Note: Ingredients listed on restricted chemical lists
EC/CAS
20859-73-8
Name of the chemical
Aluminium phosphide; Aluminium phosphide releasing phosphine (under BPR)
Concentration
56 %
General Information
Revision date
2011-01-13
Product name
Phostoxin Pellets
1.2.1 Relevant identified uses
Plant protection product
Emergency telephone
+ 49/6201/708-(0)- 503
Icons in SDS
Company Information
company name
Detia Degesch GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
Sicherheitsdatenblaetter@detia-degesch.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H260, H300, H311, H319, H400
Hazard statements
Code
Statements
H260
In contact with water releases flammable gases which may ignite spontaneously
Section 2
2.1 Classification of the substance or mixture
GHS02, GHS06, GHS09
Signal word
Danger
Hazard statements
H260- In contact with water releases flammable gases which may ignite spontaneously. H300- Fatal if swallowed.. H311- Toxic in contact with skin. H319- Causes serious eye irritation. H400- Very toxic to aquatic life. EUH029- Contact with water liberates toxic gas. EUH032- Contact with acids liberates very toxic gas highly flammable, very toxic, dangerous for the environment
Precautionary statements
P223: Keep away from any possible contact with water, because of violent reaction and possible flash fire. P232: Protect from moisture. P234: Keep only in original container. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P321 Specific treatment in case of the possibility of a poisoning, causing an irritation of the lungs, beclomethasone sprays (e. g. Ventolair 100) or an adequate product for the prevention of swelling of the respiratory ducts and accumulation of fluid in the lungs (pulmonary edema) should be administered. P335: Brush off loose particles from skin. P370+P378 In case of fire Use dry sand or powder and than with CO2 for extinction P402+P404: Store in a dry place. Store in a closed container. P405: Store locked up. P501: Dispose of contents/container to the next pollutant collection, Dispose of emptied container to recycling collections.
EU Classification
Directive 67/548/EEC or Directive 1999/45/EC
Hazard pictograms
F, T+, N
R-phrase(s)
15/29 - Contact with water liberates toxic, extremely flammable gas. 21 - Harmful in contact with skin 26/28 - Very toxic by inhalation and if swallowed. 32 - Contact with acids liberates very toxic gas. 36 - Irritating to eyes 50 - Very toxic to aquatic organisms.
S-phrase(s)
1/2 - Keep locked up and out of the reach of children. 3/9/14/49- Keep only in original container in a cool well-ventilated place away from water and acids. 7/8- Keep container tightly closed and dry. 30 - Never add water to this product. 36/37/ 39 - Wear suitable protective clothing and gloves and eye/face protection. 43- in case of fire use dry sand or powder and than with CO2 . Never use water. 45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 60 - This material and its container must be disposed of as hazardous waste. 61 - Avoid release to the environment. Refer to special instructions/safety data sheets. In contact with water or acids product evolves the extremely flammable and toxic hydrogen phosphide.
2.2 Label elements
See classification according to Directive 67/548/EEC or Directive 1999/45/EC
2.3 Other hazards
3: