical substance supplier for advice. Seveso Category - Directive 2012/18/EC: - IMDG: International Maritime Code for dangerous goods -- None 12.3. Bioaccumulative potential Personal protective equipment must be CE marked, showing that it complies with applicable standards. SKIN CORROSION / IRRITATION - IMO: International Maritime Organization 10.2. Chemical stability 5.2. Special hazards arising from the substance or mixture HAND PROTECTION Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 VOC (Directive 2004/42/EC) : - INDEX NUMBER: Identifier in Annex VI of CLP VOC (Directive 2004/42/EC) : Coatings for exterior walls of mineral substrate. Protect hands with category III work gloves (see standard EN 374). None Does not meet the classification criteria for this hazard class - LC50: Lethal Concentration 50% Coatings for exterior walls of mineral substrate. The product is stable in normal conditions of use and storage. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. VOC given in g/litre of product in a ready-to-use condition : ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - LD50: Lethal dose 50% VOC given in g/litre of product in a ready-to-use condition : 11,74 Limit value: Do not breathe combustion products. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on Substances in Candidate List (Art. 59 REACH) SERIOUS EYE DAMAGE / IRRITATION Partition coefficient: n-octanol/water - OEL: Occupational Exposure Level Limit value: 3,2 40,00 10.3. Possibility of hazardous reactions - Thinned with : the duration and type of use. On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. BCF

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation - Thinned with : 10,00 % 44,1 10,00 % WATER 5.3. Advice for firefighters SKIN PROTECTION Does not meet the classification criteria for this hazard class - PEC: Predicted environmental Concentration No hazardous reactions are foreseeable in normal conditions of use and storage. Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body Substances subject to authorisarion (Annex XIV REACH) 12.4. Mobility in soil - PEL: Predicted exposure level

2.3 Other hazards

GENERAL INFORMATION with soap and water after removing protective clothing. None RESPIRATORY OR SKIN SENSITISATION - PNEC: Predicted no effect concentration 10.4. Conditions to avoid Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for EYE PROTECTION - REACH: EC Regulation 1907/2006 On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Wear airtight protective goggles (see standard EN 166). Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: May produce an allergic reaction. ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - RID: Regulation concerning the international transport of dangerous goods by train On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. EPY 9.6.6 - SDS 1004.9