Block the leakage if there is no hazard

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) Upper inflammability limit Information not available - ADR: European Agreement concerning the carriage of Dangerous goods by Road Not available 7.1. Precautions for safe handling 12.2. Persistence and degradability 4.1. Description of first aid measures Lower explosive limit Information not relevant - CAS NUMBER: Chemical Abstract Service Number Not available

2.1 Classification of the substance or mixture

Upper explosive limit ACUTE TOXICITY - CE50: Effective concentration (required to induce a 50% effect) Not available Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the Vapour pressure - CE NUMBER: Identifier in ESIS (European archive of existing substances) Not available SECTION 15. Regulatory information EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Vapour density LC50 (Inhalation) of the mixture: ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - CLP: EC Regulation 1272/2008 The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Not available Not classified (no significant component) medical advice/attention. places in which people eat. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Relative density LD50 (Oral) of the mixture: Solubility in water - DNEL: Derived No Effect Level However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data 1360 mg/l 1,02 Not classified (no significant component) SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. sheet with appropriate information, compliant to (EU) Regulation 2015/830. Solubility LD50 (Dermal) of the mixture: Rapidly degradable - EmS: Emergency Schedule sheet with appropriate information, compliant to (EU) Regulation 2015/830. WATER Not classified (no significant component) 7.2. Conditions for safe storage, including any incompatibilities 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly Partition coefficient: n-octanol/water - GHS: Globally Harmonized System of classification and labeling of chemicals authorised by a doctor. Not available 12.3. Bioaccumulative potential Hazard classification and indication: Auto-ignition temperature - IATA DGR: International Air Transport Association Dangerous Goods Regulation Hazard classification and indication: -- Not available INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Seveso Category - Directive 2012/18/EC: None Decomposition temperature - IC50: Immobilization Concentration 50% breathing, administer artificial respiration. Take suitable precautions for rescue workers. from any incompatible materials, see section 10 for details. reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) Not available Viscosity - IMDG: International Maritime Code for dangerous goods Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 LD50 (Oral) 90-110 KU 481 mg/kg

2.2 Label elements

Explosive properties ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - IMO: International Maritime Organization LD50 (Dermal) Not available > 1,008 mg/kg 4.2. Most important symptoms and effects, both acute and delayed 7.3. Specific end use(s) None Oxidising properties Partition coefficient: n-octanol/water - INDEX NUMBER: Identifier in Annex VI of CLP LC50 (Inhalation) 3,2 Not available 1,23 mg/l/4h Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. BCF - LC50: Lethal Concentration 50% Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 44,1 Specific information on symptoms and effects caused by the product are unknown. Information not available Substances in Candidate List (Art. 59 REACH)

Further information

LD50: Lethal dose 50% ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. 12.4. Mobility in soil

Hazard pictograms

OEL: Occupational Exposure Level LD50 (Oral) -- 6500 mg/kg Rat - Carworth-Wistar 4.3. Indication of any immediate medical attention and special treatment needed SECTION 8. Exposure controls/personal protection VOC (Directive 2004/42/EC) :

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Substances subject to authorisarion (Annex XIV REACH) LD50 (Dermal) 3,00 % - 30,61 > 15200 mg/kg Rabbit - New Zeland white g/litre

Signal word

Gloss - PEC: Predicted environmental Concentration -- SATIN Information not available None SKIN CORROSION / IRRITATION ISOBUTYRIC ACID, MONOESTER WITH 2,2,4-TRIMETHYLPENTANE-1,3-DIOL - PEL: Predicted exposure level 8.1. Control parameters

Hazard statements

Partition coefficient: soil/water - PNEC: Predicted no effect concentration 2,2181 Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: SECTION 10. Stability and reactivity SECTION 5. Firefighting measures Does not meet the classification criteria for this hazard class - REACH: EC Regulation 1907/2006 EUH210 Safety data sheet available on request. None

Results of PBT and vPvB assessment

Information not available - RID: Regulation concerning the international transport of dangerous goods by train EUH208

Contains

reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one 10.1. Reactivity 5.1. Extinguishing media SERIOUS EYE DAMAGE / IRRITATION - TLV: Threshold Limit Value (3:1) 8.2. Exposure controls Substances subject to the Rotterdam Convention: On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. 1,2-Benzoisothiazol-3(2H)-one There are no particular risks of reaction with other substances in normal conditions of use. None SUITABLE EXTINGUISHING EQUIPMENT Does not meet the classification criteria for this hazard class - TWA STEL: Short-term exposure limit May produce an allergic reaction. VOC (Directive 2004/42/EC) : 10.3. Possibility of hazardous reactions SECTION 13. Disposal considerations Information not available Protect hands with category III work gloves (see standard EN 374). Decorative effect coatings. reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) Decorative effect coatings. VOC given in g/litre of product in a ready-to-use condition : HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. 1,2-Benzoisothiazol-3(2H)-one GENERAL BIBLIOGRAPHY VOC given in g/litre of product in a ready-to-use condition : 30,61 13.1. Waste treatment methods No hazardous reactions are foreseeable in normal conditions of use and storage. VOC (Directive 2004/42/EC) : Do not breathe combustion products. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on Limit value: 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament Limit value: 200,00 Decorative effect coatings. the duration and type of use. GERM CELL MUTAGENICITY 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament 10.4. Conditions to avoid Reuse, when possible. Neat product residues should be considered special non-hazardous waste. 5.3. Advice for firefighters SKIN PROTECTION 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 15.2. Chemical safety assessment Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body

Other hazards

The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is - TWA: Time-weighted average exposure limit 10.2. Chemical stability Substances subject to the Stockholm Convention: UNSUITABLE EXTINGUISHING EQUIPMENT well aired through effective local aspiration. RESPIRATORY OR SKIN SENSITISATION - VOC: Volatile organic Compounds None

Precautionary statements

None in particular. When choosing personal protective equipment, ask your chemical substance supplier for advice. Information not available -- The product is stable in normal conditions of use and storage. Personal protective equipment must be CE marked, showing that it complies with applicable standards. May produce an allergic reaction. - WGK: Water hazard classes (German). 5.2. Special hazards arising from the substance or mixture Healthcare controls HAND PROTECTION VOC (Directive 2004/42/EC) :

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation

2.3 Other hazards

Does not meet the classification criteria for this hazard class 4. Regulation (EU) 2015/830 of the European Parliament None in particular. However the usual precautions used for chemical products should be respected. CONTAMINATED PACKAGING GENERAL INFORMATION with soap and water after removing protective clothing. 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. No chemical safety assessment has been processed for the mixture and the substances it contains. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for EYE PROTECTION CARCINOGENICITY 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Wear airtight protective goggles (see standard EN 166). 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament EPY 9.6.6 - SDS 1004.9