Phostoxin Pellets

Detia Degesch GmbH

Revision date : 2011-01-13

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GHS02 GHS06 GHS07 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

20859-73-8

Name of the chemical

Aluminium phosphide; Aluminium phosphide releasing phosphine (under BPR)

Concentration

56 %

Listed in

General Information

Revision date

2011-01-13

Product name

Phostoxin Pellets

1.2.1 Relevant identified uses

Plant protection product

Emergency telephone

+ 49/6201/708-(0)- 503

Icons in SDS

GHS02 GHS06 GHS09

Company Information

company name

Detia Degesch GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

Sicherheitsdatenblaetter@detia-degesch.de

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H260, H300, H311, H319, H400

Hazard statements

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

Section 2

2.1 Classification of the substance or mixture

GHS02, GHS06, GHS09

Signal word

Danger

Hazard statements

H260- In contact with water releases flammable gases which may ignite spontaneously. H300- Fatal if swallowed.. H311- Toxic in contact with skin. H319- Causes serious eye irritation. H400- Very toxic to aquatic life. EUH029- Contact with water liberates toxic gas. EUH032- Contact with acids liberates very toxic gas highly flammable, very toxic, dangerous for the environment

Precautionary statements

P223: Keep away from any possible contact with water, because of violent reaction and possible flash fire. P232: Protect from moisture. P234: Keep only in original container. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P321 Specific treatment in case of the possibility of a poisoning, causing an irritation of the lungs, beclomethasone sprays (e. g. Ventolair 100) or an adequate product for the prevention of swelling of the respiratory ducts and accumulation of fluid in the lungs (pulmonary edema) should be administered. P335: Brush off loose particles from skin. P370+P378 In case of fire Use dry sand or powder and than with CO2 for extinction P402+P404: Store in a dry place. Store in a closed container. P405: Store locked up. P501: Dispose of contents/container to the next pollutant collection, Dispose of emptied container to recycling collections.

EU Classification

Directive 67/548/EEC or Directive 1999/45/EC

Hazard pictograms

F, T+, N

R-phrase(s)

15/29 - Contact with water liberates toxic, extremely flammable gas. 21 - Harmful in contact with skin 26/28 - Very toxic by inhalation and if swallowed. 32 - Contact with acids liberates very toxic gas. 36 - Irritating to eyes 50 - Very toxic to aquatic organisms.

S-phrase(s)

1/2 - Keep locked up and out of the reach of children. 3/9/14/49- Keep only in original container in a cool well-ventilated place away from water and acids. 7/8- Keep container tightly closed and dry. 30 - Never add water to this product. 36/37/ 39 - Wear suitable protective clothing and gloves and eye/face protection. 43- in case of fire use dry sand or powder and than with CO2 . Never use water. 45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 60 - This material and its container must be disposed of as hazardous waste. 61 - Avoid release to the environment. Refer to special instructions/safety data sheets. In contact with water or acids product evolves the extremely flammable and toxic hydrogen phosphide.

2.2 Label elements

See classification according to Directive 67/548/EEC or Directive 1999/45/EC

2.3 Other hazards

3:

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