DECO VAROSI

Hazard statements (CLP)

H301, H311, H314, H317, H331, H400, H410

Code

Statements

H301

Toxic if swallowed

Further information

Does not meet the classification criteria for this hazard class 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. SUITABLE EXTINGUISHING EQUIPMENT GERM CELL MUTAGENICITY - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. - IFA GESTIS website SECTION 14. Transport information the duration and type of use. The product is stable in normal conditions of use and storage. Text of hazard (H) indications mentioned in section 2-3 of the sheet:

2.1 Classification of the substance or mixture

8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Information not available Healthcare controls Specific information on symptoms and effects caused by the product are unknown. TLV of solvent mixture: SERIOUS EYE DAMAGE / IRRITATION 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament 1 mg/m3 VOC (Directive 2010/75/EC) : Information not available 0 The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament Gloss The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). SATIN 4.3. Indication of any immediate medical attention and special treatment needed 8.2. Exposure controls SECTION 13. Disposal considerations Does not meet the classification criteria for this hazard class 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data VOC (Directive 2004/42/EC) : However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data sheet with appropriate information, compliant to (EU) Regulation 2015/830. 12. Regulation (EU) 2016/1179 (IX Atp. CLP) Decorative effect coatings. sheet with appropriate information, compliant to (EU) Regulation 2015/830. 13.1. Waste treatment methods SECTION 10. Stability and reactivity Information not available As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is RESPIRATORY OR SKIN SENSITISATION 13. Regulation (EU) 2017/776 (X Atp. CLP) well aired through effective local aspiration. 15.2. Chemical safety assessment Hazard classification and indication: -- 10.1. Reactivity When choosing personal protective equipment, ask your chemical substance supplier for advice. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. May produce an allergic reaction. - The Merck Index. - 10th Edition SECTION 5. Firefighting measures Personal protective equipment must be CE marked, showing that it complies with applicable standards. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.

Contains

Handling Chemical Safety No chemical safety assessment has been processed for the mixture and the substances it contains. HAND PROTECTION There are no particular risks of reaction with other substances in normal conditions of use. CONTAMINATED PACKAGING reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type This document must not be regarded as a guarantee on any specific product property. H301 Toxic if swallowed. (3:1) 5.3. Advice for firefighters 14.2. UN proper shipping name B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases None in particular. However the usual precautions used for chemical products should be respected. Does not meet the classification criteria for this hazard class The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health H311 Toxic in contact with skin. May produce an allergic reaction. or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. H331 Toxic if inhaled. 10.5. Incompatible materials Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the GENERAL INFORMATION STOT - SINGLE EXPOSURE Not applicable Provide appointed staff with adequate training on how to use chemical products. H314 Causes severe skin burns and eye damage. threshold values considered. The protection provided by masks is in any case limited. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for H317 May cause an allergic skin reaction.

2.2 Label elements

5.1. Extinguishing media reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) - INRS - Fiche Toxicologique (toxicological sheet) Protect hands with category III work gloves (see standard EN 374). Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. - Patty - Industrial Hygiene and Toxicology 10.2. Chemical stability

Hazard pictograms

UNSUITABLE EXTINGUISHING EQUIPMENT Does not meet the classification criteria for this hazard class - ECHA website -- SKIN PROTECTION None in particular. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy 10.3. Possibility of hazardous reactions Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body CARCINOGENICITY (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. Acute Tox. 3 Acute toxicity, category 3

Signal word

5.2. Special hazards arising from the substance or mixture with soap and water after removing protective clothing. Skin Corr. 1B Skin corrosion, category 1B

UN Number

EYE PROTECTION No hazardous reactions are foreseeable in normal conditions of use and storage. Does not meet the classification criteria for this hazard class Note for users: Skin Sens. 1 Skin sensitization, category 1

Hazard statements

Wear airtight protective goggles (see standard EN 166). The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1 HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE EUH210 Safety data sheet available on request. 10.4. Conditions to avoid RESPIRATORY PROTECTION REPRODUCTIVE TOXICITY suitability and thoroughness of provided information according to each specific use of the product. Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1 Do not breathe combustion products. Not applicable EUH208

Precautionary statements

14.3. Transport hazard class(es) If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an Information not available health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Does not meet the classification criteria for this hazard class Changes to previous review: H400 Very toxic to aquatic life. emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing contaminated water used for extinction and the remains of the fire according to applicable regulations. The following sections were modified: H410 Very toxic to aquatic life with long lasting effects. VOC (Directive 2004/42/EC) : 10.6. Hazardous decomposition products apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS STOT - REPEATED EXPOSURE Not applicable 02 / 03 / 08 / 11 / 12 / 16. EUH210 Safety data sheet available on request. Decorative effect coatings. ENVIRONMENTAL EXPOSURE CONTROLS Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with VOC given in g/litre of product in a ready-to-use condition : 0,00 14.4. Packing group The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure Information not available self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Does not meet the classification criteria for this hazard class Limit value: 200,00 compliance with environmental standards. LEGEND: - ADR: European Agreement concerning the carriage of Dangerous goods by Road

TOXICOLOGICAL INFORMATION

Not applicable SECTION 6. Accidental release measures - CAS NUMBER: Chemical Abstract Service Number

Environmental hazards

6.1. Personal precautions, protective equipment and emergency procedures In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it Does not meet the classification criteria for this hazard class - CE50: Effective concentration (required to induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive of existing substances) contains, using the criteria specified in the applicable regulation for classification. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - CLP: EC Regulation 1272/2008 It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the Not applicable Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in - DNEL: Derived No Effect Level toxicological effects of exposure to the product. emergency procedures. EPY 9.6.6 - SDS 1004.9