LD50 (Dermal)

SECTION 2: Hazards identification

1272/2008 HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE None required. REPRODUCTIVE TOXICITY suitability and thoroughness of provided information according to each specific use of the product. VOC (Directive 2004/42/EC) : SECTION 13. Disposal considerations Do not breathe combustion products. RESPIRATORY PROTECTION This document must not be regarded as a guarantee on any specific product property.

2.1 Classification of the substance or mixture

Information not available Interior/exterior trim and cladding paints for wood, metal or plastic. If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type Does not meet the classification criteria for this hazard class The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health 13.1. Waste treatment methods 5.3. Advice for firefighters A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases and safety laws and regulations. The producer is relieved from any liability arising from improper uses. 10.6. Hazardous decomposition products 15.2. Chemical safety assessment The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. STOT - SINGLE EXPOSURE Provide appointed staff with adequate training on how to use chemical products. amendments and supplements). Reuse, when possible. Neat product residues should be considered special non-hazardous waste. amendments and supplements). GENERAL INFORMATION Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the Information not available Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. No chemical safety assessment has been processed for the mixture and the substances it contains. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for threshold values considered. The protection provided by masks is in any case limited. Hazard classification and indication: Does not meet the classification criteria for this hazard class Changes to previous review: CONTAMINATED PACKAGING Hazard classification and indication: -- health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an The following sections were modified: Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. contaminated water used for extinction and the remains of the fire according to applicable regulations. emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing

Further information

STOT - REPEATED EXPOSURE 01 / 02 / 04 / 05 / 06 / 07 / 08 / 09 / 11 / 12 / 14 / 15. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.

2.2 Label elements

SECTION 14. Transport information Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with ENVIRONMENTAL EXPOSURE CONTROLS According to currently available data, this product has not yet produced health damages. Anyway, it must be handled according to good Does not meet the classification criteria for this hazard class self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure industrial practices. LEGEND:

Hazard pictograms

compliance with environmental standards. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail - ADR: European Agreement concerning the carriage of Dangerous goods by Road

Aspiration hazard

11.1. Information on toxicological effects (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. - CAS NUMBER: Chemical Abstract Service Number SECTION 6. Accidental release measures

Signal word

CE50: Effective concentration (required to induce a 50% effect) Does not meet the classification criteria for this hazard class

UN Number

SECTION 9. Physical and chemical properties Metabolism, toxicokinetics, mechanism of action and other information - CE NUMBER: Identifier in ESIS (European archive of existing substances) 6.1. Personal precautions, protective equipment and emergency procedures

Hazard statements

CLP: EC Regulation 1272/2008 9.1. Information on basic physical and chemical properties

ECOLOGICAL INFORMATION

Information not available Not applicable - DNEL: Derived No Effect Level Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in

Precautionary statements

EmS: Emergency Schedule emergency procedures. 14.2. UN proper shipping name Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or Information on likely routes of exposure - GHS: Globally Harmonized System of classification and labeling of chemicals VOC (Directive 2004/42/EC) : Appearance contaminate soil or vegetation. VOC (Directive 2004/42/EC) : liquid - IATA DGR: International Air Transport Association Dangerous Goods Regulation 6.2. Environmental precautions Interior/exterior trim and cladding paints for wood, metal or plastic. Colour Interior/exterior trim and cladding paints for wood, metal or plastic. white Information not available Not applicable - IC50: Immobilization Concentration 50% Odour characteristic 12.1. Toxicity VOC given in g/litre of product in a ready-to-use condition : 34,00 - IMDG: International Maritime Code for dangerous goods The product must not penetrate into the sewer system or come into contact with surface water or ground water. Odour threshold Not available Limit value: 130,00 14.3. Transport hazard class(es) Delayed and immediate effects as well as chronic effects from short and long-term exposure - IMO: International Maritime Organization pH 8,5 - Thinned with : 5,00 % WATER 6.3. Methods and material for containment and cleaning up - INDEX NUMBER: Identifier in Annex VI of CLP Melting point / freezing point Not available ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL Information not available Not applicable - LC50: Lethal Concentration 50% Initial boiling point LC50 - for Fish 33 mg/l/96h Pimephales promelas Not available - LD50: Lethal dose 50% Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material Boiling range Not available

2.3 Other hazards

EC50 - for Crustacea 147,8 mg/l/48h Daphnia magna 14.4. Packing group Interactive effects - OEL: Occupational Exposure Level should be disposed of in compliance with the provisions set forth in point 13. Flash point > 60 °C EC50 - for Algae / Aquatic Plants > 57 mg/l/72h Pseudokirchnerella subcapitata

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Evaporation Rate Not available On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. 6.4. Reference to other sections Information not available Not applicable - PEC: Predicted environmental Concentration Flammability of solids and gases Not available 12.2. Persistence and degradability - PEL: Predicted exposure level