1,2-Benzoisothiazol-3(2H)-one

Hazard statements (CLP)

H315, H317, H318, H400, H410, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

1272/2008 The full wording of hazard (H) phrases is given in section 16 of the sheet. Any information on personal protection and disposal is given in sections 8 and 13. Evaporation Rate Delayed and immediate effects as well as chronic effects from short and long-term exposure proper measures to reduce harmful effects on aquifers. H318 Causes serious eye damage. Not available Flammability of solids and gases H315 Causes skin irritation. Not available

2.1 Classification of the substance or mixture

12.1. Toxicity Changes to previous review: Lower inflammability limit Information not available H317 May cause an allergic skin reaction. Not available SECTION 7. Handling and storage Not applicable The following sections were modified: Upper inflammability limit H400 Very toxic to aquatic life. Not available SECTION 4. First aid measures The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). 09. Lower explosive limit Interactive effects Information not available The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). H410 Very toxic to aquatic life with long lasting effects. Not available 7.1. Precautions for safe handling 14.6. Special precautions for user However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Upper explosive limit However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data H411 Toxic to aquatic life with long lasting effects. Not available 4.1. Description of first aid measures sheet with appropriate information, compliant to (EU) Regulation 2015/830. Vapour pressure Information not available sheet with appropriate information, compliant to (EU) Regulation 2015/830. EUH210 Safety data sheet available on request. 23 mmHg Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the Not applicable 12.2. Persistence and degradability Vapour density EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering Not available Hazard classification and indication: Relative density ACUTE TOXICITY Hazard classification and indication: -- 1,45 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code persists, seek medical advice. places in which people eat. Solubility LEGEND: SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention immediately. Wash contaminated WATER 7.2. Conditions for safe storage, including any incompatibilities Partition coefficient: n-octanol/water LC50 (Inhalation) of the mixture: CALCIUM CARBONATE - ADR: European Agreement concerning the carriage of Dangerous goods by Road clothing before using it again. Information not relevant Not available Not classified (no significant component)

2.2 Label elements

Auto-ignition temperature LD50 (Oral) of the mixture: Solubility in water - CAS NUMBER: Chemical Abstract Service Number 0,1 - 100 mg/l Not available Not classified (no significant component) INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention immediately. Decomposition temperature LD50 (Dermal) of the mixture: - CE50: Effective concentration (required to induce a 50% effect) INGESTION: Get medical advice/attention immediately. Do not induce vomiting. Do not administer anything not explicitly authorised by a Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Not available Not classified (no significant component) SECTION 15. Regulatory information Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Viscosity TALC - CE NUMBER: Identifier in ESIS (European archive of existing substances) Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 120±10 KU doctor. from any incompatible materials, see section 10 for details. Explosive properties Solubility in water - CLP: EC Regulation 1272/2008 < 0,1 mg/l Not available

Hazard pictograms

Oxidising properties - DNEL: Derived No Effect Level reaction mass of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one (3 1) -- Not available 4.2. Most important symptoms and effects, both acute and delayed 7.3. Specific end use(s) 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture TITANIUM DIOXIDE - EmS: Emergency Schedule LD50 (Oral) 481 mg/kg

Signal word

Solubility in water - GHS: Globally Harmonized System of classification and labeling of chemicals LD50 (Dermal) -- < 0,001 mg/l > 1,008 mg/kg Specific information on symptoms and effects caused by the product are unknown. Information not available Seveso Category - Directive 2012/18/EC: None Degradability: information not available - IATA DGR: International Air Transport Association Dangerous Goods Regulation LC50 (Inhalation) 1,23 mg/l/4h

Hazard statements

VOC (Directive 2004/42/EC) : - IC50: Immobilization Concentration 50% 0,95 % - 13,78 g/litre 4.3. Indication of any immediate medical attention and special treatment needed 12.3. Bioaccumulative potential SECTION 8. Exposure controls/personal protection Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Gloss - IMDG: International Maritime Code for dangerous goods EUH210 CALCIUM CARBONATE Safety data sheet available on request. 2,5 (60) 22 (85) None LD50 (Oral) - IMO: International Maritime Organization EUH208

Contains

reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H -isothiazol-3- one 6450 mg/kg Rat Information not available INDEX NUMBER Identifier in Annex VI of CLP (3 1) (3:1) 8.1. Control parameters SECTION 10. Stability and reactivity Substances in Candidate List (Art. 59 REACH) - LC50: Lethal Concentration 50% TITANIUM DIOXIDE 1,2-Benzoisothiazol-3(2H)-one SECTION 5. Firefighting measures On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. - LD50: Lethal dose 50% LD50 (Oral) May produce an allergic reaction. > 10000 mg/kg Rat 10.1. Reactivity TLV of solvent mixture: 1 mg/m3 12.4. Mobility in soil - OEL: Occupational Exposure Level 5.1. Extinguishing media Substances subject to authorisarion (Annex XIV REACH) SKIN CORROSION / IRRITATION

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation 8.2. Exposure controls There are no particular risks of reaction with other substances in normal conditions of use. None

Precautionary statements

Information not available - PEC: Predicted environmental Concentration -- SUITABLE EXTINGUISHING EQUIPMENT Does not meet the classification criteria for this hazard class - PEL: Predicted exposure level CALCIUM CARBONATE The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: VOC (Directive 2004/42/EC) : - PNEC: Predicted no effect concentration VOC (Directive 2004/42/EC) : UNSUITABLE EXTINGUISHING EQUIPMENT well aired through effective local aspiration. None Decomposes at temperatures above 800°C/1472°F.

Results of PBT and vPvB assessment

Coatings for exterior walls of mineral substrate. SERIOUS EYE DAMAGE / IRRITATION - REACH: EC Regulation 1907/2006 Coatings for exterior walls of mineral substrate. VOC given in g/litre of product in a ready-to-use condition : None in particular. When choosing personal protective equipment, ask your chemical substance supplier for advice. - RID: Regulation concerning the international transport of dangerous goods by train VOC given in g/litre of product in a ready-to-use condition : 11,56 10.2. Chemical stability Personal protective equipment must be CE marked, showing that it complies with applicable standards. Substances subject to the Rotterdam Convention: Limit value: Does not meet the classification criteria for this hazard class On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - TLV: Threshold Limit Value Limit value: 40,00 5.2. Special hazards arising from the substance or mixture - Thinned with : HAND PROTECTION None - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. - Thinned with : 10,00 % WATER The product is stable in normal conditions of use and storage.

Other hazards

Protect hands with category III work gloves (see standard EN 374). RESPIRATORY OR SKIN SENSITISATION - TWA STEL: Short-term exposure limit HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Substances subject to the Stockholm Convention: - TWA: Time-weighted average exposure limit 10.3. Possibility of hazardous reactions Do not breathe combustion products. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on None

2.3 Other hazards

May produce an allergic reaction. Information not available - VOC: Volatile organic Compounds the duration and type of use.

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation No hazardous reactions are foreseeable in normal conditions of use and storage. SKIN PROTECTION Healthcare controls On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - WGK: Water hazard classes (German). On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. EPY 9.6.6 - SDS 1004.9