DECONYL SILK WHITE

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H330, H331, H400, H410, H411

Code

Statements

H301

Toxic if swallowed

ECOLOGICAL INFORMATION

Flash point Information not available Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2 > 60 °C 4.1. Description of first aid measures 14.3. Transport hazard class(es) Evaporation Rate H330 Fatal if inhaled. Not available

2.1 Classification of the substance or mixture

Flammability of solids and gases Delayed and immediate effects as well as chronic effects from short and long-term exposure No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil and H301 Toxic if swallowed. Not available Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Vapours may catch fire and an explosion may Note for users: Lower inflammability limit waterways. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. Please take all the H311 Toxic in contact with skin. Not available EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem occur; vapour accumulation is therefore to be avoided by leaving windows and doors open and ensuring good cross ventilation. Without Not applicable The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Upper inflammability limit Information not available proper measures to reduce harmful effects on aquifers. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). H331 Toxic if inhaled. Not available persists, seek medical advice. adequate ventilation, vapours may accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid suitability and thoroughness of provided information according to each specific use of the product. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Lower explosive limit However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data H302 Harmful if swallowed. Not available 14.4. Packing group SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash bunching of electrostatic charges. When performing transfer operations involving large containers, connect to an earthing system and wear This document must not be regarded as a guarantee on any specific product property. 12.1. Toxicity sheet with appropriate information, compliant to (EU) Regulation 2015/830. Upper explosive limit Interactive effects sheet with appropriate information, compliant to (EU) Regulation 2015/830. H314 Causes severe skin burns and eye damage. Not available contaminated clothing before using it again. antistatic footwear. Vigorous stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Vapour pressure INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately. charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they Not applicable H318 Causes serious eye damage. 23 mmHg Hazard classification and indication: and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Vapour density Information not available Hazard classification and indication: H315 Causes skin irritation. -- Not available INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious may be pressurised. Do not eat, drink or smoke during use. Avoid leakage of the product into the environment. Provide appointed staff with adequate training on how to use chemical products.

Environmental hazards

Relative density ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL person, unless authorised by a doctor. H317 May cause an allergic skin reaction. 1,28 7.2. Conditions for safe storage, including any incompatibilities Solubility ACUTE TOXICITY LC50 - for Fish H400 Very toxic to aquatic life. 33 mg/l/96h Pimephales promelas WATER

2.2 Label elements

Changes to previous review: Partition coefficient: n-octanol/water EC50 - for Crustacea H410 Very toxic to aquatic life with long lasting effects. 147,8 mg/l/48h Daphnia magna Not available 4.2. Most important symptoms and effects, both acute and delayed Not applicable The following sections were modified: Auto-ignition temperature LC50 (Inhalation) of the mixture: EC50 - for Algae / Aquatic Plants Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a well ventilated H411 Toxic to aquatic life with long lasting effects. > 57 mg/l/72h Pseudokirchnerella subcapitata Not available Not classified (no significant component) Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 01 / 02 / 03 / 04 / 05 / 07 / 08 / 09 / 10 / 11 / 12 / 14 / 15 / 16. Decomposition temperature LD50 (Oral) of the mixture: Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. EUH210 Safety data sheet available on request. Not available Not classified (no significant component) 14.6. Special precautions for user Specific information on symptoms and effects caused by the product are unknown. place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any 12.2. Persistence and degradability Viscosity LD50 (Dermal) of the mixture: 95-105 KU Not classified (no significant component) incompatible materials, see section 10 for details.

Hazard pictograms

Explosive properties -- Not available 4.3. Indication of any immediate medical attention and special treatment needed Not applicable 7.3. Specific end use(s) Oxidising properties LEGEND: Not available

Signal word

CALCIUM CARBONATE - ADR: European Agreement concerning the carriage of Dangerous goods by Road reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) -- 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Information not available

Further information

Solubility in water - CAS NUMBER: Chemical Abstract Service Number Information not available LD50 (Oral) 0,1 - 100 mg/l 481 mg/kg

Hazard statements

CE50: Effective concentration (required to induce a 50% effect) LD50 (Dermal) > 1,008 mg/kg Information not relevant SECTION 5. Firefighting measures VOC (Directive 2004/42/EC) : TITANIUM DIOXIDE - CE NUMBER: Identifier in ESIS (European archive of existing substances) EUH210 LC50 (Inhalation) Safety data sheet available on request. 2,31 % - 29,52 1,23 mg/l/4h g/litre SECTION 8. Exposure controls/personal protection Gloss Solubility in water - CLP: EC Regulation 1272/2008 EUH208

Contains

reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one < 0,001 mg/l 9-11 (60) 28-35 (85) 5.1. Extinguishing media SECTION 15. Regulatory information Degradability: information not available - DNEL: Derived No Effect Level CALCIUM CARBONATE (3:1) - EmS: Emergency Schedule LD50 (Oral) 1,2-Benzoisothiazol-3(2H)-one 6450 mg/kg Rat 8.1. Control parameters SECTION 10. Stability and reactivity SUITABLE EXTINGUISHING EQUIPMENT ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - GHS: Globally Harmonized System of classification and labeling of chemicals May produce an allergic reaction. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. Solubility in water - IATA DGR: International Air Transport Association Dangerous Goods Regulation TITANIUM DIOXIDE 1360 mg/l 10.1. Reactivity UNSUITABLE EXTINGUISHING EQUIPMENT TLV of solvent mixture: 1,02 mg/m3 Rapidly degradable - IC50: Immobilization Concentration 50% LD50 (Oral) > 10000 mg/kg Rat

Precautionary statements

None in particular. Seveso Category - Directive 2012/18/EC: - IMDG: International Maritime Code for dangerous goods -- None 8.2. Exposure controls There are no particular risks of reaction with other substances in normal conditions of use. 12.3. Bioaccumulative potential - IMO: International Maritime Organization ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL 5.2. Special hazards arising from the substance or mixture VOC (Directive 2004/42/EC) : Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 - INDEX NUMBER: Identifier in Annex VI of CLP VOC (Directive 2004/42/EC) : LD50 (Oral) 6500 mg/kg Rat - Carworth-Wistar CALCIUM CARBONATE As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Matt coatings for interior walls and ceilings. None LD50 (Dermal) - LC50: Lethal Concentration 50% Matt coatings for interior walls and ceilings. > 15200 mg/kg Rabbit - New Zeland white HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE well aired through effective local aspiration. Decomposes at temperatures above 800°C/1472°F. VOC given in g/litre of product in a ready-to-use condition : ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - LD50: Lethal dose 50% VOC given in g/litre of product in a ready-to-use condition : 11,81 Limit value: Do not breathe combustion products. When choosing personal protective equipment, ask your chemical substance supplier for advice. Substances in Candidate List (Art. 59 REACH) SKIN CORROSION / IRRITATION Partition coefficient: n-octanol/water - OEL: Occupational Exposure Level Limit value: 3,2 30,00 10.2. Chemical stability - Thinned with : Personal protective equipment must be CE marked, showing that it complies with applicable standards. On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. BCF

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation - Thinned with : 10,00 % 44,1 10,00 % WATER 5.3. Advice for firefighters HAND PROTECTION Does not meet the classification criteria for this hazard class - PEC: Predicted environmental Concentration The product is stable in normal conditions of use and storage. Protect hands with category III work gloves (see standard EN 374). Substances subject to authorisarion (Annex XIV REACH) 12.4. Mobility in soil - PEL: Predicted exposure level

2.3 Other hazards

GENERAL INFORMATION The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. None SERIOUS EYE DAMAGE / IRRITATION - PNEC: Predicted no effect concentration 10.3. Possibility of hazardous reactions Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on - REACH: EC Regulation 1907/2006 On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of the duration and type of use. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Does not meet the classification criteria for this hazard class ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - RID: Regulation concerning the international transport of dangerous goods by train On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. EPY 9.6.6 - SDS 1004.9