Appearance

Hazard statements (CLP)

H317, H400, H410, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Upper inflammability limit Information not available proper measures to reduce harmful effects on aquifers. H317 May cause an allergic skin reaction. Not available 7.1. Precautions for safe handling

Environmental hazards

4.1. Description of first aid measures Lower explosive limit H400 Very toxic to aquatic life. Not available

2.1 Classification of the substance or mixture

12.1. Toxicity Changes to previous review: Upper explosive limit Interactive effects H410 Very toxic to aquatic life with long lasting effects. Not available Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the Not applicable The following sections were modified: Vapour pressure H411 Toxic to aquatic life with long lasting effects. 23 mmHg EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering 01 / 02 / 03 / 04 / 08 / 09 / 10 / 11 / 12 / 14 / 15 / 16. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Vapour density Information not available The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). EUH210 Safety data sheet available on request. Not available 14.6. Special precautions for user persists, seek medical advice. places in which people eat. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Relative density However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data 1,53 SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention immediately. Wash contaminated sheet with appropriate information, compliant to (EU) Regulation 2015/830. Solubility ACUTE TOXICITY sheet with appropriate information, compliant to (EU) Regulation 2015/830. WATER 7.2. Conditions for safe storage, including any incompatibilities clothing before using it again. Not applicable 12.2. Persistence and degradability Partition coefficient: n-octanol/water LEGEND: INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention immediately. Not available Hazard classification and indication: Auto-ignition temperature LC50 (Inhalation) of the mixture: - ADR: European Agreement concerning the carriage of Dangerous goods by Road Hazard classification and indication: -- Not available Not classified (no significant component) 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code INGESTION: Get medical advice/attention immediately. Do not induce vomiting. Do not administer anything not explicitly authorised by a Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Decomposition temperature LD50 (Oral) of the mixture: - CAS NUMBER: Chemical Abstract Service Number doctor. from any incompatible materials, see section 10 for details. Not available Not classified (no significant component) Viscosity LD50 (Dermal) of the mixture: CALCIUM CARBONATE - CE50: Effective concentration (required to induce a 50% effect) Information not relevant 120±10 KU Not classified (no significant component)

2.2 Label elements

Explosive properties Solubility in water - CE NUMBER: Identifier in ESIS (European archive of existing substances) 0,1 - 100 mg/l Not available 4.2. Most important symptoms and effects, both acute and delayed 7.3. Specific end use(s) Oxidising properties - CLP: EC Regulation 1272/2008 Not available SECTION 15. Regulatory information Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. TALC - DNEL: Derived No Effect Level Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) Specific information on symptoms and effects caused by the product are unknown. Information not available

Further information

Solubility in water - EmS: Emergency Schedule LD50 (Oral) < 0,1 mg/l 481 mg/kg

Hazard pictograms

GHS: Globally Harmonized System of classification and labeling of chemicals LD50 (Dermal) -- > 1,008 mg/kg 4.3. Indication of any immediate medical attention and special treatment needed 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture SECTION 8. Exposure controls/personal protection VOC (Directive 2004/42/EC) : TITANIUM DIOXIDE - IATA DGR: International Air Transport Association Dangerous Goods Regulation LC50 (Inhalation) 0,90 % - 13,77 1,23 mg/l/4h g/litre

Signal word

Gloss Solubility in water - IC50: Immobilization Concentration 50% -- < 0,001 mg/l 2,6 (60) 29 (85) Information not available Seveso Category - Directive 2012/18/EC: None Degradability: information not available - IMDG: International Maritime Code for dangerous goods CALCIUM CARBONATE 8.1. Control parameters

Hazard statements

IMO: International Maritime Organization LD50 (Oral) 6450 mg/kg Rat 12.3. Bioaccumulative potential SECTION 10. Stability and reactivity SECTION 5. Firefighting measures Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 - INDEX NUMBER: Identifier in Annex VI of CLP EUH210 Safety data sheet available on request. TLV of solvent mixture: None TITANIUM DIOXIDE - LC50: Lethal Concentration 50% EUH208

Contains

reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one 1 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one mg/m3 10.1. Reactivity 5.1. Extinguishing media Information not available - LD50: Lethal dose 50% LD50 (Oral) (3:1) > 10000 mg/kg Rat 8.2. Exposure controls Substances in Candidate List (Art. 59 REACH) - OEL: Occupational Exposure Level 1,2-Benzoisothiazol-3(2H)-one There are no particular risks of reaction with other substances in normal conditions of use. SUITABLE EXTINGUISHING EQUIPMENT On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. SKIN CORROSION / IRRITATION

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation May produce an allergic reaction. 12.4. Mobility in soil The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is - PEC: Predicted environmental Concentration CALCIUM CARBONATE UNSUITABLE EXTINGUISHING EQUIPMENT well aired through effective local aspiration. Substances subject to authorisarion (Annex XIV REACH) Does not meet the classification criteria for this hazard class - PEL: Predicted exposure level Decomposes at temperatures above 800°C/1472°F.

Precautionary statements

None in particular. When choosing personal protective equipment, ask your chemical substance supplier for advice. Information not available None - PNEC: Predicted no effect concentration -- Personal protective equipment must be CE marked, showing that it complies with applicable standards. SERIOUS EYE DAMAGE / IRRITATION - REACH: EC Regulation 1907/2006 10.2. Chemical stability 5.2. Special hazards arising from the substance or mixture HAND PROTECTION Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: VOC (Directive 2004/42/EC) : - RID: Regulation concerning the international transport of dangerous goods by train VOC (Directive 2004/42/EC) :

Results of PBT and vPvB assessment

Coatings for exterior walls of mineral substrate. Protect hands with category III work gloves (see standard EN 374). None Does not meet the classification criteria for this hazard class - TLV: Threshold Limit Value Coatings for exterior walls of mineral substrate. The product is stable in normal conditions of use and storage. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. VOC given in g/litre of product in a ready-to-use condition : - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. VOC given in g/litre of product in a ready-to-use condition : 11,56 Limit value: Do not breathe combustion products. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on Substances subject to the Rotterdam Convention: RESPIRATORY OR SKIN SENSITISATION On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - TWA STEL: Short-term exposure limit Limit value: 40,00 10.3. Possibility of hazardous reactions - Thinned with : the duration and type of use. None - TWA: Time-weighted average exposure limit - Thinned with : 10,00 % WATER 5.3. Advice for firefighters

Other hazards

SKIN PROTECTION May produce an allergic reaction. - VOC: Volatile organic Compounds No hazardous reactions are foreseeable in normal conditions of use and storage. Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body Substances subject to the Stockholm Convention:

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation

2.3 Other hazards

GENERAL INFORMATION with soap and water after removing protective clothing. None Information not available - WGK: Water hazard classes (German). 10.4. Conditions to avoid Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for EYE PROTECTION On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Wear airtight protective goggles (see standard EN 166). Healthcare controls On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. EPY 9.6.6 - SDS 1004.9